Chemistry of Life - Chapter 2 Flashcards

Chemistry of Life - Chapter 2

2.1 Elements

  • Definition: Elements are the basic form of all matter.

  • Composition: They cannot be broken down into different components by chemical means.

  • Periodic Table: The periodic table lists all known elements, with 9292 occurring naturally in nature.

Elements Essential to Living Things (2.1 & 2.2)

  • Major Elements (96%): All living things primarily consist of:

    • Carbon (C)

    • Oxygen (O)

    • Nitrogen (N)

    • Hydrogen (H)

  • Secondary Elements (4%): Humans also require:

    • Calcium (Ca)

    • Phosphorus (P)

    • Potassium (K)

    • Sulfur (S)

    • Sodium (Na)

    • Chlorine (Cl)

    • Magnesium (Mg)

  • Trace Elements (0.01%): Essential in very small amounts:

    • Iron (Fe)

    • Iodine (I)

    • Fluorine (F)

Element, Molecule, Compound, or Mixture? (2.1)

  • Element: Consists of only one type of atom.

  • Molecule: Formed when two or more atoms are joined together chemically.

    • The atoms can be the same element (e.g., O<em>2O<em>2) or different elements (e.g., H</em>2OH</em>2O).

    • Relationship to Compounds: All compounds are molecules, but not all molecules are compounds.

  • Compound: Formed when two or more different elements are joined together chemically in a fixed proportion.

    • Compounds take on different physical and/or chemical properties than their individual constituent elements.

    • They are typically difficult to separate into their individual elements.

  • Mixture: A combination of two or more different molecules that are not chemically bonded.

    • The substances in a mixture retain their individual properties.

    • Mixtures can be separated using physical means, such as filtration, differences in density, or evaporation.

2.3 ATOMS

  • Definition: The smallest unit of an element that retains the chemical properties of that element.

  • Differentiation: Elements differ from one another based on the number of protons they contain.

  • Atomic Number: This number is unique to each element and is equal to the number of protons in an atom's nucleus.

  • Atomic Mass: Represents the average mass of an element's naturally occurring isotopes, typically measured in atomic mass units (amu).

Subatomic Particles
  • Protons (P+P^+)

    • Location: Found within the nucleus of an atom.

    • Identity: The number of protons defines the element (e.g., all carbon atoms have 66 protons).

    • Atomic Number: The number of protons is equal to the atomic number.

    • Charge: Positively charged (+1+1).

    • Role: Their positive charge holds the negatively charged electrons close to the nucleus.

  • Neutrons (N0N^0)

    • Location: Also found within the nucleus.

    • Number: The number of neutrons is calculated as the atomic mass (rounded to the nearest whole number for a specific isotope) minus the number of protons.

    • Charge: Neutrally charged (00).

    • Role: Help to stabilize the nucleus, especially in larger atoms.

  • Electrons (EE^-)

    • Location: Orbit the nucleus in specific energy levels called orbitals or electron shells.

    • Number: In a neutral atom, the number of electrons is equal to the number of protons.

    • Charge: Negatively charged (1-1).

    • Role: They are the basis of chemical reactions, as their arrangement and interactions determine how atoms bond.

Atomic Structure / Lewis Dot Structure
  • Elements are typically represented by a symbol with associated numbers:

    • Mass Number: Located at the top left, it is the total number of protons plus neutrons in a specific isotope ($ ext{e.g., Atomic # of Carbon = 6, Mass # = 12, means 6 protons + 6 neutrons}$).

    • Atomic Number: Located at the bottom left, it is the number of protons ($ ext{e.g., Carbon has 6 protons, Oxygen has 8 protons}$).

    • Atomic Mass (or Atomic Weight): Usually found below the element symbol, it's the average mass of all isotopes (e.g., Carbon's atomic mass is 12.01112.011, Oxygen's is 15.99915.999).

  • Electron Shells/Orbitals:

    • Electrons occupy distinct energy levels around the nucleus.

    • The innermost shell holds a maximum of 22 electrons.

    • Subsequent shells (outer shells) attempt to achieve an octet, holding up to 88 electrons for stability (e.g., Oxygen has 88 total electrons, with 66 in its outer shell).

2.3 ISOTOPES

  • Definition: Isotopes are varying forms of an element that have the same number of protons (and thus the same atomic number) but differ in the number of neutrons.

  • Chemical Behavior: Despite differing neutron counts, isotopes generally behave in a similar manner in chemical reactions because chemical reactions primarily involve electrons, which are the same in a neutral atom.

  • Stability: A difference in neutron number, especially a significant deviation from the most common isotope, can lead to instability of the element's nucleus.

2.4 RADIOISOTOPE

  • Definition: A radioisotope is an isotope with an unstable nucleus due to an unfavorable proton-to-neutron ratio. This instability causes the atom to release energy waves and particles, known as radiation, as it decays to a more stable form. This process is called radioactive decay.

Uses for Radioisotopes
  1. Basic Science Research:

    • Goal: To develop targeting molecules (vehicles) to deliver medications or