Covalent, Ionic, and Hydrogen Bonds

Introduction to Biology and Chemistry

  • Biology is primarily about sex and not dying.
  • To understand biology, a basic understanding of chemistry is essential.
  • Organic compounds that contain carbon is the basis of all living things.

Carbon: The Foundation of Life

  • Carbon is a relatively small atom with 6 protons and 6 neutrons (atomic weight of 12).
  • It can form rings, sheets, spirals, and double or triple bonds due to its size.
  • Carbon is "kind" because it's not as reactive as elements like fluorine, chlorine, or sodium.
  • Carbon needs four extra electrons and bonds with various molecules like hydrogen, oxygen, phosphorus, and nitrogen.
  • Life is based on carbon, so scientists have difficulty conceiving non-carbon-based life.

Electron Shells and Covalent Bonds

  • Atoms have electron shells and need them filled to be stable.
  • Carbon has 6 electrons: 2 fill the first shell, and 4 are in the second shell.
  • Carbon forms covalent bonds by sharing electrons with other atoms. Methane (CH_4) is an example where carbon shares four electrons with four hydrogen atoms.
  • Lewis dot structures represent how atoms bond together.

Gilbert Lewis and Lewis Dot Structures

  • Gilbert Lewis created Lewis dot structures and also worked on Lewis acids and bases.
  • Nominated for the Nobel Prize 35 times but never won.
  • Coined the term "photon," revolutionized acid-base theories, produced the first molecule of heavy water, and conceptualized the covalent bond.
  • Elements react to achieve eight electrons in their outermost shell (octet rule).

Examples of Bonding

  • Oxygen has six electrons and needs two, so it forms H_2O. (Water)
  • It can form two double bonds with carbon, creating CO_2 globally warming gas.
  • Nitrogen has five electrons; it bonds with three hydrogens to form ammonia (NH_3).
  • Amino groups consist of nitrogen bonded to two hydrogens.
  • Amino acids have an amino group bonded to a carbon that's bonded to a carboxylic acid group.

Polar vs. Non-Polar Covalent Bonds

  • Non-polar covalent bonds: Electrons are shared equally (e.g., O_2).
  • Polar covalent bonds: Electrons are shared unequally, creating partial charges (e.g., water). Oxygen is more electronegative than hydrogen, thus has a slightly negative charge, and hydrogen has a slight positive charge.

Ionic Bonds: Electron Transfer

  • Atoms transfer electrons to achieve a full octet, becoming ions.
  • Atoms generally prefer to be neutral but will sacrifice neutrality for a complete octet.

Sodium Chloride (NaCl) Example

  • Sodium chloride (table salt) is an ionic compound.
  • Chlorine (halogen) needs one electron, and sodium (alkali metal) has one electron in its outer shell.
  • Sodium transfers its electron to chlorine, forming Na^+ and Cl^-. Opposite charges cause them to stick together forming an ionic bond.
  • Sodium and Chlorine can be very dangerous on their own, but together they are delicious.

Hydrogen Bonds: Weak Attractions

  • Hydrogen bonds occur when hydrogen is bonded to a highly electronegative atom such as Oxygen.
  • Since water has a polar covalent bond, the hydrogen end is partially positive, and the oxygen end is partially negative.
  • Water molecules stick together due to hydrogen bonds.
  • Hydrogen bonds play an important role in proteins.

Bond Strengths and Biological Implications

  • Covalent and ionic bonds vary in strength.
  • Making and breaking bonds is essential for life and death.
  • Living organisms are collections of organic compounds in water.