Pearson Edexcel IAL Physics Unit 2 Waves and Electricity January 2025 Study Guide

Fundamental Constants and Formula Reference

Physical constants govern all classical and quantum calculations in wave dynamics and circuit theory. The acceleration of free fall close to Earth's surface is g=9.81ms2g = 9.81\,m\,s^{-2}, which is identical to the gravitational field strength g=9.81Nkg1g = 9.81\,N\,kg^{-1}. An electron carries an elementary charge magnitude of e=1.60×1019Ce = 1.60 \times 10^{-19}\,C and has a rest mass of me=9.11×1031kgm_e = 9.11 \times 10^{-31}\,kg. The conversion factor between energy units is 1eV=1.60×1019J1\,eV = 1.60 \times 10^{-19}\,J. Electromagnetic radiation in a vacuum travels at a constant speed of c=3.00×108ms1c = 3.00 \times 10^8\,m\,s^{-1}, and quantum photon interaction calculations rely on Planck's constant h=6.63×1034Jsh = 6.63 \times 10^{-34}\,J\,s

Classical mechanics relations integrate into electrical and wave energy concepts. Kinematic equations for uniform acceleration include s=(u+v)t2s = \frac{(u + v)t}{2}, v=u+atv = u + at, s=ut+12at2s = ut + \frac{1}{2}at^2, and v2=u2+2asv^2 = u^2 + 2as. Dynamics and energy relations dictate that net force is ΣF=ma\Sigma F = ma, weight is W=mgW = mg, linear momentum is p=mvp = mv, and moment of force is moment=Fx\text{moment} = Fx. Mechanical work and energy transformations follow ΔW=FΔs\Delta W = F\Delta s, kinetic energy Ek=12mv2E_k = \frac{1}{2}mv^2, gravitational potential energy ΔEgrav=mgΔh\Delta E_{\text{grav}} = mg\Delta h, and mechanical power P=Et=WtP = \frac{E}{t} = \frac{W}{t}. Efficiency is expressed as the ratio of useful energy output to total energy input, or useful power output to total power input. Material properties include density ρ=mV\rho = \frac{m}{V}, Stokes' law for viscous drag F=6πηrvF = 6\pi\eta rv, Hooke's law ΔF=kΔx\Delta F = k\Delta x, elastic strain energy ΔEel=12FΔx\Delta E_{\text{el}} = \frac{1}{2}F\Delta x, and Young modulus E=σεE = \frac{\sigma}{\varepsilon} where tensile stress σ=FA\sigma = \frac{F}{A} and tensile strain ε=Δxx\varepsilon = \frac{\Delta x}{x}

Wave mechanics equations relate wave speed v=fλv = f\lambda, transverse wave speed on a stretched string v=Tμv = \sqrt{\frac{T}{\mu}}, radiation intensity I=PAI = \frac{P}{A}, Snell's law of refraction n1sin(θ1)=n2sin(θ2)n_1 \sin(\theta_1) = n_2 \sin(\theta_2), refractive index n=cvn = \frac{c}{v}, critical angle sin(C)=1n\sin(C) = \frac{1}{n}, and diffraction grating maxima nλ=dsin(θ)n\lambda = d \sin(\theta). Electrical transport equations define potential difference V=WQV = \frac{W}{Q}, resistance R=VIR = \frac{V}{I}, electric power P=VI=I2R=V2RP = VI = I^2R = \frac{V^2}{R}, electrical work W=VItW = VIt, electrical resistivity R=ρlAR = \frac{\rho l}{A}, charge flow rate I=ΔQΔtI = \frac{\Delta Q}{\Delta t}, and microscopic current density I=nqvAI = nqvA. Series resistor combinations sum linearly as R=R1+R2+R3R = R_1 + R_2 + R_3, whereas parallel combinations sum reciprocally as 1R=1R1+1R2+1R3\frac{1}{R} = \frac{1}{R_1} + \frac{1}{R_2} + \frac{1}{R_3}. Quantum phenomena follow the photon energy relation E=hfE = hf, Einstein's photoelectric equation hf=Φ+12mvmax2hf = \Phi + \frac{1}{2}mv_{\text{max}}^2, and the de Broglie wavelength equation λ=hp\lambda = \frac{h}{p}

