Chemistry in Context Lecture Notes

What’s the Matter with Materials?

Introduction to Matter

  • Definition of Matter:
    • Matter is defined as anything that occupies space and has mass. Everything around us can be classified as matter.

Classification of Matter

  • Classification by Phase:

    PhaseTakes the shape of its container?Completely fills its container?Definite volume?Definite shape?
    SolidNoNoYesYes
    LiquidYesNoYesNo
    GasYesYesNoNo
  • Interactive Activity:

    • Engage with simulations showing atoms and molecules in different states of matter.

Types of Matter by Composition

  • Pure Substances:
    • Elements:
    • Comprised solely of one type of atom (e.g., silicon - Si).
    • Compounds:
    • Composed of two or more different types of atoms bonded together (e.g., silicon dioxide - SiO₂).
  • Mixtures:
    • Heterogeneous Mixtures:
    • Composition varies throughout (e.g., gravel).
    • Homogeneous Mixtures:
    • Uniform composition throughout (e.g., sugar solutions in water).

Physical and Chemical Properties

  • Physical Process:

    • A transformation that does not alter the chemical identity of substances involved (e.g., a change in state).
  • Physical Change:

    • Occurs when a substance's physical appearance changes, but its chemical composition remains constant.
    • Examples:
      • Water melting.
      • Salt dissolving in water.
  • Chemical Change:

    • Involves a change in the substance's chemical composition.
    • Example:
      • Ignition of gasoline:

2extC<em>8extH</em>18+25extO<em>2ightarrow16extCO</em>2+18extH2extO2 ext{C}<em>8 ext{H}</em>{18} + 25 ext{O}<em>2 ightarrow 16 ext{CO}</em>2 + 18 ext{H}_2 ext{O}

Characteristics of Pure Substances

  • Defined as made up of one type of particle and have invariant composition.
  • Properties are consistent throughout; cannot be separated into simpler substances by physical means.
    • Examples:
    • Helium (He), water (H₂O), sodium chloride (NaCl).

Classification of Mixtures

  • Mixtures consist of two or more pure substances and can be separated by physical processes.
  • They can vary in composition from one sample to another.
    • Homogeneous Mixtures:
    • Uniform distribution, no visible boundaries (e.g., sweetened tea).
    • Heterogeneous Mixtures:
    • Non-uniform distribution, may show distinct regions (e.g., water and sand).

Example Classification of Matter

  • Examples:
    • Carbon Dioxide: Compound
    • Nickel: Element
    • Sugar: Compound
    • Water: Compound
    • Fluorine: Element
    • Table Salt: Compound
    • Soap: Mixture
    • Sea Water: Mixture

The Periodic Table

  • Composed mainly of metals; metalloids include: B, Si, Ge, As, Sb, Te, Po.
  • Categories of Elements:
    • Metals:
    • Shiny solids, conduct heat and electricity, malleable and ductile.
    • Nonmetals:
    • Solids, liquids, and gases that are nonconductor, and brittle in solid form.
    • Metalloids:
    • Have properties of both metals and nonmetals, are semiconductors.

Groups of the Periodic Table

  • Notable Groups:
    • Group 1: Alkali Metals
    • Group 2: Alkaline Earth Metals
    • Group 15: Pnictogens
    • Group 16: Chalcogens
    • Group 17: Halogens
    • Group 18: Noble Gases

Chemical Symbols

  • Chemical symbols are typically 1 or 2-letter abbreviations for elements.
    • Examples:
    • O: Oxygen
    • Si: Silicon
    • Pb: Lead (Plumbum in Latin)
    • Hg: Mercury (Hydrargyrum in Greek)
    • Cu: Copper (Cuprum in Latin)
    • Fe: Iron (Ferrum in Latin)
    • K: Potassium (Kalium in Latin)
    • Sb: Antimony (Stibium in Latin)
    • Ag: Silver (Argentum in Latin)
    • Au: Gold (Aurum in Latin)

From Elements to Compounds

  • Elements combine in integer ratios to form compounds with different properties.
    • Examples:
    • Iron (Fe)
    • Iron (III) Oxide (Fe₂O₃)
    • Magnetite (Fe₃O₄)

Atom Structure

  • Atoms are the smallest building blocks of matter and are made of subatomic particles: protons, neutrons, and electrons.
    • Components:
    • Protons and neutrons are in the nucleus; electrons orbit.
ParticleRelative ChargeRelative MassActual Mass (kg)
Proton+11$1.67 imes 10^{-27}$
Neutron01$1.67 imes 10^{-27}$
Electron-10$9.11 imes 10^{-31}$
  • For neutral atoms, the number of electrons equals the number of protons to balance charge.
    • Example Atoms:
    • Hydrogen: Atomic #: 1 (1 proton) Mass #: 1.
    • Helium: Atomic #: 2 (2 protons, 2 neutrons) Mass #: 4.

Importance of Recycling

  • Average cell phones contain significant amounts of valuable metals:
    • 300 mg of silver.
    • 30 mg of gold (30 times denser than in gold ore).
  • Urban Mining:
    • Refers to recycling electronics to recover valuable metals.
    • Some companies are developing robotic disassembly to enhance safety and environmental sustainability.

Rare Earth Metals

  • Rare earth metals are critical for various applications, such as:
    • Rechargeable batteries
    • Magnets
    • Speakers
    • Memory chips
    • Fluorescent lighting
    • Catalytic converters
    • Advanced electronics and weaponry
  • Global Supply:
    • China dominates the production of rare earth metals, controlling over 90% of the global supply with 50% of the world's reserves.

Questions for Reflection

  • Your Turn Activities:
    • Analyze atomic structures and identify protons and electrons in several elements.
    • Discuss the implications of electronic waste and urban mining on the environment.