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Polar and Non-polar Molecules

Page 1:

  • The physical properties of a substance are dictated by whether or not a molecule is polar

  • Examples of polar and nonpolar molecules are given in Model 1

  • A polar bond is indicated by one circle being blank, while a nonpolar bond has both circles colored

Page 2:

  • Formaldehyde (CH2O) is trigonal planar

  • The shape of a molecule cannot explain polarity, as molecules of all shapes can be polar or nonpolar

  • Nonpolar molecules may contain polar bonds, while polar molecules always contain polar bonds

  • The presence or absence of a lone pair of electrons can explain the polarity of molecules

Page 3:

  • In a nonpolar molecule, polar bonds are arranged on opposite sides, while in a polar molecule, polar bonds are on the same side

  • In a nonpolar molecule, lone pairs of electrons are on opposite sides, while in a polar molecule, lone pairs of electrons are on the same side

  • Nonpolar molecules are symmetric about multiple planes of symmetry

Page 4:

  • Polar molecules have an unequal distribution of charge, caused by polar bonds or lone pairs of electrons

  • The angle between two polar bonds in a molecule needs to be 180 degrees for the molecule to be nonpolar

  • The angle between any of the four polar bonds in a molecule needs to be 109.5 degrees for the molecule to be nonpolar

  • If a molecule contains only one polar bond and no lone pairs, it cannot be made nonpolar

Page 5:

  • The table is filled in to determine if each molecule is polar or nonpolar

  • The three-dimensional structures of each molecule are drawn

  • Carbon tetrafluoride (CF4) is nonpolar

  • Water (H2O) and sulfur dioxide (SO2) are polar

  • Phosphorous pentachloride (PCl5) and hydrogen sulfide (H2S) are also polar

Page 5:

  • The polarity of a molecule can be quantified as the dipole moment.

    • Dipole moment is measured in debyes.

  • The abbreviation for the unit "debye" is D.

  • NH3 is the most polar molecule according to the given dipole moments.

  • Possible explanations for the changes in dipole moments between the three molecules should be discussed.

  • Polar bonds in Model 2 can be determined using a table of electronegativity values.

    • A large difference in electronegativity is characteristic of a polar bond.

  • Arrows should be drawn next to significantly polar bonds in Model 2 to show the direction of polarity.

  • Lone pairs in a molecule also provide a dipole, and arrows should be drawn pointing away from the center atom for any lone pairs in Model 2.

Page 6:

  • NH3 is the most polar molecule because there is a high concentration of negative charge in the center atom.

  • NF3 is the least polar molecule because all the arrows point out, balancing each other.

  • The phosphorus trifluoride molecule (PF3) has a larger dipole moment (1.03 D) compared to the nitrogen trifluoride molecule in Model 2.

    • The larger dipole moment could be due to a difference in electronegativity.

  • The molecules should be ranked in order of polarity from least to most, using arrows on each molecule to support the answer.

  • CS2 has a larger dipole moment compared to SO2 because of the presence of polar bonds and asymmetrical structure.

  • SF6 has a greater dipole moment compared to CF4 because of the greater concentration of lone electron