Section A: Multiple Choice Conceptual Analysis

Microscopic current conduction is defined by the transport equation I=nqvAI = nqvA, where II represents electric current, qq represents charge per carrier, vv represents drift velocity, and AA represents cross-sectional area. The variable nn represents the charge carrier number density, defined explicitly as the number of conduction electrons contained within a unit volume of 1m31\,m^3 of a given material. It does not represent total electrons, nor is it restricted to a specific wire length

The total number of electrons passing a given point in a conductor over a time interval tt depends on total charge QQ and elementary charge ee. Since total charge passing a point is Q=ItQ = I t, dividing total charge by the charge of a single electron ee yields the total number of electrons N=IteN = \frac{I t}{e}

Pulse-echo positioning systems utilize the velocity and travel time of reflected sound waves to measure distance. A sensor emits a pulse that travels to a target object and returns after time tt. The total distance traversed by the pulse during time tt at speed vv is 2d=vt2d = v t. Solving for the distance between the vehicle and the object yields d=0.5vtd = 0.5 v t

When two identical transverse pulses of wavelength λ\lambda travel toward each other on a string at equal speeds, their spatial positions determine the interference pattern. When both waves advance by half a wavelength (0.5λ0.5\lambda), their crests align directly in phase at the midpoint. By the principle of superposition, the resultant displacement is the algebraic sum of individual displacements, producing constructive interference with peak displacement equal to the sum of the individual amplitudes

In a circuit containing a negative temperature coefficient (NTC) thermistor, a decrease in ambient temperature causes a reduction in thermal energy supplied to the crystal lattice. This reduces the number of bound electrons promoted to the conduction band, decreasing the conduction electron number density nn. With fewer available charge carriers, the thermistor's electrical resistance increases, which reduces total circuit current and causes the ammeter reading to decrease

A potential divider circuit containing three identical resistors of resistance RR connected to an e.m.f. source ε\varepsilon with negligible internal resistance distributes voltage according to equivalent resistance. Two resistors connected in parallel yield an equivalent resistance of Rp=R2=0.5RR_p = \frac{R}{2} = 0.5R. Connected in series with the third resistor RR, the total circuit resistance becomes Rtotal=R+0.5R=1.5R=32RR_{\text{total}} = R + 0.5R = 1.5R = \frac{3}{2}R. Circuit current is I=ε1.5R=2ε3RI = \frac{\varepsilon}{1.5R} = \frac{2\varepsilon}{3R}. The potential difference across the single series resistor measured by a voltmeter is V=IR=(2ε3R)R=23εV = I R = \left(\frac{2\varepsilon}{3R}\right) R = \frac{2}{3}\varepsilon

Stationary waves on a string feature fixed spatial variations in displacement amplitude and phase. All points oscillating within the same anti-nodal loop between two adjacent nodes move in phase, resulting in a phase difference of 00^\circ. However, amplitude varies continuously along the loop from zero at the nodes to a maximum value AA at the antinode. Therefore, any two arbitrary points PP and QQ on the string within a loop (not both at antinodes) have a phase difference of 00^\circ and an oscillation amplitude strictly less than AA

Electrical resistance of a uniform conductor is directly proportional to its length LL for a constant cross-sectional area and material composition. If a segment of length dd exhibits resistance RR, the resistance per unit length is Rd\frac{R}{d}. Multiplying this unit resistance by the total length LL yields the total resistance of the copper wire as Rtotal=Ld×RR_{\text{total}} = \frac{L}{d} \times R

