The Chemical Basis of Life (Chemical Bonds)

Chemistry of Life

Fundamental Concepts of Matter

  • Matter: Occupies space and has mass.

  • States of Matter: Found in solid, liquid, and gas states.

    • Examples: Rocks (solid), Water (liquid), Gas (gaseous).

Elements and Compounds

  • Element: A substance that cannot be broken down into other substances.

    • Periodic Table: Consists of 92 naturally occurring elements.

    • Examples of Elements: Gold (Au), Copper (Cu), Platinum (Pt), Silver (Ag), Carbon (C), Oxygen (O).

  • Compound: Substances composed of two or more different elements.

    • Examples: Table Salt (NaCl), Water (H₂O), Sugar (C₁₂H₂₂O₁₁).

    • More common in nature than pure elements.

Periodic Table of Elements

  • Structure: Elements organized in vertical columns and horizontal rows.

  • Groups: Elements in a vertical column have similar chemical properties due to the same number of valence electrons.

    • Notable Groups: Alkali metals, Alkaline earth metals, Halogens, Noble gases.

  • Periods: Each horizontal row represents elements with the same total number of electron shells and ordered by increasing atomic number.

Elements and Body Weight

  • 118 Different Elements: Matter is composed of these elements.

  • Elements Constituting Most Organisms: Oxygen (O), Carbon (C), Hydrogen (H), Nitrogen (N) account for 96% of body weight.

  • Definition of Element: A substance that consists of only one kind of atom.

Atom Structure

  • Atom: The smallest particle that retains chemical properties.

  • Subatomic Particles:

    • Protons: Positively charged, defines the atomic number.

    • Neutrons: No charge, contribute to mass number (mass = protons + neutrons).

    • Example: Carbon has 6 protons and 6 neutrons, so the mass number is 12.

    • Electrons: Negatively charged, equal in number to protons, resulting in a net electrical charge of 0.

  • Atomic Properties:

    • Atomic Number: Number of protons in the nucleus.

    • Atomic Mass: Sum of protons and neutrons in the nucleus.

Electron Configuration

  • Electron Distribution: Electrons occupy different energy levels or shells around the nucleus.

    • First Shell: Can hold 2 electrons.

    • Second Shell: Can hold up to 8 electrons.

  • Reactivity: Atoms with incomplete outer shells are more reactive, often gaining, losing, or sharing electrons to fill outer layers.

Potential Energy of Electrons

  • Potential Energy: Energy based on the electron's position relative to the nucleus.

    • Moving electrons closer releases energy; moving them further requires energy input.

  • Chemical Behavior: Determined by the distribution of electrons; electrons can capture or release energy, forming bonds between atoms.

Ions

  • Ion Definition: Atoms that have gained or lost electrons, resulting in a charge imbalance.

    • Cations: Positively charged ions formed by losing electrons.

    • Example: Sodium (Na) → Na⁺ (11 protons, 10 electrons).

    • Anions: Negatively charged ions formed by gaining electrons.

    • Example: Chloride (Cl) → Cl⁻ (17 protons, 18 electrons).

Chemical Bonds

  • Definition: Atoms held together by energy, forming a cohesive structure.

  • Types of Chemical Bonds:

    • Ionic Bonds: Formed by the electrical attraction between oppositely charged ions.

    • Covalent Bonds: Involve the sharing of electron pairs between atoms.

    • Types:

      • Nonpolar Covalent Bonds: Electrons are shared equally (e.g., H₂, O₂).

      • Polar Covalent Bonds: Unequal sharing due to differing electronegativities (e.g., H₂O).

    • Hydrogen Bonds: Weak bonds formed between slightly charged regions of polar molecules.

Specific Types of Bonds

  • Covalent Bonds:

    • Involve the sharing of electrons; can be single or double bonds based on the number of shared pairs.

    • Stronger than ionic bonds.

  • Nonpolar vs. Polar Covalent Bonds:

    • Nonpolar: Equal sharing (e.g., CH bonds).

    • Polar: Unequal sharing with partial charges (e.g., water).

  • Ionic Bonds:

    • Formed when one atom donates electrons to another. Sodium chloride (NaCl) serves as a common example of an ionic bond.

Chemical Reactions

  • Definition: Making and breaking of chemical bonds.

    • Reactants: Starting molecules in a chemical reaction.

    • Products: Final molecules resulting from a reaction.

  • Reversibility: All chemical reactions can be reversed.

  • Example of Biological Reaction: Photosynthesis

    • Chemical Equation:
      6CO<em>2+6H</em>2OC<em>6H</em>12O<em>6+6O</em>26 CO<em>2 + 6 H</em>2O —→ C<em>6H</em>{12}O<em>6 + 6 O</em>2