Covalent, Ionic, and Hydrogen Bonds
Introduction to Biology and Chemistry
- Biology is primarily about sex and not dying.
- To understand biology, a basic understanding of chemistry is essential.
- Organic compounds that contain carbon is the basis of all living things.
Carbon: The Foundation of Life
- Carbon is a relatively small atom with 6 protons and 6 neutrons (atomic weight of 12).
- It can form rings, sheets, spirals, and double or triple bonds due to its size.
- Carbon is "kind" because it's not as reactive as elements like fluorine, chlorine, or sodium.
- Carbon needs four extra electrons and bonds with various molecules like hydrogen, oxygen, phosphorus, and nitrogen.
- Life is based on carbon, so scientists have difficulty conceiving non-carbon-based life.
Electron Shells and Covalent Bonds
- Atoms have electron shells and need them filled to be stable.
- Carbon has 6 electrons: 2 fill the first shell, and 4 are in the second shell.
- Carbon forms covalent bonds by sharing electrons with other atoms. Methane (CH_4) is an example where carbon shares four electrons with four hydrogen atoms.
- Lewis dot structures represent how atoms bond together.
Gilbert Lewis and Lewis Dot Structures
- Gilbert Lewis created Lewis dot structures and also worked on Lewis acids and bases.
- Nominated for the Nobel Prize 35 times but never won.
- Coined the term "photon," revolutionized acid-base theories, produced the first molecule of heavy water, and conceptualized the covalent bond.
- Elements react to achieve eight electrons in their outermost shell (octet rule).
Examples of Bonding
- Oxygen has six electrons and needs two, so it forms H_2O. (Water)
- It can form two double bonds with carbon, creating CO_2 globally warming gas.
- Nitrogen has five electrons; it bonds with three hydrogens to form ammonia (NH_3).
- Amino groups consist of nitrogen bonded to two hydrogens.
- Amino acids have an amino group bonded to a carbon that's bonded to a carboxylic acid group.
Polar vs. Non-Polar Covalent Bonds
- Non-polar covalent bonds: Electrons are shared equally (e.g., O_2).
- Polar covalent bonds: Electrons are shared unequally, creating partial charges (e.g., water). Oxygen is more electronegative than hydrogen, thus has a slightly negative charge, and hydrogen has a slight positive charge.
Ionic Bonds: Electron Transfer
- Atoms transfer electrons to achieve a full octet, becoming ions.
- Atoms generally prefer to be neutral but will sacrifice neutrality for a complete octet.
Sodium Chloride (NaCl) Example
- Sodium chloride (table salt) is an ionic compound.
- Chlorine (halogen) needs one electron, and sodium (alkali metal) has one electron in its outer shell.
- Sodium transfers its electron to chlorine, forming Na^+ and Cl^-. Opposite charges cause them to stick together forming an ionic bond.
- Sodium and Chlorine can be very dangerous on their own, but together they are delicious.
Hydrogen Bonds: Weak Attractions
- Hydrogen bonds occur when hydrogen is bonded to a highly electronegative atom such as Oxygen.
- Since water has a polar covalent bond, the hydrogen end is partially positive, and the oxygen end is partially negative.
- Water molecules stick together due to hydrogen bonds.
- Hydrogen bonds play an important role in proteins.
Bond Strengths and Biological Implications
- Covalent and ionic bonds vary in strength.
- Making and breaking bonds is essential for life and death.
- Living organisms are collections of organic compounds in water.