Atomic energy absorption and subsequent photon emission follow discrete energy quantization. An electron in the ground state (0eV0\,eV) of a mercury atom absorbing a photon of energy E=8.74×1019JE = 8.74 \times 10^{-19}\,J gains an equivalent energy in electronvolts calculated by E=8.74×1019J1.60×1019JeV1=5.4625eV5.46eVE = \frac{8.74 \times 10^{-19}\,J}{1.60 \times 10^{-19}\,J\,eV^{-1}} = 5.4625\,eV \approx 5.46\,eV. This promotes the electron directly to the 5.46eV5.46\,eV excited energy level. From the 5.46eV5.46\,eV level, de-excitation can occur via three distinct radiative decay pathways: a direct transition to the ground state (5.46eV0eV5.46\,eV \rightarrow 0\,eV), a transition to an intermediate state (5.46eV4.91eV5.46\,eV \rightarrow 4.91\,eV), and subsequent transition from that intermediate state to the ground state (4.91eV0eV4.91\,eV \rightarrow 0\,eV). These three distinct energy transitions produce exactly 3 unique frequencies of emitted light

A cell of e.m.f. E=9VE = 9\,V connected to an external load resistor R=10ΩR = 10\,\Omega producing a terminal potential difference V=6VV = 6\,V loses potential difference across its internal resistance rr equal to lost volts v=EV=9V6Vv = E - V = 9\,V - 6\,V. The circuit current is I=VR=610I = \frac{V}{R} = \frac{6}{10}. Applying internal resistance formula r=EVIr = \frac{E - V}{I} yields r=106×(96)r = \frac{10}{6} \times (9 - 6)

Quantum Physics and De Broglie Wavelength Analysis

Moving particles exhibit wave-like properties with a characteristic de Broglie wavelength inversely proportional to their linear momentum. For an electron traveling at a velocity of v=3.6×107ms1v = 3.6 \times 10^7\,m\,s^{-1}, the linear momentum pp is calculated using the electron rest mass me=9.11×1031kgm_e = 9.11 \times 10^{-31}\,kg

p=mev=(9.11×1031kg)×(3.6×107ms1)=3.2796×1023kgms1p = m_e v = (9.11 \times 10^{-31}\,kg) \times (3.6 \times 10^7\,m\,s^{-1}) = 3.2796 \times 10^{-23}\,kg\,m\,s^{-1}

Applying the de Broglie relation λ=hp\lambda = \frac{h}{p} with Planck's constant h=6.63×1034Jsh = 6.63 \times 10^{-34}\,J\,s

λ=6.63×1034Js3.2796×1023kgms1=2.0216×1011m\lambda = \frac{6.63 \times 10^{-34}\,J\,s}{3.2796 \times 10^{-23}\,kg\,m\,s^{-1}} = 2.0216 \times 10^{-11}\,m

Thus, the de Broglie wavelength of the electron is 2.02×1011m2.02 \times 10^{-11}\,m

Solar Cell Intensity and Power Calculations

To determine whether a watch battery will charge, the absolute incident optical power on the surface of a solar cell must be evaluated against the device's operational threshold of 0.80W0.80\,W. The solar cell has a total surface area of A=6.4cm2A = 6.4\,cm^2, which converts to square metres as

A=6.4×104m2A = 6.4 \times 10^{-4}\,m^2

When light of intensity I=750Wm2I = 750\,W\,m^{-2} strikes the solar cell, total incident power PinputP_{\text{input}} is given by the intensity relation I=PAI = \frac{P}{A}

Pinput=I×A=750Wm2×6.4×104m2=0.48WP_{\text{input}} = I \times A = 750\,W\,m^{-2} \times 6.4 \times 10^{-4}\,m^2 = 0.48\,W

