9.1: Stratospheric Ozone
Ozone forms naturally in stratosphere (3 oxygen atoms)
Stratospheric ozone layer protects organisms and ecosystems by blocking harmful UV radiation
Naturally forms when UV radiation splits O2 into O atoms that collide and bond with other O2 molecules to form O3
Stratospheric ozone depletion
When pollutants break down ozone molecules caused by human emissions of ozone depleting substances (CFCs, HBFCs, Halons, nitrous oxide)
Can also be broken down by natural phenomena like volcanic eruptions but human’s actions are more harmful
Thinner ozone layer = more UV radiation = more harmful impacts like skin cancer, cataracts, reduced phytoplankton abundance, lower plant productivity
Ozone thinning is SEASONAL:
Severe in polar regions due to polar stratospheric clouds that accumulate ozone depleting substances
Spring in each hemisphere — ozone depleted air moves to lower latitudes and warmer temperatures speed up chemical reactions that help ozone layers recover
Ozone in troposphere (earth’s lower atmosphere) is harmful as it irritates respiratory systems and worsens health conditions, while reducing plants abilities to photosynthesis → lowered crop yields
Tropospheric ozone formed by VOCs, NOx, and sunlight
Ozone depleting substances include:
Chlorofluorocarbons (CFCs) — chemicals that were used mainly in refrigerants, aerosols, and cleaning solvents
hydrobromofluorocarbons (HBFCs), halons, methyl bromide, hydrogen chloride
Nitrous oxide — released through human activities and natural phenomena
9.2 — Reducing Ozone Depletion
Human emissions of ODSs led to substantial stratospheric ozone depletion
Replacing ODSs (Ozone depleting substances) supports natural regeneration of ozone layer
Some substitutes work well but others have drawbacks
HCFCs can still damage ozone layers
HFCs (hydrofluorocarbons) and PFCs don’t break down ozone but are greenhouse gases that contribute to global warming
Other technologies and strategies can also reduce ozone depletion like using pumps instead of aerosol sprays
Montreal Protocol — global treaty signed that aims to phase out ODs
U.S. Clean Air Act — allows the environmental protection agency to regulate ODs with strict penalties for non-compliance
Global efforts led to a 99% reduction of ODS emissions, causing increase in stratospheric ozone but full recovery is not expected until 2050
9.3 — The Greenhouse Effect
Principal greenhouse gases include carbon dioxide, methane, water vapor, nitrous oxide, and chlorofluorocarbons (CFCs)
Water vapor is a greenhouse gas but it isn’t that significant since it has a short residence time in the atmosphere
Greenhouse effect — process by which energy from the sun is trapped in the form of heat by various types of gases
Results in the surface temperature necessary for life on earth to exist
Sun releases thermal and light energy → visible light and UV radiation reaches the earth → some energy absorbed by earth and then re-emitted as lower-energy infrared radiation → energy moves away from earth back into space
When infrared radiation sent back to earth’s surface reaches the atmosphere, greenhouse gases trap a portion of the radiation that causes the earth to rise in temperature, holding the energy into the troposphere
Carbon dioxide (has a global warming potential — GWP — of 1) is used as a reference point for the comparison of different greenhouse gases and their impacts on global climate change
Chlorofluorocarbons have highest GWP, followed by nitrous oxide, then methane
Thermal retention property — gases holding ponto heat at a greater rate than others
Greenhouse gases have higher thermal retention properties:
Carbon dioxide
Methane
Water vapor
Nitrous oxide
CFCs
9.4 — Increases in the Greenhouse Gases
Rising sea levels and flooding
Melting of polar ice caps, ice sheets, permafrost, and glaciers, shoreline erosion
Temperature of earth’s ocean increases → water expands
Spread of disease vectors
Diseases previously confined to the tropics spread to the poles: temperatures increase → disease vectors like mosquitos and ticks can survive and reproduce in areas they previously couldn’t
Warmer temperatures → ranges of host species can shift, bringing them in contact with new populations and allowing for more disease transmission
Warmer temperatures → changes in distribution and abundance of certain species, disrupting balance of ecosystems and increasing risks of disease outbreaks due to population density impacts
Ocean acidification:
Increased CO2 from burning of fossil fuels → absorbed in oceans → increases concentration of dissolved CO2 → decreases pH of the ocean, making it more acidic
Reduces access to calcium, impacting the ability of some marine organisms to build and maintain their shells and skeletons
Extreme weather events and changing weather patterns
Increased global temperatures → changes in atmospheric and ocean circulation patterns → affects occurrence of extreme weather events
Loss of biodiversity
Changes the range of species, leading to species displacement as a pursuit of finding more suitable habits
If suitable habits are not available or if they can’t migrate/evolve quickly enough, they can become extinct
Impacts the availability of water, severity of natural disasters, spread of diseases
9.5 — Global Climate Change
Heating and cooling climate cycles
Earth naturally warms and cools over thousands of years
Scientists study ice cores (in antarctica) to track past CO2 levels
Air bubbles in ice = “time capsules” of ancient atmosphere
Higher CO2 in bubbles = warmer climate in that area
Earth moves heat from the equator to the poles using air currents and ocean currents that help keep the climate stable
Climate change disrupts these currents leading to stronger storms, hotter weather, colder weather, more unpredictable weather
Positive feedback loops at the poles:
Melting ice and snow → less solar radiation reflected and more solar radiation absorbed → poles warming even faster = POSITIVE FEEDBACK LOOP FOR WARMING
Positive feedback loops causes
Rising sea levels
Loss of habitat (polar bears, seals, etc.)
