21. States of Matter & Changing State

1. The Three States of Matter

State

Arrangement & Forces

Movement & Shape

Solid

Strong forces of attraction hold particles close together in a fixed, regular lattice structure.

Particles vibrate in fixed positions. They keep a definite shape and volume; they cannot flow.

Liquid

Weak forces of attraction. Particles are randomly arranged but tend to stay close and compact.

Particles are free to move around each other. They have a definite volume but no fixed shape (they flow to fit a container).

Gas

Very weak forces of attraction between particles. Particles are far apart.

Particles move quickly and in straight lines in any direction. They have no definite shape or volume and fill their container.


2. Changing State

Changes of state occur when energy is added or removed, affecting the forces between particles:

  • Melting (Solid to Liquid): Heating a solid gives particles energy to vibrate more. At the melting point, they gain enough energy to break free from their fixed positions.

  • Boiling/Evaporating (Liquid to Gas): Heating a liquid makes particles move faster. At the boiling point, they gain enough energy to break the bonds holding them together entirely.

  • Condensing (Gas to Liquid): Cooling a gas reduces particle energy. They move slower, and forces of attraction begin to pull them together into a liquid.

  • Freezing (Liquid to Solid): Cooling a liquid further reduces energy until the particles move so slowly that more bonds form, fixing them in a solid lattice.


3. Limitations of Particle Theory

While useful, the simple "sphere" model of particles has limitations:

  • In reality, particles are not solid, inelastic spheres; they are complex atoms, ions, or molecules.

  • The model does not detail the specific strength or number of forces between particles.