11) Nanoparticle

What Are Nanoparticles?

  1. Size: Nanoparticles are incredibly small particles, ranging from 1 nm (1 x 10-9 m) to 100 nm (1 x 10-7 m) in diameter.

  2. Composition: They consist of only a few hundred atoms, while a typical atom has a diameter of about 0.1 nm (1 x 10-10 m).

  3. Types of Particles:

    • Coarse Particles (PM10): Diameter between 2.5 x 10^-5 m and 10,000 m (1 x 10^-5 m); also known as dust.

    • Fine Particles (PM2.5): Diameter between 100 nm (1 x 10-7 m) and 2,500 m (2.5 x 10-6 m).


Nanoscience

  • This is the field of science that studies nanoparticles and their unique properties and uses.


Surface Area to Volume Ratio

  1. Definition: The surface area to volume ratio affects how particles behave.

    • Formula: Surface area to volume ratio = surface area ÷ volume

  2. Effect of Size: As particles decrease in size, their surface area increases relative to their volume, resulting in a higher surface area to volume ratio.

  3. Example Calculation:

    • Cube with 100 nm sides:

      • Surface area: 6 × (100 nm × 100 nm) = 60,000 nm²

      • Volume: 100 nm × 100 nm × 100 nm = 1,000,000 nm³

      • Ratio: 60,000 nm² ÷ 1,000,000 nm³ = 0.06 nm-1

    • Cube with 10 nm sides:

      • Surface area: 6 × (10 nm × 10 nm) = 600 nm²

      • Volume: 10 nm × 10 nm × 10 nm = 1,000 nm³

      • Ratio: 600 nm² ÷ 1,000 nm³ = 0.6 nm-1

  4. Implications: Nanoparticles have a very high surface area to volume ratio, meaning their surface area is much larger compared to their volume, leading to different properties compared to bulk materials.


Properties and Applications

  • The unique properties of nanoparticles can make them more effective than bulk materials, such as needing less of a nanoparticle-based catalyst to achieve the same effect as larger particles.