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Thermal energy will always be transferred from hotter areas to colder areas.
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Objects will always lose heat until they are in thermal equilibrium with their surroundings: eg. a mug of hot tea will cool down until it reaches room temperature.
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Conduction
Conduction is the main method of thermal energy transfer in solids.
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- Metals are extremely good at conducting heat→ They have an additional method of conduction: %%free delocalised electrons can collide with the atoms, helping to transfer the vibrations through the material and hence transfer heat through the metal very quickly.%%
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- Solids are also good conductors because the particles are close together and bonds are strong, making transfer of KE more rapid.
In fact, diamond, a non-metal, is also an excellent conductor because it has very strong intermolecular bonds.
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- Non-metals, liquids and gases are poor at conducting: Poor conductors are called insulators.
In fact, materials containing small pockets of trapped air are especially good at insulating, as air is a gas and so a poor conductor
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- When a substance is heated, the atoms start to vibrate more.
- They bump into each other, transferring energy from atom to atom
- Intermolecular forces allo the atoms to pass vibrations from one to another
- The stronger the forces, the faster the vibrations are passed
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Convection
Convection in the transfer of heat through fluids (liquids and gases); it cannot occur in solids.
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- When a fluid is heated:
- Molecules push each other apart, making the fluid expand
- The hot fluid becomes less dense than the surroundings
- The hot fluid rises, and the cooler surrounding fluid moves in to take its place
- Eventually, the hot fluid cools, contracts and sinks back down again
- This is called a %%convection current%%
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Thermal Radiation
Thermal radiation is the transfer of heat energy by infrared (IR) waves.
- All bodies, no matter what temperature, %%emit a spectrum of thermal radiation in the form of IR waves%%.
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Radiation is the only type of heat transfer that can travel through a vacuum.
Gases allow radiation through better than liquids, liquids better than solids.
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The hotter object, the more infrared radiation it emits in a given time.
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Colours and surfaces affect how well a body emits and absorbs thermal radiation:
- Black objects are the best at emitting and absorbing thermal radiation
- Shiny objects are the worst at emitting and absorbing thermal radiation
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