mRNA to Protein (Translation)
mRNA to Protein Translation
Overview
Translation is the process of synthesizing proteins from messenger RNA (mRNA).
Key Components of Translation
tRNA (transfer RNA): Bridges mRNA and amino acids; contains a specific nucleotide triplet codon that corresponds to an amino acid.
Amino Acid Binding: Each amino acid is bound to the 3’ end of a tRNA molecule.
Wobble Codon
The third base of each codon plays a lesser role in specifying an amino acid. This is referred to as the wobble codon where tRNA recognizes multiple codons for a single amino acid.
The codon-anticodon interaction is less stringent at the third position, allowing one tRNA to pair with several codons.
Codon/Amino Acid Codiversity: 4 bases of tRNA allow for coding of 20 amino acids.
Table 27-4: Codon Recognition by tRNA
Anticodon Recognition: Different anticodons can pair with codons giving rise to varying recognition capabilities.
One codon recognized:
Anticodon (3') X-Y-C (5') corresponds to Codon (5') Y-X-G (3').
Anticodon (3') X-Y-A (5') corresponds to Codon (5') Y-X-U (3').
Two codons recognized:
Anticodon (3') X-Y-U (5') corresponds to Codon (5') Y-X-(3') and (5') Y-X-C (3').
Three codons recognized:
Anticodon (3') X-Y-I (5') corresponding includes Codon variation.
Open Reading Frame (ORF)
Nonoverlapping Code: Clarifies how sequences are read without sharing nucleotides.
Overlapping Code: Shows how some nucleotides may be included in more than one reading frame.
Reading Frames: E.g.: AUACGAGUC has three reading frames based on starting position within the sequence.
tRNA Structure
The end of the anticodon arm has seven unpaired nucleotides:
Modified nucleotides include: mG (methylguanosine), dimethylguanosine T, ribothymidine I, inosine Psi, pseudouridine D, 5,6-dihydrouridine, and mI (methylinosine).
nucleotide variations: Extra nucleotides can appear in the extra arm or D arm of tRNA.
Structural Variants of tRNA
Key Loops:
D loop
Anticodon loop
Variable loop
Accepting stem
tRNA arms: Example structures visualized on specific diagrams. CCA at 3' end is crucial for amino acid attachment.
Amino Acid Activation
Ester Bond Formation: An ester bond forms between an amino acid and the 3' end OH of tRNA:
This process consumes 1 ATP and is catalyzed by aminoacyl-tRNA synthetase.
Aminoacyl-tRNA Synthetase: Ensures the correct amino acid is bound to its corresponding tRNA.
Editing Mechanism in Synthetases
Hydrolytic Editing: There is a proofreading mechanism via hydrolytic editing in AA-tRNA synthetase that removes incorrectly bound amino acid after synthesis occurs.
This is crucial for ensuring fidelity in protein synthesis.
Ribosome Composition and Function
Ribosome Structure: Ribosomes are large complex machines that catalyze protein synthesis, made of RNA and protein.
Bacterial Ribosome: Consists of a 70S unit formed by a large 50S subunit and a small 30S subunit, with equal parts RNA and protein.
Heavier in Eukaryotes: Eukaryotic ribosomes are larger and more complex than prokaryotic ones.
Components of the Bacterial Ribosome
Large Subunit (50S):
Contains rRNAs: 5S (120 nt), 23S (2900 nt), and approximately 34 proteins.
Small Subunit (30S):
Contains 16S rRNA (1540 nt) and approximately 21 proteins.
Comparison of Prokaryotic and Eukaryotic Ribosomes
Bacterial: Total Weight: 70S (2.5 MDa), large unit: 50S, small unit: 30S.
Eukaryotic: Total Weight: 80S (4.2 MDa), large unit: 60S (2.8 MDa) with more extensive rRNA varieties (5S, 5.8S, 28S) and corresponding proteins.
The Shine-Dalgarno Sequence
Translation Initiation: The Shine-Dalgarno sequence is essential for ribosome alignment with the mRNA.
Requires initiation factor proteins (IFs) and GTP hydrolysis for effective binding.
Each Open Reading Frame (ORF) includes its own Ribosome Binding Site (RBS).
Peptide Bond Formation**
E,P,A Sites: The ribosome contains E (exit), P (peptidyl), and A (aminoacyl) sites facilitating amino acid addition and peptide bond formation during translation.
fMet-tRNA brings the start codon (AUG) into the ribosome's P site.
Peptide bonds are formed between amino acids at the A site creating a growing peptide chain.
Directionality during Translation
Peptide Chain Growth: The direction of ribosome movement is described in relation to codon positioning on the mRNA strand; crucial towards understanding peptide synthesis.
Ribosome Movement and Dynamics**
Translocation: Mediated by elongation factors with energy input from GTP. The growing peptide chain continues to attach at the A-site tRNA and subsequently moves to the P site.
Visualization: Diagrams illustrate ribosome structure, alignment with mRNA and detailed sites for E, P, and A interactions during translation.