Chapter 5: Chemicals and Their Properties - Summary Notes

Chemicals and Their Properties

Key Concepts
  • Pure substances are classifiable by their properties.
  • Changes are classifiable as chemical or physical.
  • A substance’s properties (chemical & physical) determine its usefulness and effects.
  • Ionic compounds consist of positive and negative ions.
  • Molecular compounds consist of distinct molecules.
  • Many consumer products are developed from petrochemicals.
Space Elevator
  • A space elevator would consist of a long cable attached to Earth’s equator with a large mass at the other end (40,000 km up).
  • The mass would orbit Earth at the same rate as Earth rotates, keeping the cable taut.
  • A "space-proof" elevator car could climb the cable.
  • Questions needing answers:
    • Cable requirements and operating conditions.
    • Physical and chemical properties of the cable.
    • Suitable common substances and their limitations.
    • Potential modifications to overcome limitations.
    • Impact on our lives and planetary home.
Atoms and Ions
  • Hyponatremia: A condition of disorientation and loss of balance caused by drinking too much water, resulting in diluted sodium concentration in the blood.
  • An atom is an electrically neutral particle with equal electrons and protons.
  • An ion is a charged atom due to gaining or losing electrons.
  • Sodium atoms lose one electron to form Na+Na^+ ions (positive charge).
  • Fluorine gains an electron to form FF^- ions (negative charge).
  • Noble gases are stable due to full outer orbits.
  • Sodium and fluoride ions are stable because they have the same electron arrangement as neon.
  • Sodium loses its outermost electron to achieve a stable electron arrangement like neon.
  • Fluorine gains an electron to achieve a stable electron arrangement like neon.
Properties and Changes
  • Chemistry: Study of substances, their composition, behavior, and uses.
  • Physical Property: A characteristic or description of a substance (e.g., color, texture, density, smell, solubility, taste, melting point, physical state).
  • Chemical Property: A characteristic behavior when a substance changes into a new substance (e.g., flammability, bleaching ability, corrosion).
  • Physical Change: Does not produce a new substance (e.g., changes of state, dissolving).
  • Chemical Change: Produces a new substance (or more than one new substance).
  • Evidence of Chemical Changes:
    • A new color appears.
    • A solid material (precipitate) forms in a liquid.
    • Heat or light is produced or absorbed.
    • Change is generally difficult to reverse.
    • Bubbles of gas are formed.
Hazardous Products and Workplace Safety
  • WHMIS (Workplace Hazardous Materials Information System): Provides information on the safe use of hazardous products in Canadian workplaces.
  • WHMIS Information is conveyed through:
    • Product labels.
    • Materials safety data sheets (MSDS).
    • Worker training.
  • Supplier Label: Required on hazardous materials sold or imported to a workplace in Canada; includes hatched border, bilingual (English/French), product name, hazard symbol, supplier information, and MSDS reference.
  • Workplace Label: Required on hazardous materials produced or transferred within a workplace; includes product name, safe handling information, MSDS reference, and hazard symbol.
  • MSDS (Materials Safety Data Sheet): Provides detailed information on hazardous properties, safe handling/storage, and emergency procedures.
Patterns and the Periodic Table
  • Element: A pure substance that cannot be broken down into simpler substances.
  • Periodic Table: Used to explain and predict element properties.
  • Metals: Generally solid, shiny, malleable, and conductors of electricity.
  • Non-metals: Solid, liquid, or gas; dull, brittle (if solid), and insulators.
  • Period: Each row of elements in the periodic table.
  • Group: Each column of elements with similar properties.
  • Alkali Metals: Group 1 elements (except hydrogen); soft, highly reactive metals.
  • Alkaline Earth Metals: Group 2 elements; light, reactive metals.
  • Halogens: Group 17 elements; one of the most reactive groups.
  • Noble Gases: Group 18 elements; stable, rarely react.
  • Atomic Structure:
    • Proton (p+p^+): positive charge, located in the nucleus.
    • Neutron (n0n^0): neutral charge, located in the nucleus.
    • Electron (ee^−): negative charge, orbits around the nucleus.
    • Atomic Number: Number of protons in the nucleus; elements arranged in order of increasing atomic number.
  • Bohr−Rutherford Diagram: Represents arrangement of electrons around the nucleus.
    • First orbit holds up to 2 electrons.
    • Second and third orbits hold up to 8 electrons each.
Atoms and Ions
  • Ion: Atom that has become charged by gaining or losing electrons.
  • Sodium Ion (Na+Na^+): Sodium atom loses one electron; has +1 charge.
  • Fluoride Ion (FF^−): Fluorine atom gains one electron; has -1 charge.
  • Noble Gases: Stable due to full outer orbits.
  • Sodium and Fluoride Ions: Stable because they have the same electron arrangement as neon.
  • Aluminum: Can lose 3 electrons to form Al3+Al^{3+} ions.
  • Sulfur: Gains 2 electrons to form S2S^{2−} ions.
  • Cation: Positively charged ion.
  • Anion: Negatively charged ion.
Ionic Compounds
  • Ionic Compound: Compound made up of positive (metal) and negative (non-metal) ions(e.g., sodium chloride - table salt)
  • Ionic Bond: Attraction that holds oppositely charged ions together.
  • Ions join together to form an ionic crystal.
  • When dissolved in water, water molecules surround each ion, preventing them from rejoining the crystal.
  • Electrolyte: Compound that separates into ions when dissolved in water, producing a solution that conducts electricity.
Names and Formulas of Ionic Compounds
  • IUPAC (International Union of Pure and Applied Chemistry) is the organization that decides how chemicals will be named.
  • The name of the metal ion remains the same as the name of the neutral metal atom, but the ending of the name of the second ion- the nonmetal- changes to "ide".
  • The compound's total ion charge- the negative and positive ion charges added together- must equal zero.
  • If there are two charges on the copper ion, use x to represent the unknown value. Remember that the charge on all the ions must remain zero overall.
Polyatomic Ions
  • Polyatomic Ion: Ion made up of more than one atom that acts as a single particle (e.g., phosphate (PO4)3(PO_4)^{3-}.
  • The ionic charge of a polyatomic ion is shared over the entire ion rather than being on just one atom.
Molecules and Covalent Bonding
  • Molecular Compound: Pure substance formed from two or more non-metals.
  • Molecule: Individual particle in a molecular compound.
  • Chemical Formula: Gives exact numbers of atoms in each molecule.
  • Covalent Bond: Bond resulting from sharing outer electrons between non-metal atoms.
  • Diatomic Molecules: Molecules consisting of two atoms joined with a covalent bond.
  • Molecular Compounds: Naming involves using prefi xes to specify the number of atoms.