Periodic Table and Lithium
Lithium's History
- Mid-1800s: Medical community links uric acid to various maladies.
- Lithium carbonate solutions were found to dissolve uric acid, leading to therapeutic preparations containing lithium carbonate salt.
- Non-medical companies added lithium to soft drinks.
- 1940s: Doctors recommend salt-restricted diets for cardiac patients.
- Lithium chloride was commercially available as a sodium chloride table salt substitute.
- Reports of severe poisonings and deaths due to lithium overdosing led to US companies withdrawing lithium salts from the market.
- Australian psychiatrist John Cade proposed using lithium salts to treat mania, with successful clinical trials.
- Lithium carbonate became commonly prescribed in Europe for manic behavior.
- 1970: US Food and Drug Administration approved lithium carbonate for manic symptoms.
- Lithium (Li) has an atomic number of 3.
- It is a soft alkali metal and the least dense solid element under standard conditions (specific gravity = 0.53).
- Lithium is highly reactive and found only in salt compounds.
Periodic Table
- 1869: Dmitry Mendeleev published his periodic table, arranging elements by atomic weight to reveal recurring physical and chemical properties.
- Revised periodic table organizes elements by increasing atomic number (number of protons).
- The periodic table represents the periodic law: chemical and physical properties of elements depend on their atomic numbers.
- Elements are arranged into periods (rows) and groups/families (columns) based on atomic number.
- There are seven periods, corresponding to the principal quantum numbers n=1 through n=7 for the s and p block elements.
- Each period fills sequentially, with each element having one more proton and electron than the element to its left.
- Groups contain elements with the same electronic configuration in their valence shell, sharing similar chemical properties.
Valence Electrons
- Valence electrons are farthest from the nucleus and have the highest potential energy.
- They participate in chemical bonds with other atoms' valence electrons.
- Valence shell electrons determine chemical reactivity and properties of an element.
- Roman numerals above each group indicate the number of valence electrons in that group's elements.
Element Classification
- Elements are separated into two classes using the letters "a" and "b" alongside Roman numerals.
- A elements: Representative elements (groups 1A through 8A) with valence electrons in s or p subshells.
- B elements: Non-representative elements, including transition elements (valence electrons in s and d subshells) and lanthanide/actinide series (valence electrons in s and f subshells).
- Representative elements' electron configuration is determined by the Roman numeral and letter designation (e.g., Group 5A has 5 valence electrons with configuration s2p3).
- Non-representative elements may have unexpected electron configurations (e.g., Chromium Cr: 4s13d5, Copper Cu: 4s13d10).
- Modern IUPAC system numbers groups 1 to 18 without A and B subdivisions.