Exam 3 Learning Goals (1)

CHM1045 Fall 2024 Exam 3 Study Guide

Content from Lectures 15-20

The exam will cover material presented in Lectures 15 through 20, including details discussed during recitation and workshops.

Lecture Highlights

Lecture 15: Solutions
  • Definition of Solution: A solution is a homogeneous mixture consisting of two or more substances that are evenly distributed.

  • Components of Solution: Identify the different components, classifying them as solute (the substance being dissolved) or solvent (the substance doing the dissolving).

  • Aqueous Solutions: Solutions where water is the solvent are referred to as aqueous solutions.

  • Solubility Prediction: The solubility of substances can be predicted based on the dipole moments, which indicate how polar a compound is.

  • Ionic Compounds: Soluble ionic compounds dissociate into their respective ions when dissolved in a solvent, exhibiting characteristics of electrolytic solutions.

  • Electrolytic vs Nonelectrolytic Solutions: Understand the differences, where electrolytic solutions conduct electricity due to free ions, while nonelectrolytic solutions do not.

Lecture 16-17: Concentration Concepts and Calculations
  • Units of Concentration: Understand various units of concentration, including percent by mass (wt%), percent by volume (vol%), parts per million (ppm), parts per billion (ppb), mole fraction, molarity, and molality.

  • Density Conversions: Master conversions necessary to switch between these units effectively.

  • Recognize the advantages of different concentration units in practical applications for real-world problem-solving.

  • Conversions: Be able to convert between molarity, amount of solute in moles, solute mass, and total solution volume.

  • Dilution Calculations: Calculate concentrations of diluted solutions that are derived from stock solutions using the dilution equation (C1V1 = C2V2).

Lecture 18: Chemical Notation and Reactions
  • Chemical Notation: Understand how to write chemical equations symbolizing the transformation from reactants to products.

  • Reaction Procedure: Be able to interpret procedural details indicated above or below the reaction arrow, including mixing, heating, or timing instructions.

  • Balancing Reactions: Learn the importance of balancing chemical equations to reflect the law of conservation of mass.

  • Stoichiometric Coefficients: Comprehend the significance of stoichiometric coefficients and how to use molar ratios to relate reactants and products quantitatively.

Lecture 19: Reactants and Yields
  • Limiting and Excess Reactants: Familiarize yourself with the concepts surrounding limiting and excess reactants, which determine the maximum amount of product formed.

  • Theoretical Product Yield: Predict the theoretical yield based on the limiting reactant present in the reaction.

  • Percent Yield Calculation: Learn how to calculate the percent yield of a reaction by comparing actual product yield to theoretical yield.

  • Titration Techniques: Understand the fundamentals of titration as a method to determine the concentrations of unknown reactants in solutions.

Lecture 20: Ion Exchange and Acids/Bases
  • Ion Exchange Reactions: Practice predicting products in various types of reactions, including Bronsted-Lowry acid/base reactions and precipitation reactions.

  • Solubility Rules: Review the general solubility rules for ionic compounds, including:

    • Generally Soluble: Group I metals, ammonium, nitrates, and acetates.

    • Generally Soluble: Halides and sulfates unless they are combined with Ag+, Hg22+, or Pb2+.

    • Generally Insoluble: Carbonates, phosphates, and hydroxides unless paired with Group I metals or ammonium.

  • Bronsted-Lowry Acids and Bases: Identify strong acids (e.g., HCl, HBr, HI, HNO3, HClO4, H2SO4) and weak acids (notably, carboxylic acid functional group -COOH).

  • Strong Bases: Recognize that soluble -OH salts (such as NaOH) function as strong bases.

  • Weak Base: Ammonia (NH3) is classified as a weak base.

  • Acid/Base Reactions: Be prepared to predict the products of acid/base reactions involving the acids and bases discussed.