Unit 2 - Understanding the Atom

The Historical Development of Atomic Theory

  • Democritus - Early philosopher who proposed the existence of the atom
  • Dalton’s Atomic Theory
    • First scientific theory of the atom
    • Based on Joseph Proust and other scientists’ research
    • Proust’s research: each compound contains exact proportions
      • Law of definite proportions
    • Atoms are indivisible
    • Elements are made of identical atoms unique to each element
    • Compounds are made of 2+ atoms in fixed proportion
    • A chemical reaction is the rearrangement of atoms
  • Discovery of the Electron (Cathode Ray Experiment)
  • By JJ Thompson
  • Led to the Plum Pudding Model
  • Oil Drop Experiment
    • By Millikan
    • Thompson found charge & mass of electron
  • Discovery of Nucleus (Gold Foil Experiment)
    • By Rutherford
    • Most particles pass directly through the atom, some get deflected
    • → Most of the atom is empty space, with a large particle at the center
  • Quiz: https://quizizz.com/admin/quiz/5faee2a376564d001b6fb43a/the-historical-development-of-atomic-theory

Electromagnetic Waves

  • Vocab
    • Electric Field - The area surrounding a charged object in which it can act upon another charged object
    • Electromagnetic Spectrum
    • The frequency spectrum containing all electromagnetic waves
    • Electromagnetic Wave
    • A combination of electric & magnetic fields radiating from a source @ the speed of light.
      • The electric & magnetic fields oscillate perpendicular of each other
    • Caused by disturbing charged particles, which then oscillate and produce oscillating fields
      • Source produces an magnetic field, the magnetic field then produces an electric field, the electric field the produces another magnetic field, repeat forever
    • Magnetic Field - The area surrounding a magnetic object in which it can act upon an object
    • Polarization
  • Types of Waves
    • Mechanical - Waves that use matter to carry energy
    • Electromagnetic - Waves that do not use/need matter to carry energy
    • Are all transverse waves
  • Parts of a Transverse Wave
    • Crest - Midline → Top
    • Trough - Midline → Bottom
    • Amplitude - Top → Midline or Midline → Bottom
    • Wavelength - Crest 1 → Crest 2
    • Frequency - Oscillations per second
  • Electromagnetic Waves
    • Each type is contained on a different part of the electromagnetic spectrum
    • High frequency/low wavelength → low frequency/high wavelength:
      • Gamma Rays → X-Rays → Ultraviolet → Visible Light → Infrared → Microwaves → Radio waves
    • Energy transferred
    • Energy = plank’s constant * frequency
      • Plank’s constant ~ 6.63 * 10^-34
    • Frequency, Wavelength, & Speed
    • Speed of light = frequency(hertz) * wavelength(meters)
    • Slower = Smaller wavelength
    • Uses
    • Gamma Rays - Used to destroy cancer cells
    • Ultraviolet Rays - Disrupts DNA production in bacteria & viruses
    • X-Rays - Used for medical imaging
    • Infrared - Heat lamps, remote controls
    • Microwaves - Warm food
    • Radio waves - Long distance transmission of information
    • Polarization - Modifying light by forcing it to only vibrate in a singular plane

The Modern Atomic Theory

  • Theories of Light
    • Newton - Corpuscular theory; light is made of particles
    • Thomas Young - Diffraction double slit experiment; light behaves like waves
    • Heinrich Hertz - Photoelectric effect observed; also acts like a particle
  • Photoelectric Effect
    • Electrons are emitted when electromagnetic waves hit a material
    • Shows particle like behavior
    • Einstein proposes light is a stream of particles called photons
      • Energy = Plank’s constant * frequency
  • Emission Spectrum
    • Visible light spectrum where emitted light produce colored bands
    • Some metals showed up as discrete lines
  • Bohr Model
    • Electrons orbit nucleus made of protons & neutrons
  • Electron Cloud Model
    • Electrons have probable locations
    • Each cloud has different energy levels

The Structure of the Atom

  • Atom - Smallest particle of a substance
    • Made of a nucleus surrounded by orbitals
    • Consists of 3 types of particals
    • Protons - Positively charged
    • Neutrons - Particle w/o charge
    • Electron - Negatively charged electron
    • Charge of proton = negative charged of electron
    • If charge of atom = 0, then the atoms has == number of protons & electrons
    • Locations
    • Nucleus - Contains all the protons & neutrons
    • Orbitals - Contains the electrons
  • Atomic mass unit
    • 1/12 of a C12 atom
    • ~ 1.660538921 * 10^-24 g
    • Proton - 1 amu
    • Neutron - 1 amu
    • Electron - 0.0006 amu
  • Atomic Number
    • \
      # of Protons in an atom
  • Ions
    • Charged atoms
    • Changed number of electrons
  • Atomic Mass / Mass Number
    • \
      # of Protons + # of Neutrons
  • Isotopes
    • Different # of neutrons