Periodic Table and Lithium

Lithium's History

  • Mid-1800s: Medical community links uric acid to various maladies.
  • Lithium carbonate solutions were found to dissolve uric acid, leading to therapeutic preparations containing lithium carbonate salt.
  • Non-medical companies added lithium to soft drinks.
  • 1940s: Doctors recommend salt-restricted diets for cardiac patients.
  • Lithium chloride was commercially available as a sodium chloride table salt substitute.
  • Reports of severe poisonings and deaths due to lithium overdosing led to US companies withdrawing lithium salts from the market.
  • Australian psychiatrist John Cade proposed using lithium salts to treat mania, with successful clinical trials.
  • Lithium carbonate became commonly prescribed in Europe for manic behavior.
  • 1970: US Food and Drug Administration approved lithium carbonate for manic symptoms.
  • Lithium (Li) has an atomic number of 3.
  • It is a soft alkali metal and the least dense solid element under standard conditions (specific gravity = 0.53).
  • Lithium is highly reactive and found only in salt compounds.

Periodic Table

  • 1869: Dmitry Mendeleev published his periodic table, arranging elements by atomic weight to reveal recurring physical and chemical properties.
  • Revised periodic table organizes elements by increasing atomic number (number of protons).
  • The periodic table represents the periodic law: chemical and physical properties of elements depend on their atomic numbers.
  • Elements are arranged into periods (rows) and groups/families (columns) based on atomic number.
  • There are seven periods, corresponding to the principal quantum numbers n=1n = 1 through n=7n = 7 for the s and p block elements.
  • Each period fills sequentially, with each element having one more proton and electron than the element to its left.
  • Groups contain elements with the same electronic configuration in their valence shell, sharing similar chemical properties.

Valence Electrons

  • Valence electrons are farthest from the nucleus and have the highest potential energy.
  • They participate in chemical bonds with other atoms' valence electrons.
  • Valence shell electrons determine chemical reactivity and properties of an element.
  • Roman numerals above each group indicate the number of valence electrons in that group's elements.

Element Classification

  • Elements are separated into two classes using the letters "a" and "b" alongside Roman numerals.
    • A elements: Representative elements (groups 1A through 8A) with valence electrons in s or p subshells.
    • B elements: Non-representative elements, including transition elements (valence electrons in s and d subshells) and lanthanide/actinide series (valence electrons in s and f subshells).
  • Representative elements' electron configuration is determined by the Roman numeral and letter designation (e.g., Group 5A has 5 valence electrons with configuration s2p3s^2p^3).
  • Non-representative elements may have unexpected electron configurations (e.g., Chromium Cr\text{Cr}: 4s13d54s^13d^5, Copper Cu\text{Cu}: 4s13d104s^13d^{10}).
  • Modern IUPAC system numbers groups 1 to 18 without A and B subdivisions.