Thawing permafrost → methane released → more warming
Rising sea + marine impacts
Melting ice → more volume to oceans → flooding in coastal cities
Sea levels make species gain habitat (flooded shelves) and others lose habitat (sunlight no longer reaches deeper water = no photosynthesis)
9.6 — Ocean Warming
Climate change in the oceans
Ectotherms (fish, amphibians, reptiles, invertebrates) depend on external sources of heat for body temperature: meaning that body temperature of an aquatic ectotherm is very close to temp of surrounding water
Warmer ocean waters → organisms facing metabolic stress and can lose ability to metabolize their food/reproduce
Impacts on coral:
Coral has symbiotic relationship with algae (zooxanthellae): algae have stable habitat and nutrients → provides coral with sugar
Algae in coral are sensitive to temperature and cannot live in warmer water → when algae die and are expelled, coral turns white/bleaches → cannot recover
Melting of sea ice → destroys polar habitats and changes habitats globally with sea-level rise and changes to currents
9.7 — Ocean Acidification
Acid formation ^^
Ocean acidification: caused by absorption of excess atmospheric CO2 into the ocean, lowering pH levels
Due to 200 years of global industrialization, ocean pH levels have dropped by 0.1 pH units (30% increase in ocean acidity levels)
Calcium Carbonate
CO2 + sea water → carbonic acid → reduction of pH in water → reduces available calcium carbonate in the ocean (needed to help build skeleton/shells of marine organisms)
Calcium carbonate used to control internal pH and reglate the number of calcium ions in their bodies
Fish physiology (behavior + physiology) is disrupted through acidification, making it difficult for them to interact with stimuli in their external environment
Aquatic plants thrive in a CO2 rich environment, so an excess of CO2 can create eutrophication heavy environment
Pteropods — small pelagic snails that make up the basis for the food chain for a wide variety of animals
Current predicated acidity levels would dissolve their shells and lead to the collapse of their species, creating a domino effect on the rest of the organisms that rely on it
9.8 — Invasive Species
Invasive species: Species that can live, and thrive, outside of their normal habitats
Can sometimes be beneficial but are considered invasive when they threaten native species
Often generalists, r-selected species, and therefore may outcompete native species for resources
Can be controlled through a variety of human interventions
Physical removal: manually removing individuals/entire populations of invasive species
hand-pulling, cutting, digging, and trapping
Chemical control: pesticides and other chemicals killing/inhibiting the growth of invasive species
Biological control: using natural predators, pathogens, or competitors of the invasive species to reduce its population
Habit modification: altering environment to make it less suitable for invasive species and more suitable for native species
Monitoring and early detection: regularly monitoring new invasive species and taking action as soon as they are detected
Public education/outreach: educating public about negative impacts of invasive species and encouraging them to take action to prevent the spread of the species
Prevention: most effective and cost-efficient strategy for controlling invasive species (strict quarantine regulations, inspections of cargo/vehicles, and regulations on import/trade of live organisms)
9.9 — Endangered Species
Endemic species — species that exist in a specific area and nowhere else in the world
Have limited range, high habitat, or resource specificity, and low abundance
Classification: any organism can become endangered and are classified by the International Union for Conservation of Nature (IUCN) into the following categories:
Extinct (EX) — These species no longer exist and have become extinct
Extinct in the wild (EW) — survives only in captivity, cultivation, and/or outside the native range, as presumed after exhaustive surveys
Critically endangered (CR) — these species are at an extremely high risk of extinction in the wild and their population is declining at an alarming rate
Endangered (EN) — species at a very high risk of extinction in the wild and their population is declining rapidly
Vulnerable (VU) — meets one of the 5 red list criteria and thus considered to be at high risk of unnatural (human-caused) extinction without further human intervention
Near threatened (NT) — species at risk of becoming endangered in the near future
Least concern (LC) — these species are considered to have a low risk of extinction and are not considered endnagered