Comparing the calculated power input of 0.48W0.48\,W to the minimum required threshold of 0.80W0.80\,W demonstrates that 0.48W<0.80W0.48\,W < 0.80\,W. Consequently, the incident optical power is insufficient, and the watch battery will not charge under an intensity of 750Wm2750\,W\,m^{-2}

Temperature Dependence of Resistance and Wire Resistivity

When electrical power is supplied to a metal wire cutting tool, resistive heating increases the thermal energy of the metallic lattice. As temperature rises, positive metal ions vibrate with greater amplitude and kinetic energy about their fixed lattice positions. Conduction electrons moving through the wire experience more frequent collisions with these rapidly vibrating ions. This increases the rate of carrier scattering, obstructing charge flow and causing the overall electrical resistance of the wire to increase

The resistivity ρ\rho of a conductor with circular cross-section depends on resistance RR, length ll, and diameter dd. For a cutting wire with resistance R=0.67ΩR = 0.67\,\Omega, length l=0.14ml = 0.14\,m, and diameter d=0.51mm=0.51×103md = 0.51\,mm = 0.51 \times 10^{-3}\,m, the radius is r=d2=0.255×103mr = \frac{d}{2} = 0.255 \times 10^{-3}\,m

The cross-sectional area AA is calculated as

A=πr2=π×(0.255×103m)2=2.0428×107m2A = \pi r^2 = \pi \times (0.255 \times 10^{-3}\,m)^2 = 2.0428 \times 10^{-7}\,m^2

Rearranging the resistivity formula R=ρlAR = \frac{\rho l}{A} to solve for resistivity ρ\rho

ρ=RAl=0.67Ω×2.0428×107m20.14m=9.776×107Ωm\rho = \frac{R A}{l} = \frac{0.67\,\Omega \times 2.0428 \times 10^{-7}\,m^2}{0.14\,m} = 9.776 \times 10^{-7}\,\Omega\,m

The resistivity of the metal wire at its operating cutting temperature is 9.78×107Ωm9.78 \times 10^{-7}\,\Omega\,m

Wave Properties and Diffraction Grating Optics

A transverse wave is defined as a wave in which particle oscillations or field vibrations occur perpendicular (9090^\circ) to the direction of wave propagation and energy transfer

A diffraction grating experiment utilizes monochromatic light of wavelength λ=650nm=650×109m\lambda = 650\,nm = 650 \times 10^{-9}\,m incident on a grating positioned at a distance L=1.30mL = 1.30\,m from a screen. The observed spatial separation between the central zero-order maximum and the first-order (n=1n = 1) maximum is x=0.22mx = 0.22\,m. The angle of diffraction θ\theta for the first-order peak is calculated using trigonometry

tan(θ)=xL=0.22m1.30m=0.16923    θ=arctan(0.16923)=9.603\tan(\theta) = \frac{x}{L} = \frac{0.22\,m}{1.30\,m} = 0.16923 \implies \theta = \arctan(0.16923) = 9.603^\circ

Evaluating sin(θ)\sin(\theta)

sin(9.603)=0.16686\sin(9.603^\circ) = 0.16686

Alternatively, using the exact hypotenuse distance L2+x2=1.302+0.222=1.3185m\sqrt{L^2 + x^2} = \sqrt{1.30^2 + 0.22^2} = 1.3185\,m

sin(θ)=xL2+x2=0.221.3185=0.16686\sin(\theta) = \frac{x}{\sqrt{L^2 + x^2}} = \frac{0.22}{1.3185} = 0.16686

Applying the diffraction grating equation nλ=dsin(θ)n\lambda = d \sin(\theta) for n=1n = 1

d=λsin(θ)=650×109m0.16686=3.8955×106md = \frac{\lambda}{\sin(\theta)} = \frac{650 \times 10^{-9}\,m}{0.16686} = 3.8955 \times 10^{-6}\,m

