Equilibrium

Chemical equilibrium

  • There are 2 conditions for equilbrium to be established for a certain reaction:

    1. Forward and backward reaction occur at the same rate.

    2. The concentration of reactants and products remain constant.

  • Equilibrium can only happen in a closed system, where the reactants and/or products do not come in contact with the surroundings.

  • Equilibrium is dynamic, meaning that at a microscopic level, the reaction does not stop as the reactants are continuously changed to products and the products are continuously changed to the reactants. However, at a macroscopic level, there is no change in the properties such as pressure, colour, pH, or concentration.

Physical Equilibrium

  • Physical equilibrium does not involve a chemical reaction, rather a change in the state, for example from liquid to gas and gas to liquid.

  • Even for this type of equilibrium, similar conditions apply:

    1. The rate of forward process is equal to the rate of backward process.

    2. The volume of liquid remains constant.

  • Equilibrium can only occur in a closed system.

  • Similiar to chemical equilibrium, the equilibrium is dynamic at a microscopic level where the liquid is getting continuously evaporated and the gas is getting continuously condensed, but at a macroscopic level the properties remain the same, such as color.