Reactions of Alkenes

React via additional reaction

  • The carbon-carbon double bond will open up and add additional atoms on
  • New atoms are added to each carbon

Reactions with hydrogen:

  • Open up the double bond and form the equivalent saturated alkane
  • Needs a catalyst

Reaction with steam/water:

  • Water is added across the double bond and an alcohol is formed
      * For example ethene and water makes ethanol
      * After reactions, mixture is passed from the reactor into a condenser
      * Ethanol and water have a higher boiling point then ethene so both condense whilst any unreacted ethene gas is recycled back into the reactor
      * Alcohol can then be purified through fractional distillation

Reactions with halogens

  • Halogens include bromine, chlorine and iodine
  • Molecules formed are saturated, with the C=C carbons each becoming bonded to a halogen atom
  • Form di(halogen-ine)(alkane)

Test for alkene:

  • The addition of bromine to a double bond can be used to test for alkenes
      * When orange bromine water is added to a saturated compound, like an alkene, no reaction will happen and it remains bright orange
      * If it’s added to an alkene the bromine will add across the double bond making a colourless dibromo-compound, so the bromine water is decolourised