The number of grating lines per millimetre NmmN_{\text{mm}} is the reciprocal of slit spacing dd expressed in millimetres

d=3.8955×103mmd = 3.8955 \times 10^{-3}\,mm

Nmm=1d=13.8955×103mm=256.7lines/mmN_{\text{mm}} = \frac{1}{d} = \frac{1}{3.8955 \times 10^{-3}\,mm} = 256.7\,\text{lines/mm}

Thus, the diffraction grating contains 257 lines per mm

A first-order maximum forms on the screen because monochromatic light passes through adjacent narrow slits of the grating and undergoes diffraction, spreading outward. As these diffracted wavefronts overlap on the screen, the path difference between light originating from adjacent slits is equal to exactly one whole wavelength (1λ1\lambda). Arriving at the screen with a path difference of 1λ1\lambda, the waves are completely in phase (phase difference of 00 or 2πrad2\pi\,\text{rad}) and superpose constructively, generating a high-intensity bright line

Circuit Analysis and Non-Ohmic Component Evaluation

A potential divider circuit containing a filament lamp connected in parallel with a 15Ω15\,\Omega fixed resistor is driven by a series-connected variable resistor and a 4.5V4.5\,V battery of negligible internal resistance. When the variable resistor is adjusted so the voltmeter across the parallel combination reads 3.6V3.6\,V, the current through each parallel branch can be determined. From the characteristic current-voltage graph of the filament lamp, at potential difference V=3.6VV = 3.6\,V, the lamp current is Ilamp=0.48AI_{\text{lamp}} = 0.48\,A

The current flowing through the fixed 15Ω15\,\Omega resistor is calculated using Ohm's law

Iresistor=VR=3.6V15Ω=0.24AI_{\text{resistor}} = \frac{V}{R} = \frac{3.6\,V}{15\,\Omega} = 0.24\,A

The total current ItotalI_{\text{total}} entering the parallel combination is the sum of the branch currents

Itotal=Ilamp+Iresistor=0.48A+0.24A=0.72AI_{\text{total}} = I_{\text{lamp}} + I_{\text{resistor}} = 0.48\,A + 0.24\,A = 0.72\,A

The combined resistance RcombR_{\text{comb}} of the parallel branch is

Rcomb=VItotal=3.6V0.72A=5.0ΩR_{\text{comb}} = \frac{V}{I_{\text{total}}} = \frac{3.6\,V}{0.72\,A} = 5.0\,\Omega

Alternatively, calculating lamp resistance Rlamp=3.6V0.48A=7.5ΩR_{\text{lamp}} = \frac{3.6\,V}{0.48\,A} = 7.5\,\Omega and applying the parallel resistance formula

1Rcomb=17.5Ω+115Ω=215+115=315Ω1    Rcomb=5.0Ω\frac{1}{R_{\text{comb}}} = \frac{1}{7.5\,\Omega} + \frac{1}{15\,\Omega} = \frac{2}{15} + \frac{1}{15} = \frac{3}{15}\,\Omega^{-1} \implies R_{\text{comb}} = 5.0\,\Omega

To determine total power dissipated in the entire circuit when the battery delivers an e.m.f. of ε=4.5V\varepsilon = 4.5\,V with negligible internal resistance, total power is the product of total e.m.f. and total current drawn from the battery. Since total circuit current is Itotal=0.72AI_{\text{total}} = 0.72\,A

Ptotal=ε×Itotal=4.5V×0.72A=3.24WP_{\text{total}} = \varepsilon \times I_{\text{total}} = 4.5\,V \times 0.72\,A = 3.24\,W

Hence, total electrical power dissipated in the circuit is 3.24W3.24\,W

LDR Characteristics and Internal Resistance Dynamics

The electromotive force (e.m.f.) of a cell is defined as the total electrical energy converted from chemical energy per unit charge passing through the cell (ε=WQ\varepsilon = \frac{W}{Q}

In a circuit where a Light Dependent Resistor (LDR) is connected in series with a cell possessive of internal resistance rr, a voltmeter placed across the terminals of the cell measures its terminal potential difference VterminalV_{\text{terminal}}

