Energy unit 2 bio

Energy Transformation in Living Things – Notes

  • A firefly’s light is produced by bioluminescence.

  • Bioluminescence is a chemical reaction that converts chemical energy into light energy.

  • This reaction happens in special cells in the firefly’s lower abdomen.

  • Living things carry out thousands of chemical reactions every day.

  • These reactions require or release energy.

  • Life is energy-intensive because organisms constantly use and transform energy.

  • Energy transformation = the consumption and release of energy.

  • Energy transformations occur continuously throughout an organism’s life.

  • Energy can change from one form to another (example: chemical → light).

Metabolism – Notes

  • Metabolism is the term that describes all chemical reactions in living organisms.

  • Metabolism is constant:

    • Begins at conception

    • Ends only when an organism dies

Two Types of Metabolic Reactions
  1. Energy-producing reactions (catabolic reactions)

    • Break down complex molecules into simpler molecules

    • Release energy

  2. Energy-consuming reactions (anabolic reactions)

    • Build complex molecules from simpler molecules

    • Require energy

Example of Metabolism
  • Eating sugar:

    • Sugar molecules are broken down into simpler molecules

    • This process releases energy

  • The released energy is used to:

    • Pump blood

    • Heal tissue

    • Form muscle

    • Support growth

Metabolic Rate
  • Children have higher metabolic rates than adults

    • Because they are growing

  • Younger children have even higher metabolic rates

    • Because they grow faster

Metabolic Pathways – Notes

  • Metabolic pathways are the ordered sequences of chemical reactions that occur during metabolism.

  • There are two types of metabolic pathways:

    • Catabolic pathways

    • Anabolic pathways

How a Metabolic Pathway Works
  • A pathway starts with a specific molecule from food, called a reactant.

  • The reactant is changed through several steps.

  • These steps result in a final product.

  • Each step involves a chain of chemical reactions.

Role of Enzymes
  • Reactions occur in the presence of a catalyst.

  • A catalyst speeds up chemical reactions without being used up.

  • Enzymes are the catalysts in living organisms.

Purpose of Metabolism
  • Metabolism manages the cell’s material and energy resources.

  • It ensures cells have:

    • Enough energy

    • Necessary materials to function and grow

  • Catabolic and anabolic pathways work together to keep cells alive.

Catabolic and Anabolic Pathways – Notes

Catabolic Pathways
  • Catabolic pathways break down complex molecules into simpler compounds.

  • This process releases energy.

  • Example:

    • Cellular respiration

      • Glucose and other fuels → carbon dioxide + water

      • Energy is released

Anabolic Pathways
  • Anabolic pathways build complex molecules from simpler molecules.

  • These pathways consume (absorb) energy.

  • Example:

    • Protein synthesis

      • Thousands of amino acids join to form a protein

Relationship Between Catabolic and Anabolic Pathways
  • Catabolic pathways = downward paths

    • Release energy

  • Anabolic pathways = upward paths

    • Require energy

  • Energy released from catabolic reactions is:

    • Captured

    • Stored

    • Used to drive anabolic reactions

Example: Digestion
  • Digestion is a catabolic process:

    • Food breaks down into simpler compounds

    • Energy is released and stored

  • Anabolic processes then use this energy:

    • To build complex molecules from simpler ones

Gibbs Free Energy (ΔG) – Notes

  • Gibbs free energy measures the amount of energy in a system that is available to do work.

  • It applies when temperature and pressure are constant, such as in a living cell.

  • It was defined in 1878 by J. Willard Gibbs, a professor at Yale University.

ΔG and Spontaneous Reactions
  • ΔG (change in free energy) helps predict whether a reaction:

    • Is spontaneous (occurs without extra energy)

    • Or requires energy input to begin

  • Biologists use ΔG to:

    • Predict which metabolic reactions happen without help

    • Identify reactions that release energy

    • Identify reactions that consume energy

Types of Metabolic Reactions
  • Exergonic reactions:

    • Release free energy

    • Occur spontaneously

    • ΔG is negative

  • Endergonic reactions:

    • Absorb free energy from surroundings

    • Require energy input

    • ΔG is positive

Exergonic Reactions & Activation Energy – Notes

ΔG in Exergonic Reactions
  • In an exergonic reaction, the system loses free energy.

