Therapeutic Drug Monitoring
Therapeutic Drug Monitoring (TDM)
Definition of TDM
TDM is the analysis, assessment, and evaluation of the circulating concentration of drugs in serum, plasma, and whole blood.
Objectives of TDM:
Ensure a given dose produces:
Maximum therapeutic benefit.
Minimal toxic side effects.
Basis of TDM
Key Factors Influencing TDM:
Route of administration.
Rate of absorption.
Distribution of the drug within the body.
Rate of elimination.
Complexities:
Many factors influence the four key aspects of TDM, making the process of achieving therapeutic drug concentrations complicated.
Figure: Overview of Drug Concentration Influencing Factors
Processes Include:
Absorption from the gastrointestinal tract.
Distribution throughout the body.
Metabolism and elimination (renal excretion).
Protein binding.
Impact on:
Biological response and metabolite formation.
Mechanism of Therapeutic Drugs
Receptor Interaction:
Drugs mediate actions by interacting with receptors such as enzymes, structural proteins, transport proteins, and macromolecules.
Potential Actions:
Compete with endogenous substances for binding sites.
Block formation, release, uptake, or transport of essential substances.
Modify cellular functions through changes in membrane permeability or DNA transcription.
Dosage Regimens
General Rule:
TDM is rarely needed for well-established dosage regimens unless there are significant concerns.
Process When TDM Required:
Establish baseline concentration that is therapeutic.
Initiate therapy.
Individualized monitoring for each patient to maintain regimen effectiveness.
Indications for TDM
TDM is indicated when:
There are small gaps between therapeutic and toxic doses.
Serious consequences arise from overdosing or under-dosing.
Poor dose-concentration correlation exists, but a correlation between drug concentration and effects is strong.
Physiological changes occur in the patient that may alter drug concentration.
Drug interactions are suspected.
Patient compliance monitoring is needed.
Factors Leading to Adoption of TDM
Key Advancements:
Expanded range of drugs with therapeutic potential but narrow therapeutic ranges.
Development of analytical methods (accurate, precise, sensitive, and specific) for TDM.
Use of computers for pharmacokinetic data analysis to predict dosing.
Pharmacokinetics Overview
Defined as the activity of a drug in the body, emphasizing absorption, distribution, metabolism, and excretion.
Application of Pharmacokinetics:
Involves mathematical modeling of drug concentration.
Supports establishment or modification of dosage regimens.
Bioavailability:
Represents the fraction of an administered dose that reaches systemic circulation in an unchanged form.
Stages of Pharmacokinetics
Absorption Process:
Effective concentration must be achieved at the drug's site of action.
Chronic drug administration typically occurs extravascularly before entering the bloodstream.
Routes of Administration:
IV (Intravenous): Direct and effective.
IM (Intramuscular) and SC (Subcutaneous): Through muscle tissue.
Inhalation and transdermal delivery (patches).
Rectal administration via suppository.
Oral: Most common route.
Factors Affecting Drug Absorption
Critical Elements:
Drug nature: Dissociation from the dosing form is essential.
Solubility in gastrointestinal fluids; weak acids absorbed better in the stomach, weak bases in the intestine.
Diffusion across GI membranes, influenced by abnormal GI motility, pH changes, inflammation/disease, age, pregnancy, and food interactions.
Drug Metabolism
Hepatic Portal System:
All substances from the intestine enter the hepatic portal system first before general circulation.
First-pass metabolism can significantly affect bioavailability.
First-Pass Effect:
Refers to significant hepatic uptake/metabolism leading to reduced bioavailability.
Varies among patients influenced by genetics (pharmacogenomics).
Drug Biotransformation
Defined as the conversion of a drug to its metabolites in biological systems.
Clinical Consideration:
Patients with impaired liver function may require reduced drug dosages due to a decreased rate of metabolism and elimination.
Protein Binding Dynamics
General Properties:
Drugs enter circulation mainly bound to proteins (e.g., acidic drugs to albumin, basic drugs to globulin).
Active Fraction Impact:
Only the free fraction can interact with therapeutic sites.
Influenced by serum protein content, competition for binding sites from other substances, and stress factors.
Toxicity Risks:
Increased free fraction can lead to significant toxicity.
Distribution of Drugs
Drugs circulate in the bloodstream, interact with blood constituents, and are carried to different body organs.
The Process:
Free drug crosses various membranes to interact with receptors and elicit biological responses.
Factors Influencing Distribution
Include:
Drug binding to circulating blood components.
Binding to fixed receptors.
Membrane permeability.
Solubility in lipids (easier for hydrophobic drugs).
Drug Metabolism and Elimination
Excretion:
Occurs through biliary, intestinal, pulmonary, or renal routes.
Key Metabolic Routes:
Hepatic metabolism leading to bile or bloodstream, followed by renal excretion.
Organ Function Impact:
Decreased liver function raises serum drug concentrations and pharmacological response.
Hepatic Drug Metabolism Overview
Xenobiotics:
Substances not inherently human and that can enter pathways intended for endogenous substances.
Mixed Function Oxidase (MFO) System:
Major metabolic process converting non-polar drugs to polar, water-soluble substances through enzymatic reactions (including oxidation, reduction, hydrolysis, deamination, conjugation).
Divided into:
Phase 1: Produces reactive intermediates through functional group changes.
Phase 2: Conjugates those intermediates to form water-soluble products.
Rate of Metabolism Variability
Varies based on:
Individual patient differences.
Changes in hepatic status, age, weight, genetics.
Environmental exposures.
Drug-food interactions, co-administered drugs, or alcohol.
Drug Metabolites
Some drug biotransformation produces active metabolites needing monitoring.
Renal Excretion Details
Plasma free fraction of drugs and their metabolites undergo glomerular filtration and tubular secretion.
Creatinine Clearance:
Evaluates kidney function reliably and correlates effective elimination rates.
Concentration of Circulating Drugs
Pharmacokinetics Study Use:
Establish needed dosage regimens based on expected drug levels in blood.
Observations:
If absorption rate exceeds distribution and elimination, serum concentrations rise.
If absorption is less, concentrations fall.
Peak and Trough Understanding
Drugs are not typically administered as a single large dose but scheduled at intervals, leading to varying concentrations known as:
Maximum: peak level.
Minimum: trough level.
Goals:
Achieve therapeutic peak and trough without approaching toxicity.
Steady-state evaluations require about 5-7 doses for accurate assessment.