Redox Reaction

Overview of REDOX Reactions

  • REDOX Reaction: A chemical reaction where one substance loses electrons (oxidation) and another gains electrons (reduction).

Key Concepts in REDOX

  • Oxidation:

    • Definition: Losing electrons.
    • Mnemonic: OIL (Oxidation Is Losing).
  • Reduction:

    • Definition: Gaining electrons.
    • Mnemonic: RIG (Reduction Is Gaining).
  • Electron Transfer:

    • Involves the transfer of electrons between atoms, ions, or molecules.
    • Examples: Burning of fuels, corrosion of metals, photosynthesis, and cellular respiration.

Oxidation Numbers

  • Definition: The oxidation number changes when an atom, molecule, or ion gains or loses an electron in redox reactions.

Rules for Assigning Oxidation Numbers:

  1. Element Alone:

    • An element alone has an oxidation number of 0.
    • Example: O₂ has an oxidation number of 0 since it is not involved in any electron exchange.
  2. Simple Ions:

    • The charge of a simple ion is its oxidation number.
    • Example: Na⁺ = +1, Cl⁻ = -1.
  3. Oxygen:

    • Mostly has an oxidation number of -2 (takes electrons).
    • Example: In H₂O, oxygen is -2 and hydrogen is +1.
  4. Hydrogen:

    • Generally +1 (shares electrons), except in metal hydrides (e.g., NaH where it is -1).
  5. Sum in Neutral Compounds:

    • The sum of oxidation numbers in a neutral compound equals 0.
    • Example: In CO₂, since O is -2, C must be +4 to balance.
  6. Sum in Ions:

    • The sum of oxidation numbers in an ion equals the ion's charge.
    • Example: In SO₄²⁻: O is -2 (4 O's = -8), so S must be +6.

Agents in REDOX Reactions

  • Reducing Agent (RA):

    • The substance that donates electrons and is oxidized.
  • Oxidizing Agent (OA):

    • The substance that accepts electrons and is reduced.

Tips for Remembering REDOX Terminology

  • Mnemonic 1: GER OA (Gain Electrons, Reduced/Reduction, Oxidizing Agent)
  • Mnemonic 2: LEOR A (Lose Electrons, Oxidized/Oxidation, Reducing Agent)