_Unit 7 Smedes APES Note Slides (22-23)
Introduction to Air Pollution
Overview
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Suggested Skill: Experimental Modifications
Skill 4.E
Explain modifications to an experimental procedure that will alter results.
Learning Objectives and Essential Knowledge
Objective: Identify Sources and Effects of Air Pollutants
STB-2.A
STB-2.A.1: Coal combustion releases pollutants:
Carbon dioxide (CO2)
Sulfur dioxide (SO2)
Toxic metals (e.g., mercury, arsenic)
Particulates
STB-2.A.2: Combustion of fossil fuels releases:
Nitrogen oxides (NO & NO2) - leads to photochemical smog and acid rain.
Other pollutants include carbon monoxide (CO) and particulates.
STB-2.A.3: Air quality affected by sulfur dioxide from burning diesel fuels.
STB-2.A.4: Clean Air Act reduced atmospheric lead levels, particularly from fuels.
STB-2.A.5: Distinction between primary (direct emissions) and secondary (transformation of primary pollutants) pollutants.
Basics of Air Pollution
Key Pollutants
Coal combustion impacts: respiratory irritants, smog, acid precipitation.
Combustion of fossil fuels (FF) and biomass leads to:
SO2, nitrogen oxides (NOx), carbon monoxide (CO), particulate matter (PM).
Clean Air Act identifies six criteria air pollutants requiring regulation by the EPA.
Air Pollutants vs. Greenhouse Gases
CO2 Distinctions
Not a criteria pollutant under Clean Air Act despite EPA’s ability to regulate it post-2007 SC ruling.
CO2 does not directly impair air quality or human health from a toxicity standpoint but has environmental impacts due to greenhouse effect.
Impact of Coal Combustion
Coal as a Power Source
Accounts for ~35% of global electricity production.
Releases various pollutants including:
CO, CO2, SO2, NOx, toxic metals, PM.
Major impacts of SO2:
Respiratory irritant, worsens asthma, forms sulfurous smog, and acid precipitation.
Nitrogen Oxides (NOx)
Release Sources
Produced from combustion processes, especially fossil fuels and biomass.
Forms when nitrogen in the atmosphere combines with oxygen.
Contributes to ozone formation and acid rain.
EPA Regulations on Lead
Lead Phaseout
Lead was common in gasoline but phased out by EPA in 1974.
Vehicles made post-1974 require catalytic converters, reducing NOx, CO, and hydrocarbon emissions.
Primary vs. Secondary Air Pollutants
Definitions
Primary pollutants: emitted directly (e.g., CO, NOx).
Secondary pollutants: formed from reactions in sunlight, water, and O2 (e.g., tropospheric ozone).
Photochemical Smog
Formation of Photochemical Smog
Learning Objective: Causes and Effects
Produced through reactions of NOx and VOCs under sunlight.
Formation occurs more prominently in urban areas.
Environmental Factors
Key Influencers: direct sunlight, heat, and urban traffic contribute to higher levels of photochemical smog, especially in the afternoon.
Health Impacts
Human Risks
Causes respiratory issues, eye irritation, and other health problems.
Thermal Inversion
Concept and Effects
Definition
The normal temperature gradient is altered, trapping pollutants close to the ground. Impacts include:
Pollution Concentration
Human Health
Increased respiratory problems and economic impacts due to lower tourism and photosynthesis inhibition.
Natural Sources of CO2 and PM
Natural Contributions
CO2 Origins
Releases from respiration, decomposition, volcanic eruptions.
Particulate matter from pollen, sea salt, and forest fires.
Indoor Air Pollutants
Types of Pollutants
Common Pollutants
Carbon monoxide, asbestos, dust, radon, VOCs.
Sources range from combustion, materials used in construction, to human activity.
Health Implications
Lead Effects
Damages nervous systems, particularly in children. Measures to reduce exposure involve replacing lead-based paints and pipes.
Reduction of Air Pollutants
Mitigation Strategies
Objective: Explaining Reduction Methods
Include regulatory practices, alternative fuels, and conservation practices.
Use of technologies like catalytic converters, vapor recovery nozzles, and scrubbers.
EPA Initiatives
Clean Air Act Policies
Allows for regulation of emissions and establishes standards to improve air quality.
Acid Rain
Formation and Sources
Cause
Formed from NOx and SO2 emissions. These originate mainly from vehicle emissions and coal-burning power plants.
Effects
Environmental Impact
Acidification of soil and water bodies, corrosion of structures, and regional ecological effects.
Noise Pollution
Urban Noise Sources
Key Contributors
Construction, transportation, industrial activity often exceed sound levels that can cause stress and health issues.
Wildlife Effects
Impact on Ecology
Noise pollution has physiological effects on animals and can disrupt communication, breeding, and migration.