Hematology and Coagulopathy Platelets and Coagulation Components Platelet Thrombin Antithrombin Heparin Active Sequence End Point Covalent Bond Attached Heparin Molecule Prime Coat Device Surface Neutral AT-Thrombin Complex Objectives Describe the hemostatic system. Discuss how artificial surfaces disrupt balance. Describe how artificial surfaces can cause bleeding. Discuss methods to blunt hemostatic and inflammatory response. References: Gravlee, Ghosh, Hensley, InternetIntroduction This unit describes how artificial surfaces disrupt the balance associated with bleeding and hemostasis. Relation to inflammatory response is significant in understanding these disruptions. Hemostasis in Different Systems Arterial System: High pressure operation Rapid blood loss typically occurs Platelets dominate the hemostatic processes (where nitric oxide inhibits platelets) Venous System: Low pressure operation Diminished blood flow rate Thrombin dominates (where t-PA inhibits thrombin) Impact of CPB (Cardiopulmonary Bypass) Alters hemostatic balance leading to arterial and venous bleeding Platelet Defects During CPB Decreased Platelet Counts: Platelet counts typically decrease by 30% to 50% during CPB. Transfusion threshold is significant if platelet counts dip below 50,000/µl. Hemodilution with Crystalloid Solutions: Results in decreased platelet counts. Adhesion to CPB Circuit: Fibrinogen (I) & von Willebrand factor (vWF) adhere to circuit surfaces, activating platelets. Platelets degranulate under the influence of shear stress and hypothermia. The heparin used binds to platelet surfaces and vWF, causing alpha granule degranulation (which includes proteins like GPIIb/IIIa, fibrinogen, vWF). Microscopic Examination: Observations show a heterogeneous mixture of discoid and shape-changed platelets alongside degranulated platelets. Goals of Platelet Activation Recruitment of additional platelets to the site of injury. Vasoconstriction of smaller arteries to minimize blood loss. Localized release of ligands essential for stable platelet-platelet matrix. Localization and acceleration of fibrin formation associated with platelets. Protection of clot from fibrinolysis. Coagulation Cascade and Cardiac Surgery Activation Process: Extrinsic pathway is activated first during cardiac surgery and CPB, followed by the intrinsic pathway. The common pathway activation by Factor Xa initiates the amplification phase of coagulation. Effects of Bypass/Surgery on Coagulation CPB activates both intrinsic and extrinsic pathways depending on the surface characteristics (negatively charged surfaces activate intrinsic pathway). Influencing Factors: Coronary suction introduces tissue factor from damaged cells activating extrinsic pathways. Platelet activation occurs due to contact with surfaces, and intrinsic and extrinsic pathways are both stimulated. Hemostatic Factors Factors affecting hemostasis during CPB include:Hemodilution (leads to loss of clotting factors and platelets). Hypothermia (impairs platelet function). Blood management from pericardial sources. Broken balance in coagulation processes and potential for fibrinolysis. Trauma and resultant blood loss can contribute significantly to transfusion requirements. Despotis GJ et al, Anesthesiology 1999; 91: 1122-51 HEMODILUTION: Result of CPB prime using crystalloids or colloids. Use of extensive cell salvage systems is relevant for platelet and factor loss. **ACTIVATION: ** Contact activation leads to intrinsic activation (e.g., XIIa, Kallikrein). Tissue factor activated via injury and monocyte interaction. Fibrinolysis activated via increased tPA (from endothelial cells or pericardial cavity) and intrinsic pathways. CONSUMPTION: Mediated by thrombin, plasmin, and inflammatory agents (e.g., elastase, complement, leukocyte-platelet complexes). Mechanical disruptions due to ECC (e.g., oxygenator, cardiotomy suction) also contribute to consumption. Causes of Bleeding Disorders Liver Diseases: (e.g., Cirrhosis, hepatitis, cancer)Vitamin K Deficiencies: Affects coagulation factors II, VII, IX, X (all dependent on Vitamin K). Genetic Disorders: Hemophilia A: deficiency of factor VIII.Hemophilia B: deficiency of factor IX.Von Willebrand Disease: deficiency of VWF.Platelet Disorders: involve defects in platelet receptors.Treatment Options: Replacement therapy using purified factors, recombinant technology, FFP, or platelets. Artificial Surfaces Recognized as foreign by blood components, leading to:Activation of hemostatic elements for clotting. Inflammatory responses attempting to reject the artificial surface. Ideal approach involves managing coagulation and inflammation systems during exposure to foreign surfaces. Heparin Characteristics Mechanism of Action: Potentiates Anti-Thrombin III (AT-III) activity by approximately 1000-fold. AT-III inhibits thrombin (IIa) and Factor Xa (also IXa, XIa, XIIa to a lesser degree). Goal of Anticoagulation: Primarily focused on thrombin inhibition. Interaction with Artificial Surfaces Blood elements interaction activates:Plasma proteolytic systems, coagulation system, fibrinolysis, complement cascade, and contact system (intrinsic pathway). The continuous interaction leads to damage of blood cells/proteins and promotes inflammatory cytokine release. Advances in surface coatings aim at reducing these adverse effects while maintaining biocompatibility and protein conservation. New Coating Techniques Polymer Strain Development: Used in medical tubing through polymerization of monomers. Design encourages reduced protein contact through hydrophobic backbone and mild hydrophilic pendant groups. Biocompatibility Advantages: Coatings exhibit clear performance benefits through in vitro and ex vivo testing: Blocks platelet adhesion and clot activation factors. Reduces protein denaturation and cell attachment in oxygenators and circuits. Biological Response to Implanted Materials in Blood Material surface impacts include:Protein adsorption Platelet adhesion Fibrin and thrombus formation Interaction of red blood cells and fibrin with platelets. Coating Technology Historical Overview 1250 A.D.: Recognized properties of surface preparations for bonding. 18th Century Contributions: Surface-induced catalysis. 1922: Theory pertaining to protein and colloidal behavior. 1946: Development of molecular films and biological implications. 1963: Introduction of heparin surface coating. Non-Heparin Based Coatings Smart Coatings: (e.g., Phosphorylcholine - SMA)Softline Coatings: (e.g., Jostra)Xcoating: (e.g., PMEA - Terumo)Polymethoxyethylacrylate (PMEA) Functionality: Forms a hydro layer impacting blood exposure to device surfaces. Minimizes platelet adhesion and enhances overall compatibility. Heparin-Immobilized Surfaces Characteristics: Biocompatible and non-leaching with FDA clearance. Bi-polymer coating facilitates heparin bonding to surfaces. Current Coating Technologies Heparin Polymer Coatings: e.g., Hyaluronan-based, human albumin-based, polyethylene oxide-based bonding from different biomedical companies. Trillium Biosurface Features Hydrophilic, negatively charged surface with heparin: Enhancements include: Non-leaching heparin molecules Incorporation of sulfate/sulfonate groups to mimic vascular endothelial charge. Hydrophilicity via Polyethylene oxide (PEO) creating a significant water layer. Benefits of Heparin-Coated Circuits Improved biocompatibility with decreased inflammatory response. Thrombogenesis concerns, requiring maintained systemic heparinization to avoid complications. Hyaluronan Overview 1-10% of cartilage glycosaminoglycans is hyaluronan. Present in multiple body tissues, known for unique lubricious physical/chemical properties. Medical applications include improving joint function and potential drug delivery mechanisms. Rheological Properties of Hyaluronan Features unique behavior in solution due to its expansive polymer structure, enhancing lubricity and preventing adhesion formation post-surgery. Medical Applications of Hyaluronan Used in ophthalmic surgery, as an injectable for arthritis, and innovative drug release applications. Cross-linked gels acting as adhesion prevention post-surgery and enhancing device coatings. Hyaluronan-Based Heparin Bonded Circuits (GBS® Coating) Characterized by covalent bonding and preservation of biological elements. Promotes reduced inflammation and enhances cell health around implants. Evaluation Parameters in CPB Biochemical Analysis: Integration of standard blood tests, interleukin levels, and assessments of biocompatibility.Hemodynamic Monitoring: Key indicators including heart rate (HR), mean arterial pressure (MAP), cardiac output (CO), various blood gas analyses.Results of Studies and Observations Microscopy: Demonstrated less platelet adhesion and improved surface structure in coated circuits versus uncoated. Evidence shows that uncoated surfaces lead to protein adsorption indicating less favorable biocompatibility. Hematologic Data from Clinical Trials Results showcase variations in white blood cell count, platelet counts, fibrinogen levels, and C3a levels based on CPB conditions across coated and uncoated conditions throughout the trials. Conclusions and Considerations Solution to hemolytic and inflammatory responses associated with artificial surfaces is multi-faceted and includes:Pharmacological interventions Circuit modifications & reductions in surface exposure Enhanced surgical techniques fostering better outcomes. The necessity for collaboration among specialists to reconcile the complexities of artificial surface interactions with the hemostatic and inflammatory responses in clinical settings. Final Note: Happy Hunting! Knowt Play Call Kai