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Unit 8 Cellular Energetics

Photosynthesis

I. Autotrophs – Organisms that can “produce” their own food. (“Auto” means “self”; “trophe”

means “feeding”)

II. Heterotrophs – Organisms that “consume” other organisms (living or dead). (“Hetero” means

“other”)

III. Chlorophyll – A light-absorbing pigment found in chloroplasts of plants, algae, and blue-green

bacteria.

A. B.

Found mainly in the mesophyll layer of ground tissue in plant leaves. (“meso” refers to

“middle”)

“phyll” means “pigment”; “”chloro” means “green” (They reflect green light.)

IV. Chloroplast structure (“plast” means “container”) (These are organelles in Eukaryotes.)

A. Thylakoid – Little green discs that contain the pigment chlorophyll found inside the

chloroplast.

1. Site of the light reaction of photosynthesis. (The thylakoid membrane contains

the photosystems.)

a) Primary purpose is to make ATP and NADPH. (Both are Energy

molecules.)

b) Grana – a stack of thylakoids.

B. Stroma – The watery space surrounding the thylakoids. (It holds the water needed for

photosynthesis.)

1. Site of the light – independent reaction (Dark or Calvin Cycle) of photosynthesis.

Primary purpose is to use ATP and NADPH to make sugars using CO2.

a) V. Photosynthesis Chemical Reaction

A. B. Starts by taking sunlight energy and converting it into chemical energy (ATP & NADPH).

Then takes the chemical E (ATP and NADPH) and uses that chemical energy to power the

production of sugar (Sugars are chemical E storage molecules.)

C. 6 CO2 +6 H2O --> (in the presence of sunlight) C6H12O6 + 6O2 + Heat (Key Number is 6 in

balancing.)

D. E. Sugar is stored chemical energy for cellular respiration.

H20 splits by the process of photolysis (splitting of H2O with light) creating the O2 that

we breathe; CO2 does not create atmospheric O2 here.

F. Two processes involved in the conversion of sunlight energy to sugar

1. Light reaction (light dependent) – It changes sunlight into ATP and NADPH.

(Usable chemical energy.)

VI. G. H. 2. Calvin cycle (A.K.A. light independent reaction) – Makes sugar using CO2, ATP ,

and NADPH

a) Melvin Calvin discovered the working process.

NADP+ is converted to NADPH by picking up 2 negative electrons (The first cancels the

charge; the second makes the NADP molecule negative which allows for H+ to attach and

thus create NADPH.)

ADP is phosphorylated (Add a phosphate) by ATP synthase using the free E’s of electron

transport chain on the thylakoid membrane.

Sunlight (It is high quality E. Remember, High quality means it can perform work.)

A. Sunlight travels in waves with different wavelengths. (The Electromagnetic spectrum

shows all the Wavelengths/colors found in sunlight.)

1. Red Light– Has the longest wavelength. (It also has the least E of “white light”

.)

2. Blue Light- Has the shortest wavelength. (It has the most E of “white light”

.)

3. Spectrophotometer – This measures light wavelengths not absorbed by a

specimen.

B. Visible “white” light – ROY G. BIV (red, orange, yellow, green, blue, indigo, violet) are the

colors within.

C. Light travels in units of Energy called Photons

D. Absorption vs. Reflection

1. Absorbed –These colors are usable light E.

a) Plants use Reds and Blues; but not green.

b) Chlorophyll A – Main pigment found in all plants and algae. (It

has a structure that looks like a Mg spider in a carbon ring web.)

c) Chlorophyll B – Helps Chlorophyll A receive sunlight E. (B funnels

E to A.)

d) Carotenoids – These are accessory pigments that help

Chlorophyll A. (They funnel E to A too but reflect red, orange, or

yellow pigments.)

e) Photosystem – Group of light absorbing pigments in thylakoid

membrane. (Chlorophyll A would be in the reaction

center.)(“system” means “group of”).

(1) Photosystem I (P700) – Responsible for ATP and NADPH

production.

(2) Photosystem II (P680) – Responsible for ATP production

only.

2. Reflection – These colors are not usable. (They provide the color of an

object in your vision.)

a) This is why plants appear green to you. Green light is reflected

back toward your eyes

VII. Light Reaction of Photosynthesis

A. This process is used for converting sunlight into usable chemical Energy molecules.

(These molecules are: ATP and NADPH)

B. These two parts are occurring, in the presence of sunlight, at the same time on the

Thylakoid membranes.

C. There are thousands of these Photosystems (I and II) on each Thylakoid membrane.

D. Steps in the process

1. Step 1: Sunlight hits, and splits, the water in the stroma. It also hits the

photosystems I (P700) and II (P680).

