Chemistry Unit 2: Atomic Structure and Matter
Democritus Model Main idea: atoms are uniform, solid, indestructible
Democritus Model Experiments: keep breaking a seashell until you can’t anymore to reach the atom
Democritus Model Shortcomings: no experimental evidence; He believed that atoms are fully solid with no internal structure; illogical for a void of nothingness to exist; Believed that different atom shapes relate to different properties
Democritus Model Other key info: based on reasoning, not science
Empedocles Model Main idea: all matter is made up of different ratios of earth, fire, water, and air
Empedocles Model Scientist: Aristotle
other key info: chemical reactions happen when they are converted from one form to another
Solid Sphere Model Main idea: atoms are spheres that cannot be broken down
Solid Sphere Model Scientist: John Dalton
Solid Sphere Model Shortcomings: does not mention isotopes, ions, nucleus, or subatomic particles
Solid Sphere Model Other key info: Based on the law of conservation of mass and the law of constant composition
Plum Pudding Main idea: negative force exists in the atom floating around; something positive exists as well (probably floating around)
Plum Pudding Scientist: JJ Thomson
Plum Pudding Experiments: Experiments with Cathode Rays: A glass tube with some air inside and high voltage is applied. Causes a beam of negatively charged particles to flow
Plum Pudding Shortcomings: protons are centered in the nucleus
Plum Pudding Other key info: used cathode rays
Nuclear Model Main idea: Nuclear model consists of a small positively charged nucleus surrounded by orbiting negatively charged electrons
Nuclear Model Scientist: Ernest Rutherford
Nuclear Model Experiments: Gold Foil experiment - Positively charged alpha particles were fired at a very thin sheet of pure gold; Predicted: Alpha particles would pass straight through the gold foil, as there was no strong positive aspect of the atom to interfere
Nuclear Model Shortcomings: failed to explain the stability of electrons
Planetary Model Main idea: electron orbitals
Planetary Model Scientist: Niels Bohr
Planetary Model Shortcomings - explains the stability of an atom but only worked for the hydrogen atom
Planetary Model Other key info - in model, all electrons are quantized
Quantum Model Main idea: the law of uncertainty (the more you know about location, the less you know about energy and vice versa)
Quantum Model Scientist: Erwin Shrodinger
Quantum Model Other key info: based on probability, not certainty
What are the three subatomic particles? Protons, neutrons, and electrons
What is a nucleus? Most of the mass of the atom; contains protons and neutrons
Which subatomic particle distinguishes one atom from another? protons
How do you write a nuclear symbol? You write the atomic symbol in the middle; atomic mass on the top left; atomic number on the bottom left; the charge (if any) on the top right
What is an ion? An atom with a charge
What is a positively charged ion? cation
What is a negatively charged ion? anion
Are all atoms ions? No, but most are because they want to have a full valence shell
Are all atoms isotopes? yes.
What are isotopes? Atoms with different masses (neutrons)
What are the uses of a radioactive isotope? Can be used in geological dating, treating cancer, killing bacteria, and tracers in medical diagnosis
What is average atomic mass? The average mass of all of the atoms of that element
How do you calculate the average atomic mass? Multiply the mass by the fraction it appears in the world; add all of them up together
What is mass spectroscopy? an analytical tool that measures the atomic mass of an element
What are some real-world uses of mass spectroscopy? Forensics, soil contamination, medicine
What is an element? a pure substance that consists entirely of one type of atom
What is a compound? a pure substance formed by two or more different elements
How do you read a chemical formula? from left to right; coefficient x subscript
What are molecules? the simplest part of a covalent substance that retains all of the properties of a substance and exists in a free state
What does the subscript of a chemical formula mean? The number of atoms in one mole
What does the coefficient of a chemical formula mean? The number of moles
What is a pure substance? made up of only one kind of element or compound
What is a mixture? combination of two or more pure substances in which each pure substance retains its individual chemical properties
What is a homogeneous mixture? Particles are equally mixed throughout the mixture
What is an example of a homogenous mixture? a mixture that has constant composition throughout
What are the examples of homogeneous mixtures? mercury/silver fillings
What is the difference between a solvent and a solute? The solvent dissolves the solute
What is the universal solvent? water
What is a heterogeneous mixture? a mixture that does not blend smoothly through and in which the individual substances remain distinct
What is an example of a heterogeneous mixture? salad dressing
What are the types of heterogeneous mixtures? colloid and suspension
What is a colloid? Looks like a solution
How do you determine the difference between a colloid and a solution? Tyndall’s Law - shine a flashlight; colloids scatter the light
What is a suspension? a mixture of two visibly unmixable things
What are the separation techniques? Describe each one.
