Carbohydrates and Lipids
Describe characteristics of carbohydrates.
Organic compounds
Glucose, fructose, (starch)
1:2:1 ratio of carbon, hydrogen and oxygen
general empirical formula: CH20
State the function of a carbohydrate. Source of energy (ATP)
State the monomer of a carbohydrate. Monosaccharide
State the shape(s) of most monosaccharides. Ring
Distinguish between pentose and hexose sugars. Pentose has 5 carbon sugars while hexose has 6 carbon sugars.
State what functional group makes monosaccharides polar / hydrophilic. -OH (Hydroxyl) groups
State the 3 hexose monosaccharides and their function.
Galactose- combines with glucose to form lactose
Fructose- plants, sweetens fruits, honey
Glucose- most common energy source
Compare functions of alpha and beta glucose. Alpha is the monomer of starch and glycogen and beta is the monomer of cellulose. Both are made during photosynthesis and are used for ATP production.
Describe isomer. One of two or more compounds that have the same chemical formula but different arrangements of the atoms within the molecules and that may have different physical/chemical properties.
Be able to label alpha glucose
Be able to label beta glucose
State the 2 pentose monosaccharides and their function. Ribose (monomer of RNA) and Deoxyribose (monomer of DNA)
Describe the formation of a disaccharide. 2 monosaccharides covalently bond together and lose water.
State the specific type of bond that holds together disaccharides. Glycosidic bond
Distinguish between alpha and beta bonds.
If the glycosidic bond points down = alpha bond
If the glycosidic bond points up = beta bond
Be able to identify alpha and beta bonds
Outline lactose (disaccharide) by giving function and monomers. Lactose (mammal milk sugar) Glucose + Galactose
Outline maltose (disaccharide) by giving function and monomers. Maltose (sprouting grains) Glucose + Glucose
Outline sucrose (disaccharide) by giving function and monomers. Sucrose (table sugar) Glucose + Fructose
Be able to identify maltose
Outline a condensation / anabolic reaction, stating a specific example with creating a disaccharide (tell me sm/lg, water made/used and ex using glucose/maltose)
Condensation is the process of forming maltose from two glucose molecules, represented as:
2 Glucose → Maltose + Water
Here, water is produced during the reaction.
Outline a hydrolysis / catabolic reaction, stating a specific example with breaking down a disaccharide (tell me sm/lg, water made/used and ex using glucose/maltose)
Hydrolysis is a reaction that breaks down maltose (a disaccharide) into two glucose molecules using water. The reaction can be represented as:
Maltose + Water → 2 Glucose
Here, water is used to cleave the bond between the glucose units.
State the solubility of the starch, glycogen, cellulose
Starch: Insoluble in cold water, forms gel in hot water
Glycogen: Soluble in water.
Cellulose: Insoluble in water.
Outline the structure and function of starch (polysaccharide) Composed of glucose chains (amylose and amylopectin); functions as energy storage in plants
Outline the structure and function of glycogen (polysaccharide) Highly branched glucose chains; serves as energy storage in animals.
Outline the structure and function of cellulose (polysaccharide) Linear glucose chains; provides structural support
Distinguish between amylose and amylopectin
Amylose: alpha 1’-4’ glycosidic bonds (linear)
Amylopectin: alpha 1’-4’/ 1’-6’ glycosidic bond (branched)
Be able to identify starch with amylose, starch with amylose and amylopectin, glycogen, cellulose diagrams
State building blocks of lipids. Fatty acids and glycerol
State the shape of lipids. Hydrocarbon chains (fatty acids) and some rings (steroids)
State the specific bond seen in lipids. Ester Linkage
State the functions of lipids
Waterproofing / retention
Plasma membrane structure
Regulating metabolic processes
Long Term Energy storage/ Protection/ Buoyancy
State the 4 main types of lipids
Waxes
Phospholipid
Steroids
Triglycerides
Outline the structure and function of phospholipids.
Structure: 2 fatty acids, 1 glycerol, 1 phosphate bonded
Function: Form plasma membrane
Outline the structure and function of waxes.
-Structure: Long hydrocarbon chains
Function: Waterproofing or water retention in structures
Outline the structure and function of steroids.
-Structure: 4 fused rings
Function: regulate metabolic processes, signal molecule
Easily pass through plasma membrane
Ex: Cholesterol, progesterone, estrogen, testosterone
Outline the structure and function of triglycerides.
Structure: 3 Fatty acids bonded to 1 glycerol
Condensation rxn
(Anabolic) creates ester linkage
Hydrolysis rxn (catabolic) breaks down
Function: Long Term energy storage
Ex: Fats and oils
Describe how condensation and hydrolysis can make/break down triglycerides. Condensation: Glycerol + fatty acids form triglycerides + water released.
Hydrolysis: Triglycerides break down into glycerol + fatty acids + water added.
Compare the energy store of carbohydrates and lipids.
Carbohydrates: store x amounts of energy, heavier, and water required for storage.
Lipids: Store 2x amounts of energy, lighter, and no water required for storage.
State the 3 types of fatty acids. Saturated, monounsaturated, or polyunsaturated
Be able Label a saturated fatty acid
Distinguish between saturated and unsaturated fatty acids.
Saturated: No double bonds, solid at room temperature.
Unsaturated: One or more double bonds, liquid at room temperature.
Describe monounsaturated fatty acids. One double bond in the carbon chain. Liquid at room temperature. Generally healthy. Ex: Olive oil
Describe polyunsaturated fatty acids. Multiple double bonds in the carbon chain. Liquid at room temperature. Ex: Omegas 3’s (fish oil)
State the main type of fats in endotherm animals. Saturated fats
State the main type of fats in ectotherm animals. Unsaturated fats
State the main type of fats in plants. Unsaturated fats
State the main type of fats in tropical plants. Saturated fats
Compare cis and trans isomers of unsaturated fatty acids.
Cis unsaturated
Hydrogens bond to carbons on same side of double
Naturally occurring
Bent shape
Healthy
Trans unsaturated
Hydrogens bond to carbons on different sides of double bond
Not naturally occuring
Hydrogen is added to oils, solidifying them
Straight
Unhealthy
Discuss why trans fats are considered to be unhealthy.
Raise bad (LDL) cholesterol levels
Lower good (HDL) cholesterol levels
Higher risk of coronary heart disease
Higher risk for type 2 diabetes
Triglyceride
Steroid
Phospholipid
Saturated fat
Monounsaturated fat
Polyunsaturated fat