
Chapter 10 - Acids and Bases and Equilibrium
10.1 - Acids and Bases
H+ is produced by Arrhenius acid, OH- is generated by Arrhenius base in aqueous solutions.
Acids taste sour, sting, and neutralize the foundations.
Bases are bitter, slippery, and acid-neutralizing.
Simple anionic acids use a prefix, whereas ic or ous acids are named with oxygen-containing polyatomic anions.
10.2 - Brønsted–Lowry Acids and Bases
Acids are H+ donors and bases are H+ acceptors, according to Brønsted–Lowry theory.
The loss or gain of one H+ is linked to a conjugate acid-base pair.
The F- is the conjugate base, for example, when the HF acid gives H+. H3O+/H2O would be the other acid-base pair.
10.3 - Strengths of Acids and Bases
Strong acids are totally dissociated in water, and H+ is accepted as a basis for H2O.
Slightly dissociate weak acids in water, producing little H3O+.
The hydroxides of the 1A(1) and 2A(2) groups are strong bases and fully dissociate from water.
Ammonia, NH3, is an important weak base.
10.4 - Acid–Base Equilibrium
In a reversible reaction, the chemical balance occurs if the rate of the reverse reaction is equal to its rates.
At equilibrium, reactants and products are not further affected as reverse and forward reactions continue.
When reactants are removed or products are added to a balanced mixture, the system moves to reactants to restore balance
When reactants are added or products are removed from the balanced mix, the system moves toward the product to restore balance.
10.5 - Dissociation of Water
A few water molecules in pure waters transfer H+ to other water molecules, which produce small but equal H3O+ and OH- amounts.
The molar levels of H3O+ and OH- are 1,0 * 10-7 M in pure water each.
Kw = [H3O+] The expression of water dissociation = 1,0 * 10-14 at 25 degrees Celsius.
[H3O+] is higher than [OH-] in acidic solutions.
The [OH-] is larger than the [H3O+] in basic solutions.
10.6 - The pH Scale
The pH scale is the [H3O+] of solution for a range of numbers, typically 0 to 14.
A pH of 7.0 is available in a neutral solution.
The pH is lower than 7.0 is acidic solutions; the pH in basic solutions is higher than 7.0.
The negative logarithm of pH ion concentration, pH = -log[H3O+], is the mathematical pH.
10.7 - Reactions of Acids and Bases
In the production of hydrogen gas and salt, an acid reacts with a metal.
The carbonate or bicarbonate reaction of acid produces carbon dioxide, water, and salt.
An acid reacts with a basis for water and salt in neutralization.
An acid sample with a known amount of a base is neutralized in the titration.
The acid concentration is calculated based on the volume and molarity of the base.
10.8 - Buffers
When small amounts of acid or base are added, a buffer solution resists pH changes.
A buffer has either a faint acid, salt, or a weak base, and salt
A buffer with the addition of OH reacts with weak acid, and the salt anion reacts with the addition of H3O+.
10.1 - Acids and Bases
H+ is produced by Arrhenius acid, OH- is generated by Arrhenius base in aqueous solutions.
Acids taste sour, sting, and neutralize the foundations.
Bases are bitter, slippery, and acid-neutralizing.
Simple anionic acids use a prefix, whereas ic or ous acids are named with oxygen-containing polyatomic anions.
10.2 - Brønsted–Lowry Acids and Bases
Acids are H+ donors and bases are H+ acceptors, according to Brønsted–Lowry theory.
The loss or gain of one H+ is linked to a conjugate acid-base pair.
The F- is the conjugate base, for example, when the HF acid gives H+. H3O+/H2O would be the other acid-base pair.
10.3 - Strengths of Acids and Bases
Strong acids are totally dissociated in water, and H+ is accepted as a basis for H2O.
Slightly dissociate weak acids in water, producing little H3O+.
The hydroxides of the 1A(1) and 2A(2) groups are strong bases and fully dissociate from water.
Ammonia, NH3, is an important weak base.
10.4 - Acid–Base Equilibrium
In a reversible reaction, the chemical balance occurs if the rate of the reverse reaction is equal to its rates.
At equilibrium, reactants and products are not further affected as reverse and forward reactions continue.
When reactants are removed or products are added to a balanced mixture, the system moves to reactants to restore balance
When reactants are added or products are removed from the balanced mix, the system moves toward the product to restore balance.
10.5 - Dissociation of Water
A few water molecules in pure waters transfer H+ to other water molecules, which produce small but equal H3O+ and OH- amounts.
The molar levels of H3O+ and OH- are 1,0 * 10-7 M in pure water each.
Kw = [H3O+] The expression of water dissociation = 1,0 * 10-14 at 25 degrees Celsius.
[H3O+] is higher than [OH-] in acidic solutions.
The [OH-] is larger than the [H3O+] in basic solutions.
10.6 - The pH Scale
The pH scale is the [H3O+] of solution for a range of numbers, typically 0 to 14.
A pH of 7.0 is available in a neutral solution.
The pH is lower than 7.0 is acidic solutions; the pH in basic solutions is higher than 7.0.
The negative logarithm of pH ion concentration, pH = -log[H3O+], is the mathematical pH.
10.7 - Reactions of Acids and Bases
In the production of hydrogen gas and salt, an acid reacts with a metal.
The carbonate or bicarbonate reaction of acid produces carbon dioxide, water, and salt.
An acid reacts with a basis for water and salt in neutralization.
An acid sample with a known amount of a base is neutralized in the titration.
The acid concentration is calculated based on the volume and molarity of the base.
10.8 - Buffers
When small amounts of acid or base are added, a buffer solution resists pH changes.
A buffer has either a faint acid, salt, or a weak base, and salt
A buffer with the addition of OH reacts with weak acid, and the salt anion reacts with the addition of H3O+.