Increasing the intensity of light incident on the LDR increases photon absorption within its semiconductor substrate. Photons supply energy to liberate bound valence electrons into the conduction band, increasing the free charge carrier number density nn. This causes the electrical resistance of the LDR (RLDRR_{\text{LDR}}) to decrease

Because the LDR is in series with the cell's internal resistance rr, the total circuit resistance Rtotal=RLDR+rR_{\text{total}} = R_{\text{LDR}} + r decreases. With constant cell e.m.f. ε\varepsilon, the total circuit current I=εRtotalI = \frac{\varepsilon}{R_{\text{total}}} increases

The potential difference lost across the cell's internal resistance (lost volts) is given by vlost=Irv_{\text{lost}} = I r. As current II increases, lost volts IrI r increase. The terminal potential difference measured by the voltmeter is Vterminal=εIrV_{\text{terminal}} = \varepsilon - I r. Because e.m.f. ε\varepsilon remains constant while lost volts IrI r increase, the voltmeter reading across the cell terminals decreases

Stationary Waves on Vibrating Strings

Stationary waves feature distinct spatial positions where wave amplitude is fixed. Nodes (N) are points along the wave pattern where destructive interference causes zero displacement amplitude. Antinodes (A) are points where constructive interference produces maximum displacement amplitude. On a string driven at its third harmonic (3 anti-nodal loops), 4 nodes (N) are located at the fixed ends and intermediate zero-displacement boundary positions, while 3 antinodes (A) are located at peak displacement positions in the center of each loop

A stationary wave forms on a string through wave reflection and superposition. The vibration generator produces progressive transverse waves that travel down the length of the string toward the fixed support. Upon reaching the support, the waves reflect back in the opposite direction along the string with identical frequency, wavelength, and speed. As incident and reflected waves traverse each other, they superpose. At locations where waves arrive in phase, constructive interference forms antinodes. At locations where waves arrive 180180^\circ out of phase, destructive interference forms nodes, establishing a stationary wave pattern

The relationship governing standing wave frequency ff and string tension TT derives from wave speed equations. The velocity of a transverse wave on a string is v=Tμv = \sqrt{\frac{T}{\mu}}, where μ\mu is mass per unit length. Combining this with wave speed v=fλv = f\lambda yields fλ=Tμf\lambda = \sqrt{\frac{T}{\mu}}. For a string of fixed length ll vibrating at its fundamental mode, λ=2l\lambda = 2l. Substituting for λ\lambda

f(2l)=Tμ    f=12lTμf(2l) = \sqrt{\frac{T}{\mu}} \implies f = \frac{1}{2l}\sqrt{\frac{T}{\mu}}

Squaring both sides produces the linear relation

f2=14l2μTf^2 = \frac{1}{4l^2 \mu} T

Plotting f2f^2 on the y-axis against TT on the x-axis yields a straight line passing through the origin with a constant gradient equal to 14l2μ\frac{1}{4l^2 \mu}

To determine string mass per unit length μ\mu from experimental data with fixed length l=0.85ml = 0.85\,m, the line gradient mm is calculated from graph coordinates (T,f2)(T, f^2) such as (0N,0Hz2)(0\,N, 0\,Hz^2) and (4.0N,2500Hz2)(4.0\,N, 2500\,Hz^2)

m=Δf2ΔT=2500Hz204.0N0=625Hz2N1m = \frac{\Delta f^2}{\Delta T} = \frac{2500\,Hz^2 - 0}{4.0\,N - 0} = 625\,Hz^2\,N^{-1}

Equating experimental gradient to theoretical gradient 14l2μ\frac{1}{4l^2 \mu}

625=14(0.85m)2μ=14(0.7225)μ=12.89μ625 = \frac{1}{4(0.85\,m)^2 \mu} = \frac{1}{4(0.7225)\mu} = \frac{1}{2.89 \mu}