hand separation: if the particles are large and distinct enough
separation by magnetism: if one component is magnetic and the other is not
filtration: a technique that uses a porous barrier to separate a solid from liquid
Distillation: difference in boiling points
Crystallization: supersaturated solution
What is dialysis? a process that removes waste and excess from the body
What is the relationship between distillation and healthcare? recovering reactants, purifying medicines, isolating compounds
What are the types of chromatography? Gas, column, thin layer chromatography
How does chromatography help law enforcement? Chemical analysis and gas chromatography
When do nuclear reactions happen? Nuclei split, combine, emit radiation
What subatomic particle changes? Protons because you are making a new element
What is nuclear fission? Breaking apart of the nucleus
What is nuclear fusion? Joining nuclei (happens at the sun)
What are radioisotopes? Radioactive isotopes
What is the “magic” stability number? 60 AMU
What element is considered the most stable? nickel
What is alpha decay? Most stable; higher mass atoms do it; lose a hydrogen atom
What is beta decay? Lose an electron
What is gamma decay? Lose photons
What is half-life? The amount of time it takes for radioactive material to become half of its original mass
What is a decay curve? Exponential graph representing radioactive decay
Explain Coulomb’s Law. binding energy = (charge of particle 1 x charge of particle 2)/ radius^2
What are the three types of bonds? Ionic (nonmetal/metal; GIVE), covalent (nonmetal/nonmetal; SHARE), and metallic (metal/metal)
Democritus Model Main idea: atoms are uniform, solid, indestructible
Democritus Model Experiments: keep breaking a seashell until you can’t anymore to reach the atom
Democritus Model Shortcomings: no experimental evidence; He believed that atoms are fully solid with no internal structure; illogical for a void of nothingness to exist; Believed that different atom shapes relate to different properties
Democritus Model Other key info: based on reasoning, not science
Empedocles Model Main idea: all matter is made up of different ratios of earth, fire, water, and air
Empedocles Model Scientist: Aristotle
other key info: chemical reactions happen when they are converted from one form to another
Solid Sphere Model Main idea: atoms are spheres that cannot be broken down
Solid Sphere Model Scientist: John Dalton
Solid Sphere Model Shortcomings: does not mention isotopes, ions, nucleus, or subatomic particles
Solid Sphere Model Other key info: Based on the law of conservation of mass and the law of constant composition
Plum Pudding Main idea: negative force exists in the atom floating around; something positive exists as well (probably floating around)
Plum Pudding Scientist: JJ Thomson
Plum Pudding Experiments: Experiments with Cathode Rays: A glass tube with some air inside and high voltage is applied. Causes a beam of negatively charged particles to flow
Plum Pudding Shortcomings: protons are centered in the nucleus
Plum Pudding Other key info: used cathode rays
Nuclear Model Main idea: Nuclear model consists of a small positively charged nucleus surrounded by orbiting negatively charged electrons
Nuclear Model Scientist: Ernest Rutherford
Nuclear Model Experiments: Gold Foil experiment - Positively charged alpha particles were fired at a very thin sheet of pure gold; Predicted: Alpha particles would pass straight through the gold foil, as there was no strong positive aspect of the atom to interfere
Nuclear Model Shortcomings: failed to explain the stability of electrons
Planetary Model Main idea: electron orbitals
Planetary Model Scientist: Niels Bohr
Planetary Model Shortcomings - explains the stability of an atom but only worked for the hydrogen atom
Planetary Model Other key info - in model, all electrons are quantized
Quantum Model Main idea: the law of uncertainty (the more you know about location, the less you know about energy and vice versa)
Quantum Model Scientist: Erwin Shrodinger
Quantum Model Other key info: based on probability, not certainty
What are the three subatomic particles? Protons, neutrons, and electrons
What is a nucleus? Most of the mass of the atom; contains protons and neutrons
Which subatomic particle distinguishes one atom from another? protons
How do you write a nuclear symbol? You write the atomic symbol in the middle; atomic mass on the top left; atomic number on the bottom left; the charge (if any) on the top right
What is an ion? An atom with a charge
What is a positively charged ion? cation
What is a negatively charged ion? anion
Are all atoms ions? No, but most are because they want to have a full valence shell
Are all atoms isotopes? yes.
