Gases and Pressure

Gases and Pressure

Overview of the Session Goals

  • Define atmospheric pressure.

  • Outline Boyle’s Law for pressure and volume of gases.

  • Outline the Combined Gas Law for temperature, pressure, and volume of gases.

  • Perform simple calculations involving temperature, pressure, and volume of gases.

  • Discuss clinical applications of gases and pressure.

  • Week 3 Learning Goals 1, 14 - 17.

Recap from Last Week: Pressure and Fluids

  • What is pressure and how is it measured?

    • Pressure is defined as the quantity of force per unit area.

    • The SI unit of pressure is Pascal (1 Pa = 1 N/m²).

  • What are fluids?

    • A fluid is a substance that does not hold its own shape and can flow.

    • Gases are classified as a type of fluid.

The Atmosphere

  • The earth’s atmosphere consists of gas molecules that constitute air.

  • These molecules are held close to the earth due to gravity but are in motion because of their kinetic energy.

  • Each location in a fluid experiences pressure from the weight of the fluid molecules above it.

  • Atmospheric pressure is greater at lower altitudes (closer to sea level) due to the increased number of air molecules stacked above.

What is a Vacuum?

  • A vacuum is defined as a space that is not occupied by any mass.

  • Achieving a vacuum involves constricting space within a container, pushing gas out and then increasing the container size while preventing gas from re-entering, creating a negative pressure relative to the surrounding atmosphere.

  • The closer the pressure is to absolute zero, the closer it is to an ideal vacuum.

  • Pumps are devices used to push fluids (liquids or gases) in or out of apparatus, subsequently adjusting pressure as a result.

Gas in an Enclosed Container

  • Gas in an enclosed container is composed of molecules with kinetic energy that move randomly.

  • Inter-molecular and molecular-container collisions lead to forces being exerted, causing pressure within the container.

Pressure of Gas

  • What happens to total force exerted on the container if the number of gas molecules increases but the container size is constant?

  • The total pressure would increase as a result of increased molecular interactions.

Pressure of Gas and Volume

  • What happens when the number of gas molecules remains constant but the container size decreases?

  • The pressure will increase as the gas molecules are confined to a smaller volume, leading to more frequent collisions with the container walls.

Relationship Between Pressure and Density

  • Commonality of Concepts:

    • Both scenarios increase the density of the gas.

    • Pressure is proportional to density, dependent on the number of molecules or the volume of the container.

Boyle’s Law

  • Boyle’s Law defines the relationship between pressure and volume while assuming that the quantity of gas (its mass) and temperature remain unchanged.

  • The mathematical expression of Boyle’s Law is:

    • P_1V_1 = P_2V_2

  • This law indicates that pressure varies inversely with volume: when volume increases, pressure decreases by the same factor to keep their product constant.

A Simple Sample

  • A fixed quantity of helium is placed in an adjustable container with an initial volume of 1 m³.

  • If the volume is reduced to one-tenth of its original size, the increase in pressure inside the container can be predicted using Boyle’s Law.

Givens and Knowns

  • Given:

    • Mass of helium is constant

    • Initial volume: 1 m³

    • New volume: 0.1 m³

  • What facts are given directly in the question?

    • Fixed mass, initial and new volume of the gas.

  • Other Facts}:

    • Ideal gas behavior can be assumed if mentioned in the problem.

  • Assumptions:

    • Temperature is constant.

What’s our Target?

  • Target Variable:

    • New pressure of the gas after volume alteration.

  • Units of Measurement:

    • Pressure, measured in Pascals (Pa).

  • Significant Figure (SD):

    • Follow significant figure rules based on initial data provided.

  • Closing Statement:

    • State the relationship explored through Boyle’s Law and its implications on pressure change.

Relevant Concepts and Relationships

  • Which physics laws apply here?

    • Boyle’s Law as the main governing principle for this scenario.

  • Broad Predictions:

    • As volume decreases, pressure increases.

  • Symbol Representation:

    • Use symbols such as P for pressure and V for volume in equations.

  • Equations to Utilize:

    • Usage of Boyle’s Law equation for calculations.

Plan the Maths

  • Simplification:

    • Assess the equation for any potential simplifications.

  • Rearrangement:

    • Rearrange to isolate the target variable (pressure).

  • Substituting Known Values:

    • Prepare values for substitution based on definitions in Boyle's Law.

Substitute and Solve

  • Substitute known values into the equation.

  • Remember to include units in calculations to verify accuracy across dimensional analysis.

About Your Answer

  • Understand that the calculated pressure is a relative measure, not an absolute one, as pressures are defined relative to atmospheric pressure.

Pressure and Flow of Gas

  • Gases naturally extend to occupy maximum available space and minimize pressure.

  • If two gas containers are connected and pressure is higher in one, gas will flow into the lower pressure container until there is an equalized pressure (redistribution of gas molecules).

  • The flow of gases occurs when there exists a pressure gradient (ΔP).

Clinical Significance: Breathing

  • Breathing is a practical illustration of Boyle’s Law and gas flow principles.

  • To fill the lungs with air, a pressure gradient is necessary to allow external air to flow in.

  • Atmospheric pressure applies outside, which must be higher than the internal lung pressure.

Breathing Explained

  • Volume increase in lungs is achieved through the contraction of intercostal muscles and diaphragm, decreasing pressure within lungs according to Boyle’s Law, resulting in a pressure gradient (ΔP) for inhalation.

  • Exhaling Requirements:

    • Lung volume must decrease for air to flow out, creating the opposite pressure gradient.

The Significance of Kinetic Energy

  • Gas molecules are perpetually in random motion, possessing kinetic energy (KE).

  • The total KE of the gas molecules is dependent on their internal energy (temperature):

    • Higher temperatures correspond to more KE and consequently more collisions, increasing force against container walls.

How Does Gas Temperature Relate to Gas Pressure?

  • Higher temperatures lead to increased force exerted on container walls, correlating with increased gas pressure.

  • The relationship is given as pressure being proportional to temperature:

  • P ext{ is proportional to } T

  • The ratio of pressure to temperature remains constant if the volume is fixed:

  • rac{P_1}{T_1} = rac{P_2}{T_2}

The Combined Gas Law

  • Definition:

  • The Combined Gas Law integrates the relationships among pressure, temperature, and volume.

  • Combined equations include:

  • rac{P_1V_1}{T_1} = rac{P_2V_2}{T_2}

  • Important Note:

  • Temperature must be expressed in absolute terms (Kelvin).

What Does the Combined Gas Law Mean?

  • The interconnectedness of pressure, volume, and temperature is fundamental.

  • Adjusting one parameter results in changes to at least one of the other factors.

  • Altering temperature leads to a volume change if the pressure is constant, and changing pressure or volume can induce temperature variations.

Summary

  • Students should now be able to:

    • Define atmospheric pressure.

    • Outline Boyle’s Law relating pressure and volume of gases.

    • Outline the Combined Gas Law linking temperature, pressure, and volume of gases.

    • Conduct simple calculations involving temperatures, pressures, and volumes of gases.

    • Discuss clinical implications of gases and pressure, especially in the context of breathing and gas flow.