CHEM 0120/0420 Course Study Notes

CHEM 0120/0420 Course Overview

Instructor Information

  • Name: Justin K. Belardi, Ph.D. (Dr. B)

  • Institution: University of Pittsburgh

  • Established: 1787

About the Professor

  • Education:

    • B.S. Chemistry: Yale University

    • M.S. Chemistry: Yale University

    • Ph.D. Chemistry: Yale University

  • Awards:

    • The Most Valuable Parent Award:

    • Recipient: Jenny Belardi

    • Recipient: Lily Belardi

    • The Marlin Award: Justin Belardi

Work Experience

  • Industry Experience:

    • Merck

    • Knopp Biosciences

  • Educational Background:

    • Attended Central Catholic High School, Pittsburgh, Pennsylvania

Course Structure

Course Description

  • General Chemistry II

    • Topics Covered:

    • Solutions

    • Equilibrium

    • Acids/Bases

    • Thermodynamics

    • Electrochemistry

    • Kinetics

    • Intro to Organic Chemistry

  • Schedule:

    • Frequency: Monday, Wednesday, Friday (MWF)

    • Duration: 50 minutes (Approx. 40 classes total)

  • Support:

    • Weekly Recitations: Mandatory sessions with Teaching Assistants (TAs)

    • Practice Problems: Provided systematically throughout the course

    • Quizzes: Regular assessments

    • Canvas: Required platform for class materials

    • Materials Available:

      • Daily Plans

      • Syllabus

      • Worksheets, Keys

      • Textbook, Video Reinforcement, Simulations

Syllabus Key Points

  • Quizzes and Exams: Dates will be specified in the syllabus

  • Required Materials: Textbook and apps specified

  • Policies:

    • Attendance

    • Grading

    • Academic Integrity

    • Disability accommodations

    • Classroom Behavior Standards

  • Plan Subject to Change: Always check for updates regarding syllabus details

Evaluation Criteria

  • Grading Breakdown:

    • Exam #1: Wednesday, February 11th - 15%

    • Exam #2: Friday, March 20th - 15%

    • Exam #3: Friday, April 17th - 15%

    • Recitation Quizzes: Weekly - 15%

    • Final Exam: Tuesday, April 28th (8am) - 20%

    • Lab Grade (CHEM 0120 Only): 20%

  • Note: Dates are tentative and subject to change

Instructor Office Hours

  • Office Hours:

    • Monday: 10am-11am (Outside CSC 150, then in office 107K)

    • Thursday: 9am-10am (Zoom, link posted on Canvas)

    • Appointments: Available by request (Chevron 107K)

Teaching Assistants (TAs)

  • TAs are primary contacts for course clarification and academic support:

    • Declan Johnson

    • Gamze Gumuslu-Gur

    • Danielle Bellis

    • Abigail McClain

    • Connor Chee

    • Lav Barnes

    • Josphat Mwiva

  • Important Points:

    • With over 500 students, one-on-one support by Dr. B will be limited

    • Address major issues directly to Dr. B, not TAs

Tutoring and UTA Availability

  • Free Tutoring: Available in Chevron, with a schedule to be posted on Canvas

  • Undergraduate Teaching Assistants (UTAs):

    • Donovan Allen: 1st Floor Hillman, Wednesday 10:30-11:30

    • Samy Ravichandran: Hillman, Sunday Evenings

    • Nino Caligiuri: Chevron Balcony, Tuesday 1-2pm

    • Taha Chomelawala: Chevron Balcony, Thursday 9-10am

Course Content - General Chemistry II

  • Textbook: OpenStax Chemistry 2e

  • Main Topics:

    • Solutions and Colloids: Chapter 11

    • Chemical Equilibrium and Solubility Equilibrium: Chapters 13 and 15

    • Acids and Bases: Chapter 14

    • Thermodynamics: Chapter 16

    • Electrochemistry: Chapter 17

    • Chemical Kinetics: Chapter 12

    • Nuclear Chemistry / Organic Chemistry: Chapters 20 and 21

Solutions

  • Definition: A solution is a homogeneous mixture of two or more substances.

  • Components:

    • Solvent: The component of the mixture in greater concentration.

    • Solute: The component present in a lower concentration.

  • Example of Dissolution:
    C<em>12H</em>22O<em>11(s)ightarrowC</em>12H<em>22O</em>11(aq)C<em>{12}H</em>{22}O<em>{11}(s) ightarrow C</em>{12}H<em>{22}O</em>{11}(aq)

Types of Solutions
  • Air:

    • Solute: O2(g)

    • Solvent: N2(g)

  • Soft Drinks:

    • Solute: CO2(g)

    • Solvent: H2O(l)

  • Hydrogen in Palladium:

    • Solute: H2(g)

    • Solvent: Pd(s)

  • Rubbing Alcohol:

    • Solvent: H2O(l)

    • Solute: C3H8O(l) (2-propanol)

  • Saltwater:

    • Solute: NaCl(s)

    • Solvent: H2O(l)

  • Brass:

    • Solute: Zn(s)

    • Solvent: Cu(s)

Ionic Dissolution and Dissociation

  • Example Reactions:

    • extKMnO<em>4(s)ightarrowK+(aq)+extMnO</em>4(aq)ext{KMnO}<em>4(s) ightarrow K^+(aq) + ext{MnO}</em>4^{-}(aq)

    • extNa<em>2extSO</em>4(s)<br>ightarrow2extNa+(aq)+extSO42(aq)ext{Na}<em>2 ext{SO}</em>4(s) <br>ightarrow 2 ext{Na}^+(aq) + ext{SO}_4^{2-}(aq)

    • (NH<em>4)</em>2CO<em>3(s)ightarrow2NH</em>4+(aq)+CO32(aq)(NH<em>4)</em>2CO<em>3(s) ightarrow 2 NH</em>4^+(aq) + CO_3^{2-}(aq)

    • $$Al(NO3)3(s)
      ightarrow Al^{3+}(aq) + 3 NO_3^{-}(aq)

Thermodynamics of Dissolution

  • Process Steps:

    1. Break solvent-solvent interactions (Endothermic process)

    2. Break solute-solute interactions (Endothermic process)

    3. Form solute-solvent interactions (Exothermic process)

  • Discussion Points:

    • Identify Individual Intermolecular Forces (IMFs) being formed or broken when NaCl is dissolved in water.

Example of Cold Compress Activation
  • Instructions for Use:

    1. Squeeze: Squeeze firmly until you hear a pop, causing the compress to cool.

    2. Shake: Mix the contents by holding each end and shaking.

    3. Apply: Apply promptly to the affected area.

  • Caution: Single-use product, dispose after use. Store at room temperature. Do NOT freeze.

Homework Assignments

  • Canvas Access: Review the entire syllabus

  • Textbook Bookmarking: OpenStax Chemistry 2e

  • Video Materials: Watch Week 1 videos and review key points from General Chemistry 1 as needed

  • Worksheets: Practice and check work against answer keys on Canvas

  • Calculator: Obtain a scientific calculator capable of scientific notation and logarithmic functions

  • Recitation Overview: Familiarize with TA and review Molarity, mole calculations, and stoichiometry; recitation quiz #1 scheduled for the following week.