μ=12.89×625=11806.25=5.536×104kgm1\mu = \frac{1}{2.89 \times 625} = \frac{1}{1806.25} = 5.536 \times 10^{-4}\,kg\,m^{-1}

The mass per unit length of the string is 5.54×104kgm15.54 \times 10^{-4}\,kg\,m^{-1}

Optical Fibre Wave Propagation and Signal Transmission

Light entering the flat end face of a glass optical fibre (n2=1.50n_2 = 1.50) from air (n1=1.00n_1 = 1.00) at an angle of incidence θ1=50\theta_1 = 50^\circ refracts toward the normal. Applying Snell's law

n1sin(θ1)=n2sin(θ2)    1.00×sin(50)=1.50×sin(θ2)n_1 \sin(\theta_1) = n_2 \sin(\theta_2) \implies 1.00 \times \sin(50^\circ) = 1.50 \times \sin(\theta_2)

sin(θ2)=sin(50)1.50=0.7660441.50=0.51070\sin(\theta_2) = \frac{\sin(50^\circ)}{1.50} = \frac{0.766044}{1.50} = 0.51070

θ2=arcsin(0.51070)=30.71\theta_2 = \arcsin(0.51070) = 30.71^\circ

The angle of refraction inside the glass fibre is 30.730.7^\circ

To deduce whether a ray inside glass (n1=1.50n_1 = 1.50) incident on an air boundary (n2=1.00n_2 = 1.00) at an angle θ=45\theta = 45^\circ undergoes Total Internal Reflection (TIR), the critical angle CC must be calculated

sin(C)=n2n1=1.001.50=0.6667    C=arcsin(0.6667)=41.81\sin(C) = \frac{n_2}{n_1} = \frac{1.00}{1.50} = 0.6667 \implies C = \arcsin(0.6667) = 41.81^\circ

Because light travels from an optically denser medium (glass) toward a less dense medium (air), and the angle of incidence θ=45\theta = 45^\circ is greater than the critical angle C=41.8C = 41.8^\circ, the ray will undergo total internal reflection at the boundary

When light pulses propagate along an optical fibre, signal degradation occurs via attenuation and modal dispersion. Light intensity leaving the fibre is lower than initial intensity II because optical energy is absorbed by impurities in glass, scattered by density fluctuations, and partially lost through micro-refractions at surface boundary imperfections. Pulse duration leaving the fibre is longer than initial duration TT due to modal dispersion. Light rays enter at different angles and follow different paths: axial rays travel straight along the center (shortest path length), whereas marginal rays bounce via multiple internal reflections (longer path length). Traveling at the same speed v=cnv = \frac{c}{n}, axial rays arrive earlier than marginal rays, causing the output pulse to broaden over time

Adding cladding with a lower refractive index than glass (ncladding<nglassn_{\text{cladding}} < n_{\text{glass}}) alters the boundary conditions compared to an unclad glass-air boundary (nair=1.00n_{\text{air}} = 1.00). Because ncladding>nairn_{\text{cladding}} > n_{\text{air}}, the refractive index ratio ncladdingnglass\frac{n_{\text{cladding}}}{n_{\text{glass}}} is larger than nairnglass\frac{n_{\text{air}}}{n_{\text{glass}}}. Since sin(C)=nboundarynglass\sin(C) = \frac{n_{\text{boundary}}}{n_{\text{glass}}}, a higher numerical ratio increases sin(C)\sin(C), which increases the critical angle CC for light inside the core

