Reducing Sugars and Non-Reducing Sugars

Introduction

  • The monomers of sugars are monosaccharides.
  • The polymers of sugars are polysaccharides.
  • Multiple polysaccharides create carbohydrates.
  • Sugars can be classified into two categories: Reducing and Non-Reducing.
  • The categories are dependent on whether or not the sugar is able to donate electrons.
  • This relates to whether the sugar can be oxidised.

Reducing Sugars

  • The carbonyl group in reducing sugars can be oxidised.
  • Reducing sugars are able to donate electrons.#
  • This means that they can act as a reducing agent.
  • They can be detached using the Benedict test as they reduce the soluble copper sulphate to an insoluble brick red copper oxide.
  • To identify whether a substance is a reducing sugar, you can use the Benedicts Test.
  • Examples of Reducing sugars: Galactose, Glucose, Fructose, Maltose

Non-Reducing Sugars

  • Non-Reducing sugars cannot be oxidised.

  • Non-Reducing sugars cannot donate electrons.

  • This means that they cannot act as reducing agent.

  • To be detached they need to be hydrolysed to break the disaccharides into two monosaccharides before a Benedict test can be carried out.

  • To identify whether a substance is a non-reducing sugar you can do the following.

    • Add the substance to dilute hydrochloric acid.

    • Then heat it in a water bath that has been brought to a boil.

    • Add an alkali, such as sodium hydrogencarbonate, to the solution to neutralise it.

  • Examples of Non-reducing sugars: Sucrose