Quantum Theory and the Electronic Structure of Atoms

1. Fundamental Concepts of Energy
  • Energy: Capacity to do work or transfer heat.

    • Kinetic Energy: Energy of motion (e.g., thermal energy).

    • Potential Energy: Energy due to position or composition (e.g., chemical, electrostatic).

    • Electrostatic Energy (E{el}): From charged particle interaction (E{el} \propto \frac{Q1Q2}{d}).

      • Like charges repel (potential energy increases as they get closer).

      • Unlike charges attract (potential energy decreases as they get closer).

  • Law of Conservation of Energy: Energy cannot be created or destroyed, only converted.

2. Unraveling Atomic Structure through Light
  • Electron arrangement discovery was influenced by studying light emission by atoms.

2.1 Characteristics of Light Energy (Electromagnetic Radiation)
  • Light was historically seen as a wave.

    • Wavelength (\lambda): Distance between wave peaks/troughs.

    • Frequency (\nu): Number of cycles per second.

    • Amplitude: Relates to light intensity.

    • Speed of Light (c): All EM waves travel at c = 3.00 \times 10^8 \text{ m/s} in a vacuum (c = \lambda\nu).

  • Young's Double Slit Experiment: Showed light's wave nature via interference patterns.

  • Electromagnetic Spectrum: Continuous range of EM radiation, from radio waves (longest \\lambda) to gamma rays (shortest \\lambda).

3. The Quantum Revolution: Challenging Wave Theory
3.1 Blackbody Radiation and Planck's Quantum Hypothesis
  • Classical wave theory failed to explain blackbody radiation.

    • Blackbody: An ideal object that absorbs all radiation and emits light based only on its temperature.

    • The Blackbody Problem: Classical physics incorrectly predicted infinite energy emission at short wavelengths.