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Home
Science
Chemistry
Equilibrium
Equilibrium Calculations
Introduction
Types of Equilibrium Calculations:
Calculation of an equilibrium constant
Calculation of missing equilibrium concentration or partial pressure
Calculation of equilibrium concentrations (or partial pressures) from initial concentrations (or partial pressures)
Manipulating Equilibrium Constants
The equilibrium constant of a reaction in the reverse reaction is the reciprocal of the equilibrium constant of the forward reaction
The equilibrium constant of a reaction that has been multiplied by a number is the equilibrium constant raised to a power that is equal to that number
The equilibrium constant for a net reaction made up of two or more steps is the product of the equilibrium constants for the individual steps.
Solving Equilibrium Problems
All equilibrium problems require the correct expression for K (or Q).
They can be divided into 4 types. Two are very easy, the third more complicated, the fourth more complicated, but unfortunately, more common.
All concentrations (or pressures ) are given, find K.
Simply substitute the given values into the equilibrium expression.
K is given. All but one of the equilibrium concentrations are given, find the other one.
Finding K, when all the initial concentrations are known, and ONE equilibrium concentration is given.
It is necessary to set up a reaction table, sometimes called an “ICE chart” to find ALL the equilibrium concentrations.
THEN, you can put those values into the equilibrium equation to find K.
K is known, initial conc. are known, find one or more FINAL concentration.
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