  • Because free energy (G) decreases:

    • ΔG is negative

Example: Cellular Respiration
  • Cellular respiration is an exergonic reaction.

  • One mole of glucose (180 g) releases 686 kcal of energy.

  • Energy is conserved, so:

    • Products have less free energy than reactants

    • Therefore, ΔG is negative

Chemical equation:

C₆H₁₂O₆ + 6O₂ → 6CO₂ + 6H₂O
ΔG = –686 kcal/mol
Activation Energy (Eₐct)
  • Most exergonic reactions are spontaneous, but:

    • Some require an initial input of energy to start

  • Activation energy (Eₐct):

    • The minimum energy needed to start a reaction

  • Once Eₐct is supplied:

    • The reaction proceeds spontaneously

Example: Marshmallow
  • Marshmallow on a table:

    • No reaction → no energy released

  • Marshmallow in a fire:

    • Heat provides activation energy

    • Reaction begins and releases energy

Free Energy Diagram (Exergonic Reaction)
  • Reactants start at higher free energy

  • A small energy hill represents Eₐct

  • Products end at lower free energy

  • Net energy change is negative (ΔG < 0)

Endergonic Reactions – Notes

  • An endergonic reaction:

    • Absorbs free energy from its surroundings

    • Stores free energy in molecules

  • Because free energy (G) increases:

    • ΔG is positive

Example of an Endergonic Reaction
  • Building glycogen from glucose units

  • Multiple glucose molecules are joined to form a glycogen molecule

  • Energy is required to build these bonds

Spontaneity and Energy Source
  • Endergonic reactions are not spontaneous

  • They always require an outside energy source to begin

  • The magnitude of ΔG:

    • Represents the amount of energy needed to drive the reaction

Energy Coupling
  • Endergonic reactions are driven by coupling them with exergonic reactions

  • Energy released from an exergonic reaction is used to:

    • Power the endergonic reaction

Activation Energy
  • Endergonic reactions have:

    • A much higher activation energy

  • They rely on:

    • Exergonic reactions with lower activation energy

    • To provide the needed energy

Energy Coupling & ATP – Notes

  • Cells store energy released from exergonic reactions.

  • This stored energy is later used to drive endergonic reactions.

  • Metabolic pathways and chemical reactions help supply energy to cells.

Energy Coupling
  • Energy coupling is the transfer of energy:

    • From an exergonic reaction

    • To an endergonic reaction

  • Energy coupling allows non-spontaneous reactions to occur.

ATP (Adenosine Triphosphate)
  • ATP is a universal energy molecule found in all living organisms.

  • It performs the same function in:

    • Bacteria

    • Humans

    • All other living things

  • ATP is usually the immediate source of energy for:

    • Cellular work

    • Chemical reactions

    • Movement, growth, and maintenance

ATP Structure and Function – Notes

What is ATP?
  • ATP (adenosine triphosphate) is a multifunctional molecule.

  • It transports chemical energy so metabolism can occur.

  • ATP is the main energy currency of the cell.

Structure of ATP
  • ATP consists of:

    • Adenosine (an organic molecule)

    • Three phosphate groups

  • Adenosine includes:

    • The sugar ribose

    • The nitrogenous base adenine

Phosphate Bonds
  • The first phosphate is attached by a simple covalent bond.

  • The second and third phosphates are attached by high-energy bonds.

ATP Hydrolysis
  • Hydrolysis breaks the bond between phosphate groups.

  • When the terminal phosphate is removed:

    • ATP → ADP (adenosine diphosphate) + inorganic phosphate (Pi)

  • This reaction is exergonic.

  • Energy released:

    • 7.3 kcal per mole of ATP (standard conditions)

ATP in Bioluminescence
  • Fireflies use ATP hydrolysis:

    • ATP → ADP

    • Energy released produces light in the presence of oxygen

ATP Regeneration (Phosphorylation)
  • Phosphorylation adds a phosphate group to ADP:

    • ADP + Pi → ATP

  • This process requires energy.

  • Animals use energy from glucose breakdown to regenerate ATP.