Inorganic Compounds and Color
Introduction
- The human eye perceives a mixture of all the colors, in the proportions present in sunlight, as white light.
- Complementary colors, those located across from each other on a color wheel, are also used in color vision.
- The eye perceives a mixture of two complementary colors, in the proper proportions, as white light.
- Likewise, when a color is missing from white light, the eye sees its complement.
- For example, when red photons are absorbed from white light, the eyes see the color green.
- When violet photons are removed from white light, the eyes see lemon yellow
- An object is black if it absorbs all colors of light.
- An object is white if it reflects all colors of light
- An object has a color if it absorbs all colors except one
Transition Metals
- The blue color of the [Cu(NH3)4]2+ ion results because this ion absorbs orange and red light, leaving the complementary colors of blue and green.
- If white light (ordinary sunlight, for example) passes through [Cu(NH3)4]SO4 solution, some wavelengths in the light are absorbed by the solution.
- The [Cu(NH3)4]2+ ions in solution absorb light in the red region of the spectrum.
- The light which passes through the solution and out the other side will have all the colors in it except for the red.
- We see this mixture of wavelengths as pale blue (cyan).
- The partially filled d orbitals of the stable ions Cr3+(aq), Fe3+(aq), and Co2+(aq) give rise to various colors.
- Non-transition metal ions in water: appear clear/transparent
- Transition metal ions in water: produces various colors
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