2. Step 2: 2 Excited electrons travel down the electron transport chains. They came

from the Mg in the Chlorophyll A molecule. (The 2 excited electrons were able to

leave the Mg because the sunlight heated them up and made them move much

faster. Fast enough to escape the pull from the nucleus’ positive protons) As the

excited electrons go down the electron transport chain, their excited kinetic E

(also called Free E) is being used to power the proteins called Proton pumps.

(Remember, a proton is a Hydrogen ion and is shown as H+) As the electrons

go down their chain, their excited kinetic E decreases.

a) P680’s 2 excited electrons

(1) Free E of the electrons is used to actively transport protons (H+)

into the confined thylakoid space. (As the [H+] goes up inside

the space. The [H+] goes down in the stroma. So a concentration

gradient is created. This is a source of potential E now.) (It would

be like blowing air into a balloon. The pressure builds as more

air is blown in. This is also an example of potential E.)

(2) P700’s 2 excited electron

(a) Combine with NADP+, to make it negative so that

NADPH can be generated.)(This is the ending point for

non-cyclic electron flow.) OR

(b) Cyclic electron flow – P700 loses 2 excited

electrons to the electron transport chain, but

they return to P700. (Remember this makes

extra ATP .)

3. Step 3: The trapped H+, inside the Thylakoid, are released through the ATP

Synthase Complex. This is the group of enzymes in the Thylakoid membrane that

helps make ATP . Just look at its name. (This release of kinetic H+ powers the

phosphorylation of ADP ATP .) (This would be like the air coming out of the

blown up balloon and turning a pinwheel.)

a) This Kinetic movement of H+ produces a large amount of ATP

b) This is an example of Energy Coupling (Two processes working together

to make ATP . The first process was Active transport to pump the H+ into

the Thylakoid to make the concentration gradient. The second process

VIII. 4. is a type of diffusion. The H+ going from high [ ] to low [ ]. The kinetic

movement of the H+ fuels the production of ATP .) This is Chemiosmosis

Step 4: ATP and NADPH will be used to power carbon fixation of CO2 into sugar

in the Calvin Cycle.

Calvin Cycle (A.K.A. light independent reaction)

A. B. This part uses the ATP and NADPH of light reactions to make sugar using CO2.

There are 4 steps to making a single sugar molecule:

1. Step 1: 3 CO2 molecules will be used, in the chloroplasts stroma, by the enzyme

Rubisco to convert RuBPs into G3P molecules. (Remember, these were the 2

halves of a sugar molecule that were seen in Glycolysis.) The energy to power

the conversion comes from ATP and NADPH.

2. 3. Step 2: 1 G3P will be removed to put toward making sugar.

Step 3: The remaining G3P will be reconverted back into RuBP using the extra

ATP from the light reaction.

4. Step 4: Repeat steps 1 - 3 to make the second half of the sugar molecule.

C. These sugars will be needed to feed the whole plant or algae. The sugars will be

consumed in the process of cellular respiration or stored to be used later or passed to

consumers in a food chain.

Unit 8 Cellular Energetics

Cellular Respiration

I. Cellular Respiration

A. This is the process of releasing energy contained in organic molecules (mainly Glucose)

to do work. (This is an example of catabolism.)

1. The process is for making ATP using oxygen, if available

2. The process releases heat (Remember, heat is Low Quality E) and free electrons

B. C. With O2 present in the cell – Cellular Respiration can occur in the mitochondria.

Without O2 present in the cell – Fermentation occurs in the cytoplasm of the cell.

D. 6H20 + C6H12O6 6CO2 + 6O2 + Free E +Heat E

1. The Free E is used to make ATP from ADP by phosphorylation

II. Cellular Respiration is a Three Step Process:

A. Step 1: Glycolysis (This is the breaking of Glucose into 2 molecules of G3P .)

1. All organisms can do this process as it occurs in the cytoplasm of a cell.

2. There will be an additional pyruvate conversation before the Krebs Cycle begins.

B. Step 2: Kreb’s Cycle (This is all about making Electron Carriers in the continued

breakdown.)

C. Step 3: e- Transport Chain (This is where the Free E of the electrons is used to help make

ATP.)

D. The whole process yields a maximum of 38 ATP/ 95% of time only 36 produced though

III. The Process of Glycolysis

A. In this process, Glucose (C6 H12 O6 ) will be broken apart into 2 molecules of G3P . Each

molecule of G3P will then be converted to a molecule of Pyruvate. At the end of the

process, the cell will have 2 molecules of Pyruvate that can be put into the

Mitochondria, if oxygen is present and it is a Eukaryotic Cell.

B. There are two parts to Glycolysis:

1. E Investment Phase

a) Glucose is broken into 2 molecules of G3P

b) To break it in half requires 2 ATP be used. (One phosphate is put on each

side of the Glucose molecule. This makes it unstable and Glucose breaks

in half to make 2 G3P molecules.)

