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Solids

12.1

Crystal Structure:

  • Materials on Earth are crystals.

  • Crystals are arrays of atoms.

  • X-Rays confirm that crystals are three dimensional arrangements of atoms.

  • The atoms are very close together.

    • They’re the same distance apart as X-ray wavelengths.

  • A beam of X-rays directed on a crystal gets diffracted into a characteristic pattern.

  • This pattern can be made visible on a photographic film.

    • The pattern is a diffraction pattern.

    • The film shows that crystals are mosaics of atoms located in regular lattices.

  • Iron, copper, gold → simple crystal structures

  • Tin, cobalt → slightly more complex structures

  • All metals have many crystals.

    • Each crystal has the same regular lattice.

    • Each is slightly inclined to the crystal nearby.

  • When metal surface is etched, the crystals can be seen.

Etched → cleaned with acid

  • Crystal structures can be seen:

    • On the surface of galvanized iron

    • On brass doorknobs that get etched with perspiration from hands

  • There’s a formula that shows how X-rays should scatter from the atomic layers in a crystal.

  • This formula combines with the analysis of the pattern of spots in a diffraction pattern to find distances between atoms in a crystal.

X-ray diffraction is vital in biological and physical sciences.

  • Non-crystalline solids are amorphous.

    • Amorphous → atoms and molecules are distributed randomly.

    • Particles can wander.

    • Eg: Rubber, glass, plastic

  • In all atoms, atoms and ions vibrate in their positions.

  • Atoms are tied together by electrical bonding forces.

    • Called atomic bonding.

    • Types of bonding in solids:

      • ionic

      • covalent

      • metallic

      • van der Waals (the weakest)

Solids

12.1

Crystal Structure:

  • Materials on Earth are crystals.

  • Crystals are arrays of atoms.

  • X-Rays confirm that crystals are three dimensional arrangements of atoms.

  • The atoms are very close together.

    • They’re the same distance apart as X-ray wavelengths.

  • A beam of X-rays directed on a crystal gets diffracted into a characteristic pattern.

  • This pattern can be made visible on a photographic film.

    • The pattern is a diffraction pattern.

    • The film shows that crystals are mosaics of atoms located in regular lattices.

  • Iron, copper, gold → simple crystal structures

  • Tin, cobalt → slightly more complex structures

  • All metals have many crystals.

    • Each crystal has the same regular lattice.

    • Each is slightly inclined to the crystal nearby.

  • When metal surface is etched, the crystals can be seen.

Etched → cleaned with acid

  • Crystal structures can be seen:

    • On the surface of galvanized iron

    • On brass doorknobs that get etched with perspiration from hands

  • There’s a formula that shows how X-rays should scatter from the atomic layers in a crystal.

  • This formula combines with the analysis of the pattern of spots in a diffraction pattern to find distances between atoms in a crystal.

X-ray diffraction is vital in biological and physical sciences.

  • Non-crystalline solids are amorphous.

    • Amorphous → atoms and molecules are distributed randomly.

    • Particles can wander.

    • Eg: Rubber, glass, plastic

  • In all atoms, atoms and ions vibrate in their positions.

  • Atoms are tied together by electrical bonding forces.

    • Called atomic bonding.

    • Types of bonding in solids:

      • ionic

      • covalent

      • metallic

      • van der Waals (the weakest)