Chapter 5: Chemicals and Their Properties - Summary Notes
Chemicals and Their Properties
Key Concepts
- Pure substances are classifiable by their properties.
- Changes are classifiable as chemical or physical.
- A substance’s properties (chemical & physical) determine its usefulness and effects.
- Ionic compounds consist of positive and negative ions.
- Molecular compounds consist of distinct molecules.
- Many consumer products are developed from petrochemicals.
Space Elevator
- A space elevator would consist of a long cable attached to Earth’s equator with a large mass at the other end (40,000 km up).
- The mass would orbit Earth at the same rate as Earth rotates, keeping the cable taut.
- A "space-proof" elevator car could climb the cable.
- Questions needing answers:
- Cable requirements and operating conditions.
- Physical and chemical properties of the cable.
- Suitable common substances and their limitations.
- Potential modifications to overcome limitations.
- Impact on our lives and planetary home.
Atoms and Ions
- Hyponatremia: A condition of disorientation and loss of balance caused by drinking too much water, resulting in diluted sodium concentration in the blood.
- An atom is an electrically neutral particle with equal electrons and protons.
- An ion is a charged atom due to gaining or losing electrons.
- Sodium atoms lose one electron to form Na+ ions (positive charge).
- Fluorine gains an electron to form F− ions (negative charge).
- Noble gases are stable due to full outer orbits.
- Sodium and fluoride ions are stable because they have the same electron arrangement as neon.
- Sodium loses its outermost electron to achieve a stable electron arrangement like neon.
- Fluorine gains an electron to achieve a stable electron arrangement like neon.
Properties and Changes
- Chemistry: Study of substances, their composition, behavior, and uses.
- Physical Property: A characteristic or description of a substance (e.g., color, texture, density, smell, solubility, taste, melting point, physical state).
- Chemical Property: A characteristic behavior when a substance changes into a new substance (e.g., flammability, bleaching ability, corrosion).
- Physical Change: Does not produce a new substance (e.g., changes of state, dissolving).
- Chemical Change: Produces a new substance (or more than one new substance).
- Evidence of Chemical Changes:
- A new color appears.
- A solid material (precipitate) forms in a liquid.
- Heat or light is produced or absorbed.
- Change is generally difficult to reverse.
- Bubbles of gas are formed.
Hazardous Products and Workplace Safety
- WHMIS (Workplace Hazardous Materials Information System): Provides information on the safe use of hazardous products in Canadian workplaces.
- WHMIS Information is conveyed through:
- Product labels.
- Materials safety data sheets (MSDS).
- Worker training.
- Supplier Label: Required on hazardous materials sold or imported to a workplace in Canada; includes hatched border, bilingual (English/French), product name, hazard symbol, supplier information, and MSDS reference.
- Workplace Label: Required on hazardous materials produced or transferred within a workplace; includes product name, safe handling information, MSDS reference, and hazard symbol.
- MSDS (Materials Safety Data Sheet): Provides detailed information on hazardous properties, safe handling/storage, and emergency procedures.
Patterns and the Periodic Table
- Element: A pure substance that cannot be broken down into simpler substances.
- Periodic Table: Used to explain and predict element properties.
- Metals: Generally solid, shiny, malleable, and conductors of electricity.
- Non-metals: Solid, liquid, or gas; dull, brittle (if solid), and insulators.
- Period: Each row of elements in the periodic table.
- Group: Each column of elements with similar properties.
- Alkali Metals: Group 1 elements (except hydrogen); soft, highly reactive metals.
- Alkaline Earth Metals: Group 2 elements; light, reactive metals.
- Halogens: Group 17 elements; one of the most reactive groups.
- Noble Gases: Group 18 elements; stable, rarely react.
- Atomic Structure:
- Proton (p+): positive charge, located in the nucleus.
- Neutron (n0): neutral charge, located in the nucleus.
- Electron (e−): negative charge, orbits around the nucleus.
- Atomic Number: Number of protons in the nucleus; elements arranged in order of increasing atomic number.
- Bohr−Rutherford Diagram: Represents arrangement of electrons around the nucleus.
- First orbit holds up to 2 electrons.
- Second and third orbits hold up to 8 electrons each.
Atoms and Ions
- Ion: Atom that has become charged by gaining or losing electrons.
- Sodium Ion (Na+): Sodium atom loses one electron; has +1 charge.
- Fluoride Ion (F−): Fluorine atom gains one electron; has -1 charge.
- Noble Gases: Stable due to full outer orbits.
- Sodium and Fluoride Ions: Stable because they have the same electron arrangement as neon.
- Aluminum: Can lose 3 electrons to form Al3+ ions.
- Sulfur: Gains 2 electrons to form S2− ions.
- Cation: Positively charged ion.
- Anion: Negatively charged ion.
Ionic Compounds
- Ionic Compound: Compound made up of positive (metal) and negative (non-metal) ions(e.g., sodium chloride - table salt)
- Ionic Bond: Attraction that holds oppositely charged ions together.
- Ions join together to form an ionic crystal.
- When dissolved in water, water molecules surround each ion, preventing them from rejoining the crystal.
- Electrolyte: Compound that separates into ions when dissolved in water, producing a solution that conducts electricity.
- IUPAC (International Union of Pure and Applied Chemistry) is the organization that decides how chemicals will be named.
- The name of the metal ion remains the same as the name of the neutral metal atom, but the ending of the name of the second ion- the nonmetal- changes to "ide".
- The compound's total ion charge- the negative and positive ion charges added together- must equal zero.
- If there are two charges on the copper ion, use x to represent the unknown value. Remember that the charge on all the ions must remain zero overall.
Polyatomic Ions
- Polyatomic Ion: Ion made up of more than one atom that acts as a single particle (e.g., phosphate (PO4)3−.
- The ionic charge of a polyatomic ion is shared over the entire ion rather than being on just one atom.
Molecules and Covalent Bonding
- Molecular Compound: Pure substance formed from two or more non-metals.
- Molecule: Individual particle in a molecular compound.
- Chemical Formula: Gives exact numbers of atoms in each molecule.
- Covalent Bond: Bond resulting from sharing outer electrons between non-metal atoms.
- Diatomic Molecules: Molecules consisting of two atoms joined with a covalent bond.
- Molecular Compounds: Naming involves using prefi xes to specify the number of atoms.