atoms, bonding & molecular polarity U.1 L.2

  • oxygen, carbon, hydrogen, nitrogen, phosphorus and sulfur make up 99% of all living organisms

  • isotopes are atoms of the same element that vary in the number of neutrons

  • since they all have the same number of electrons all isotopes of a element usually have the same chemical properties

  • electrons are important because they control the chemical behaviour of an element, atoms with incomplete valance shells are chemically reactive

  • elements will lose/gain electrons or share electrons to gain stability

  • intramolecular bonds are bonds formed by sharing or transferring electrons, (ie. ionic bonds, the transfer of electrons or covalent bonds, the sharing of electrons)

  • cations are positively charged ions and they lose electrons

  • anions are negatively charged ions and they gain electrons

  • octet rule : atoms tend to gain, loe, or share electrons so as to have 8 electrons

  • ionic bonds occur when one atom donates or gives up one or more electrons, for example, sodium donates an electron to chlorine making it a sodium ion and a chloride ion creating sodium chloride, positives and negatives attract to each other and form an ionic compound

  • polarity is the sharing of electrons, and a molecule with a larger atom will have a stronger pull, therefore it can outpull other electrons (which is what polarity is - the equal/unequal pull when sharing electrons)

  • polar covalent bond : when electrons are shared unequally, due to different elements having different electronegativities

  • non-polar covalent bonds are when electrons are shared equally

  • higher electronegativity = stronger pull of shared electrons

  • polar molecules have dipoles

  • a dipole is a charge due to unequal sharing of electrons

  • the molecule as a whole is neutral, but has parts that act like they are changed depending on how much time electrons are spending there

  • polarity allows molecules to blend in or to dissolve

  • role of solubility : like dissolves like

  • hydrophilic (water loving) compounds dissolve in water because they are polar/charged and can form intermolecular bonds (for example salt where dipoles of water attracted to charged ions, or sugar where dipoles from polar molecules attract to dipoles of water)

  • hydrophobic (water hating) compounds do not dissolve in water because they are non-polar and cannot bind to it

  • intermolecular bonds are bonds between different molecules

  • hydrogen bonds are weak forces between polar molecules and hydrogen of another molecule, due to dipoles, between hydrogens and molecules with N,O,F

  • water is polar, and therefore can attract other water molecules which is COHESION

  • it also attracts to other molecules (non-water) which is ADHESION

  • london bonds/forces are bonds between all molecules, they end to be weaker, and are a temporary unequal distribution of electrons (dispersion forces)

  • van der waals : a bond between dipole-dipole/polar molecules