Inorganic Compounds and Color

Introduction

  • The human eye perceives a mixture of all the colors, in the proportions present in sunlight, as white light.
  • Complementary colors, those located across from each other on a color wheel, are also used in color vision.
    • The eye perceives a mixture of two complementary colors, in the proper proportions, as white light.
  • Likewise, when a color is missing from white light, the eye sees its complement.
    • For example, when red photons are absorbed from white light, the eyes see the color green.
    • When violet photons are removed from white light, the eyes see lemon yellow
  • An object is black if it absorbs all colors of light.
  • An object is white if it reflects all colors of light
  • An object has a color if it absorbs all colors except one

Transition Metals

  • The blue color of the [Cu(NH3)4]2+ ion results because this ion absorbs orange and red light, leaving the complementary colors of blue and green. 
  • If white light (ordinary sunlight, for example) passes through [Cu(NH3)4]SO4 solution, some wavelengths in the light are absorbed by the solution.
  • The [Cu(NH3)4]2+ ions in solution absorb light in the red region of the spectrum.
  • The light which passes through the solution and out the other side will have all the colors in it except for the red.
  • We see this mixture of wavelengths as pale blue (cyan).
  • The partially filled d orbitals of the stable ions Cr3+(aq), Fe3+(aq), and Co2+(aq) give rise to various colors.
  • Non-transition metal ions in water: appear clear/transparent
  • Transition metal ions in water: produces various colors

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