Quantum Theory and the Electronic Structure of Atoms
1. Fundamental Concepts of Energy
Energy: Capacity to do work or transfer heat.
Kinetic Energy: Energy of motion (e.g., thermal energy).
Potential Energy: Energy due to position or composition (e.g., chemical, electrostatic).
Electrostatic Energy (E{el}): From charged particle interaction (E{el} \propto \frac{Q1Q2}{d}).
Like charges repel (potential energy increases as they get closer).
Unlike charges attract (potential energy decreases as they get closer).
Law of Conservation of Energy: Energy cannot be created or destroyed, only converted.
2. Unraveling Atomic Structure through Light
Electron arrangement discovery was influenced by studying light emission by atoms.
2.1 Characteristics of Light Energy (Electromagnetic Radiation)
Light was historically seen as a wave.
Wavelength (\lambda): Distance between wave peaks/troughs.
Frequency (\nu): Number of cycles per second.
Amplitude: Relates to light intensity.
Speed of Light (c): All EM waves travel at c = 3.00 \times 10^8 \text{ m/s} in a vacuum (c = \lambda\nu).
Young's Double Slit Experiment: Showed light's wave nature via interference patterns.
Electromagnetic Spectrum: Continuous range of EM radiation, from radio waves (longest \\lambda) to gamma rays (shortest \\lambda).
3. The Quantum Revolution: Challenging Wave Theory
3.1 Blackbody Radiation and Planck's Quantum Hypothesis
Classical wave theory failed to explain blackbody radiation.
Blackbody: An ideal object that absorbs all radiation and emits light based only on its temperature.
The Blackbody Problem: Classical physics incorrectly predicted infinite energy emission at short wavelengths.