What are isotopes? Atoms with different masses (neutrons)
What are the uses of a radioactive isotope? Can be used in geological dating, treating cancer, killing bacteria, and tracers in medical diagnosis
What is average atomic mass? The average mass of all of the atoms of that element
How do you calculate the average atomic mass? Multiply the mass by the fraction it appears in the world; add all of them up together
What is mass spectroscopy? an analytical tool that measures the atomic mass of an element
What are some real-world uses of mass spectroscopy? Forensics, soil contamination, medicine
What is an element? a pure substance that consists entirely of one type of atom
What is a compound? a pure substance formed by two or more different elements
How do you read a chemical formula? from left to right; coefficient x subscript
What are molecules? the simplest part of a covalent substance that retains all of the properties of a substance and exists in a free state
What does the subscript of a chemical formula mean? The number of atoms in one mole
What does the coefficient of a chemical formula mean? The number of moles
What is a pure substance? made up of only one kind of element or compound
What is a mixture? combination of two or more pure substances in which each pure substance retains its individual chemical properties
What is a homogeneous mixture? Particles are equally mixed throughout the mixture
What is an example of a homogenous mixture? a mixture that has constant composition throughout
What are the examples of homogeneous mixtures? mercury/silver fillings
What is the difference between a solvent and a solute? The solvent dissolves the solute
What is the universal solvent? water
What is a heterogeneous mixture? a mixture that does not blend smoothly through and in which the individual substances remain distinct
What is an example of a heterogeneous mixture? salad dressing
What are the types of heterogeneous mixtures? colloid and suspension
What is a colloid? Looks like a solution
How do you determine the difference between a colloid and a solution? Tyndall’s Law - shine a flashlight; colloids scatter the light
What is a suspension? a mixture of two visibly unmixable things
What are the separation techniques? Describe each one.
hand separation: if the particles are large and distinct enough
separation by magnetism: if one component is magnetic and the other is not
filtration: a technique that uses a porous barrier to separate a solid from liquid
Distillation: difference in boiling points
Crystallization: supersaturated solution
What is dialysis? a process that removes waste and excess from the body
What is the relationship between distillation and healthcare? recovering reactants, purifying medicines, isolating compounds
What are the types of chromatography? Gas, column, thin layer chromatography
How does chromatography help law enforcement? Chemical analysis and gas chromatography
When do nuclear reactions happen? Nuclei split, combine, emit radiation
What subatomic particle changes? Protons because you are making a new element
What is nuclear fission? Breaking apart of the nucleus
What is nuclear fusion? Joining nuclei (happens at the sun)
What are radioisotopes? Radioactive isotopes
What is the “magic” stability number? 60 AMU
What element is considered the most stable? nickel
What is alpha decay? Most stable; higher mass atoms do it; lose a hydrogen atom
What is beta decay? Lose an electron
What is gamma decay? Lose photons
What is half-life? The amount of time it takes for radioactive material to become half of its original mass
What is a decay curve? Exponential graph representing radioactive decay
Explain Coulomb’s Law. binding energy = (charge of particle 1 x charge of particle 2)/ radius^2
What are the three types of bonds? Ionic (nonmetal/metal; GIVE), covalent (nonmetal/nonmetal; SHARE), and metallic (metal/metal)