chapter 2 lecture

Coral Reefs and Environmental Chemistry

  • Exploration of the relationship between rising atmospheric carbon dioxide and coral reefs.

    • Will rising atmospheric carbon dioxide harm coral reefs?

Major Themes of the Chapter

  • Understanding core concepts that will be explained in detail throughout the chapter:

    • Elements, Atoms, and Compounds:

    • Definition of essential terms (elements, atoms, compounds).

    • Subatomic Particles:

    • Protons, Neutrons, Electrons: Charge specifications for each:

      • Protons: Positively charged.

      • Neutrons: Neutral charge.

      • Electrons: Negatively charged.

    • The arrangement of subatomic particles in atoms and their roles in forming compounds.

    • Chemical Bonds:

    • Types of chemical bonds:

      • Covalent Bonds: Shared pairs of electrons between atoms.

      • Ionic Bonds: Transfer of electrons from one atom to another, leading to attraction between oppositely charged ions.

      • Hydrogen Bonds: The weakest bond, involving a hydrogen atom that is covalently bonded to an electronegative atom.

    • Water:

    • Importance of water as a life-supporting molecule.

    • Structure and shape of water molecules (V-shaped).

Elements, Atoms, and Compounds

  • Chemical Composition:

    • Chemicals are the raw materials for all living and non-living organisms.

    • Matter is defined as anything that occupies space and has mass (weight).

    • Elements:

    • Definition: Fundamental substances that cannot be broken down into simpler substances by chemical means.

    • Natural elements discovered: approximately 92, but only a few exist in pure form.

    • Four key elements in the human body: Oxygen, Carbon, Hydrogen, Nitrogen (96.3% of body mass).

    • Discussion of trace elements (e.g., Iron, Iodine, Fluoride) which are crucial for health in minute quantities (example: Iron deficiency leading to anemia, Iodine deficiency leading to goiter).

Definition and Importance of Compounds

  • Compounds:

    • Definition: A substance formed when two or more different elements combine in fixed ratios (e.g., sodium chloride, NaCl, formed from sodium and chlorine).

    • Compounds are more prevalent than pure elements in nature.

    • Essential to recognize key compounds discussed in class for exams.

The Atom: Structure and Calculations

  • Atoms:

    • Smallest units of matter that retain the properties of an element.

    • Structure includes:

    • Nucleus: Contains protons and neutrons.

    • Electrons orbiting the nucleus, held in place by the positive charge of protons.

    • Calculating Atomic Numbers and Mass Numbers:

    • Atomic Number = Number of Protons

    • Mass Number = Sum of Protons and Neutrons.

    • Example calculation: Atom with 2 protons and 2 neutrons has an Atomic Number of 2 and a Mass Number of 4.

Isotopes and Radioactive Isotopes

  • Isotopes:

    • Atoms with the same number of protons but different mass numbers due to varying numbers of neutrons.

    • Example with Carbon isotopes: Carbon-12, Carbon-13, and Carbon-14.

  • Radioactive Isotopes:

    • Definition: Isotopes that decay spontaneously, emitting particles and energy.

    • Applications in medicine: Used in PET scans for diagnostic imaging.

    • Ethical implications of radioactivity due to potential harm from uncontrolled exposure (e.g., damage to DNA).

Chemical Bonding

  • Chemical Activity:

    • Involves the outermost electrons or valence electrons of atoms.

    • Types of Bonds:

    • Covalent Bonding (strongest): Sharing of electrons.

      • Examples: H₂ (hydrogen molecule) and O₂ (oxygen molecule) forming bonds for full outer shells.

    • Ionic Bonding: Transfer of electrons (Sodium giving away an electron to Chlorine to form NaCl).

    • Hydrogen Bonds (weakest): Important for water molecules, enabling properties of cohesion and adhesion.

Properties of Water

  • Water as a Fundamental Molecule:

    • Water's unique V-shaped structure contributes to its properties.

    • Cohesion and Adhesion:

    • Cohesion: Attraction between like molecules.

    • Adhesion: Attraction between different types of molecules.

    • Water exhibits high surface tension due to hydrogen bonding.

  • Thermal Properties:

    • Heat capacity due to hydrogen bonds, moderating Earth's climate.

    • Evaporative Cooling: The phenomenon where the surface of the liquid cools as the molecules with the greatest kinetic energy escape into the gas phase.

Chemical Reactions and Equations

  • Chemical Reactions:

    • Rearrangement of atoms in reactants to form products (Law of conservation of mass).

    • Example: Photosynthesis as a fundamental biochemical reaction.

  • Reactants and Products Defined:

    • Reactants are the starting materials, and products are the formed substances after the reaction.

The Role of Carbon Dioxide in Climate Change

  • Global Climate Change:

    • Carbon dioxide (CO₂) as a primary product of fossil fuel combustion.

    • High levels linked to ocean acidification, affecting coral reefs.

  • Ocean acidification leads to impacts on marine life, particularly organisms that build shells (e.g., corals).

  • Importance of maintaining healthy ecosystems for biodiversity.

Conclusion

  • This chapter has provided a comprehensive introduction to key principles of chemistry relevant to biology, particularly focusing on the crucial role of water and the implications of environmental changes such as increased carbon dioxide levels.