IUCN’s 5 criteria to classify organisms and assess conservation status:
Reduction in population (decreased significantly)
Geographic range (restricted)
Population size (less than 2500 mature individuals)
Extremely small population size (less than 250 mature individuals)
Probability of extinction (analysis that shows the species becoming extinct in the wild at least 20% within 20 years or 5 generations)
Risk Factors:
How fast species reproduce
R-species: reproduces quickly → most babies don’t survive but the species bounces back fast → less risk of extinction
K-species: reproduces slowly → babies more likely to survive but takes longer to recover if numbers drop → more risk of extinction
How well species adapt to change
Specialists: live in a small range of tolerance → don’t adapt well to change → high extinction risk
Generalists: wide range of tolerance → adapts to change better → lower extinction risks
Overharvesting: when individuals are removed from a population at a rate faster than the population can replace them → leads to population declines and extinction
Regulations like hunting/fishing restrictions can help overharvesting but in some areas, regulations are not strongly enforced, leading to illegal poaching
Plant/animal trade: represents a serious threat to the persistence of some species
Lacey Act and Convention on International Trade in Endangered Species of Wild Fauna and Flora (CITES): developed to control and regulate the trade of threatened and endangered plants and animals
Endangered species act: federal law in the US that aims to protect and recover species in danger of extinction throughout all or a significant portion of their range
Administered by the US Fish and Wildlife Service and the National Oceanic and Atmospheric Administration (NOAA) → one of the strongest laws in the world for protecting endangered and threatened species
Designation of “critical habitat” - species areas that are essential for the conservation of the species, as well as the prohibition of harming the listed species and their trade, including their fur or body parts
Can restrict certain human activities in areas where listed species live, including how landowners use their land, but had significant success in protecting and recovering endangered and threatened species
Breeding programs + other organizations:
Institutions (zoos, aquariums, NGOs, research institutions) can serve as education centers while also using animals in breeding programs to rebuild populations of critically endangered species
9.10 — Human Impacts on Biodiversity
Human population growth → more land needed for housing, agriculture, industry → destructions of natural habitats and displacement of native species
Leads to pollution, overconsumption of resources, and introduction of invasive species, climate change, overfishing, pollution also contribute to loss of biodiversity
HIPPCO (Habitat destruction, Invasive species, Population growth, Pollution, Climate change, and over Exploitation) — major factors causing a decrease in biodiversity
Habitat destruction: Destruction, fragmentation, or degradation of natural habitats, making it difficult for species to live
Caused by urban development, agriculture, and logging
Leads to soil erosion, loss of biodiversity, and destruction of indigenous peoples’ ways of life
Invasive species: non-native species that are introduced and are causing harm to native species
Outcompetes native species for resources and spreads diseases
Disrupts the ecological balance of the region
Population growth: increased in human activities that harm wildlife and their habitats, such as urbanization and resource extraction
Destruction of natural habitats, habitat fragmentation, overuse of resources
Pollution: release of chemicals, plastic debris, and other harmful pollutants
Impacts different organisms, tourisms, recreation, other activities
Impacts human health
Climate change: changes in temperature, precipitation, and other weather patterns that can make it difficult for species to survive
Affects migration patterns, reproduction, and other aspects of animal behavior
Overexploitation: overuse of natural resources, including the overharvesting of wild animals and plants
Leads to population declines + endangerments
Conservation: protecting/managing genetic diversity within species
Preserving habitats, protecting/managing genetic diversity, promoting sustainable use of natural resources, addressing impacts of climate change
In-situ conservation — restoring habitats and establishing protected areas
Ex-situ conservation — protective custody and captive breeding