1.3 Physical and Chemical Properties
Physical Properties
- The characteristics that distinguish one substance from another are called properties.
- A physical property is a characteristic of matter that is not associated with a change in its chemical composition.
- Examples of physical properties: density, color, hardness, t<em>m, t</em>b, electrical conductivity.
- Some physical properties (like density and color) can be observed without a change in physical state; others require a physical change (e.g., melting iron, freezing water).
Physical Changes
- A physical change is a change in the state or properties of matter without any accompanying change in the chemical identities of the substances.
- Examples: wax melting, sugar dissolving in coffee, steam condensing to liquid water.
- Other physical changes: magnetizing/demagnetizing metals; grinding solids into powders.
Chemical Properties and Changes
- A chemical property is the ability to change from one type of matter into another (or the inability to change).
- Examples of chemical properties: flammability, toxicity, acidity, and various types of reactivity.
- Iron rusts (with oxygen and water) — rust is a different kind of matter from the original iron, oxygen, and water. Chromium does not oxidize.
- Nitroglycerin explodes easily; neon is very unreactive.
- A chemical change always produces matter that differs from the matter present before the change (e.g., rust formation, gas production in explosions).
- Additional examples of chemical changes: copper reacting with nitric acid; combustion; cooking, digestion, or rotting of food; browning of a banana.
- Example reactions: Cu+2HNO<em>3→Cu(NO</em>3)<em>2+NO</em>2↑; burning cellulose with oxygen → CO<em>2+H</em>2O; cooking red meat involves chemical changes (e.g., iron oxidation in myoglobin).
Extensive vs Intensive Properties
- An extensive property depends on the amount of matter present (e.g., mass, volume).
- Example: a gallon of milk has more mass than a cup of milk.
- An intensive property does not depend on the amount of matter (e.g., temperature).
- Temperature consistency example: if a gallon and a cup of milk are both at 20 °C, mixing them keeps the temperature at 20 °C.
- Distinguish heat vs temperature: a small drop of hot oil on the skin causes brief discomfort, a pot of hot oil causes severe burns; both at the same temperature, but the pot contains more heat (an extensive property).
- Notation: state variables for phases are often represented as s, l, g for solid, liquid, and gas.
NFPA Hazard Diamond (NFPA 704)
- The NFPA 704 hazard identification system provides safety information about substances.
- The diamond has four colored sections: red (flammability), blue (health), yellow (reactivity), white (special hazards).
- Scale for each section ranges from 0 to 4, where 0 = no hazard and 4 = extremely hazardous.
- Special hazards in the white section may indicate oxidizers, corrosive, radioactive, etc.
Periodic Table and Element Classification
- Elements can be grouped by similar properties in the periodic table.
- Some elements conduct heat and electricity well; others do not.
- Elements are broadly classified as metals (good conductors), nonmetals (poor conductors), and metalloids (intermediate conductivities).
- The periodic table places similar-property elements near each other.
Periodic Table Overview
- The periodic table shows grouping by similar properties; elements in the same column (group) tend to have similar chemical behavior.
- Visual cues: background color indicates metal/metalloid/nonmetal; symbol color indicates state at a given condition (solid, liquid, or gas).
- You will learn more about the periodic table as you study chemistry.