2. E Payoff Phase

a) The 2 molecules of G3P will then be converted to 2 molecules of

Pyruvate

b) This phase will yield 4 ATP + 2 NADH total. (2 ATP and 1 NADH per

molecule.) The cell pays back the two it used for the first part. This

leaves the cell with a payoff of two ATP . (What we refer to as Net

Gain.)

C. D. Remember, this process occurs with or without O2 present in the cell.

All organisms do it as it occurs in the cytoplasm of a cell. Even cells that do not carry on

with anaerobic respiration, use glycolysis as part of fermentation to produce small

amounts of ATP for survival

IV. If Oxygen is present within the Eukaryotic cell (“Aerobic” means “With Oxygen”), the Eukaryotic

cell can perform the other two parts of Cellular Respiration – Krebs Cycle and Electron Transport

Chain

A. In order to enter the inner Mitochondrial space, where the Krebs Cycle occurs,

Pyruvate must be converted to Acetyl Coenzyme A. This is referred to as the Pyruvate

Conversion. It occurs in the space between the outer membrane and the inner

membrane of the Mitochondria.

1. The final product is Acetyl Coenzyme A. (Each molecule is now located in the

inner mitochondrial space.)

B. Kreb’s Cycle (This occurs in the mitochondrial matrix where there is room to work.)

Remember, the main purpose of the Krebs Cycle is to make Electron Carriers by taking

the Hydrogens and attaching them to the Electron carriers. Remember, each

Hydrogen has one electron with it. See how many it makes per Acetyl Coenzyme put

into the cycle.

1. EACH Acetyl Coenzyme A that goes through the cycle will produce

a) 3 NADH, 1 FADH2, 1ATP , and CO2

b) Each Electron carrier can carry 2 electrons to the Electron Transport

Chain

(1) (2) (3) The first negative electron cancels the positive charge on either

NAD+ or FADH+.

The second negative charge makes the FADH or NAD negative.

So a positive H+ will be able to attach to a negative FADH or

NAD.

C. Electron Transport Chain

1. This occurs on the cristae membrane.

a) This membrane is folded (the folds increase surface area =more ATP can

be produced as there is room for more Electron Transport Chains.)

2. The Electron Transport Chain is always in a membrane.

a) For Bacteria- It is the plasma membrane.

b) For Eukaryotes – It is the Mitochondrial inner membrane

3. The whole process is a controlled release of E.

a) Electrons move 2 at a time down the chain toward Oxygen. (Make H2O

at the end.)

b) Energy (electrons) from NADH and FADH2 is used to produce ATP.

c) Free Energy, from the electrons, fuels the active transport of H+ into the

inner mitochondrial space.

(1) H+ (ions/protons) are pumped into the space between the

membranes using the Free E released from electrons as they go

down the chain

(2) The concentration of H+ builds inside the space (like blowing up

a balloon) to create a concentration gradient. High [] in between

and low [ ] in the center.

(3) The H+ are released using ATP Synthase. (It would be like pulling

the plug in a sink)

(4) (5) (6) The H+ rush out (going from High [ ]–>Low [ ]) allowing the ATP

Synthase to use the Kinetic E to turn ADP ATP in large

amounts by phosphorylation

This is another example of Energy Coupling – two processes

working together to make ATP . One process is Active transport

and the other is facilitated diffusion. Also known as

Chemiosmosis.

The Electron Transport Chain can make 34 or 32 ATP vii. Add it

all up now:

2 Net ATP From Glycolysis

2 ATP from the Kreb’s Cycle

34 OR 32 from the ETC

38 Maximum OR 36 Normal

V. If no Oxygen is present within the cell (“Anaerobic” means “without oxygen”):

A. Fermentation will occur to free up the electron carriers to keep at least Glycolysis going

making ATP .

1. Two types of fermentation can occur (It depends on the organism doing it.)

a) Alcohol Fermentation (This occurs in bacteria and Yeast –a fungus.)

(1) They convert the two Pyruvate to 2 molecules of Ethanol by

cutting off CO2 and filling the open bond with H from the

electron carriers. (This freed up the electron carrier to keep

Glycolysis going and thereby making some ATP to stay alive.)

(2) Beer, wine, and bread are made by this type of fermentation.

b) Lactic Acid fermentation (This occurs in animals mainly.

(1) Converts Pyruvate into Lactic Acid by breaking a double bond

with O2 and adding H. The H comes from the electron carrier.

Here again keeping the process of Glycolysis going to make a

little amount of ATP to keep the cells alive in the absence of

Oxygen.

(2) Cheese, yogurt, and muscle cramps (These force you to stop

exercising.) are all created by this type of fermentation.

VI. Facultative Anaerobes

A. These organisms can perform both Aerobic and Anaerobic Respiration but prefer oxygen

– because it produces more ATP .