Photoelectric Effect and Quantum Nature of Light

In a photocell, monochromatic light delivers photons of uniform individual energy E=hfE = hf. Einstein's photoelectric equation states that maximum kinetic energy is Ek,max=hfΦE_{k,\text{max}} = hf - \Phi, where Φ\Phi is the work function of the metal. Photoelectrons are emitted with a spectrum of kinetic energies ranging from zero up to Ek,maxE_{k,\text{max}}. Surface electrons bound with minimum energy require only Φ\Phi to escape, leaving them with Ek,maxE_{k,\text{max}}. Electrons situated deeper below the metal surface require additional energy to overcome lattice interactions and undergo collisions prior to liberation. Energy losses from these internal collisions reduce kinetic energy upon exit, producing a range of kinetic energies

Photoelectric experiments yield observations that contrast classical wave theory with quantum photon theory:

  1. Low-intensity white light produces no current
  2. High-intensity white light produces no current
  3. Low-intensity ultraviolet light produces a current

Classical wave theory predicts that energy is delivered continuously and absorbed over time proportional to wave intensity. Under wave theory, high-intensity white light should accumulate sufficient energy to eject electrons. The complete absence of current under high-intensity white light disproves classical wave theory

These results are explained by the photon model, where light consists of discrete energy quanta with photon energy E=hfE = hf. Electron emission requires one-to-one interaction between a single photon and a single bound electron. Emission occurs only if single photon energy exceeds work function (hfΦhf \ge \Phi), defining a threshold frequency f0f_0. White light consists of lower frequencies (f<f0f < f_0), so individual photons lack sufficient energy (hf<Φhf < \Phi) to release electrons regardless of intensity. Ultraviolet light has a higher frequency (fUV>f0f_{\text{UV}} > f_0), so individual UV photons carry energy hf>Φhf > \Phi. Even at low intensity, single UV photons instantly transfer energy to liberate electrons, producing a current

To test current flow when battery connections are reversed to supply a opposing potential difference of Vreverse=1.5VV_{\text{reverse}} = 1.5\,V, maximum kinetic energy Ek,maxE_{k,\text{max}} must be compared against the stopping work Estop=eVreverseE_{\text{stop}} = e V_{\text{reverse}}. The photocell is illuminated by UV light of wavelength λ=250nm=250×109m\lambda = 250\,nm = 250 \times 10^{-9}\,m, and the metal plate has a work function of Φ=6.9×1019J\Phi = 6.9 \times 10^{-19}\,J

Photon energy EphotonE_{\text{photon}} is calculated using h=6.63×1034Jsh = 6.63 \times 10^{-34}\,J\,s and c=3.00×108ms1c = 3.00 \times 10^8\,m\,s^{-1}

Ephoton=hcλ=6.63×1034Js×3.00×108ms1250×109m=7.956×1019JE_{\text{photon}} = \frac{hc}{\lambda} = \frac{6.63 \times 10^{-34}\,J\,s \times 3.00 \times 10^8\,m\,s^{-1}}{250 \times 10^{-9}\,m} = 7.956 \times 10^{-19}\,J

Applying Einstein's photoelectric equation for Ek,maxE_{k,\text{max}}

Ek,max=EphotonΦ=7.956×1019J6.900×1019J=1.056×1019JE_{k,\text{max}} = E_{\text{photon}} - \Phi = 7.956 \times 10^{-19}\,J - 6.900 \times 10^{-19}\,J = 1.056 \times 10^{-19}\,J

The energy required for an electron to overcome the opposing 1.5V1.5\,V electric potential difference is

Estop=eVreverse=1.60×1019C×1.5V=2.40×1019JE_{\text{stop}} = e V_{\text{reverse}} = 1.60 \times 10^{-19}\,C \times 1.5\,V = 2.40 \times 10^{-19}\,J

Comparing kinetic energy to stopping work demonstrates that 1.056×1019J<2.40×1019J1.056 \times 10^{-19}\,J < 2.40 \times 10^{-19}\,J (Ek,max<EstopE_{k,\text{max}} < E_{\text{stop}}). No photoelectrons possess sufficient kinetic energy to cross the potential barrier and reach the opposite electrode. Consequently, there is no current in the circuit