Chemistry Test Study Guide: Chemical Reactions

Chemical Equations and Recipes

  • A chemical equation is like a recipe because it shows the ingredients (reactants) and what they produce (products).

Parts of a Chemical Equation

  • Reactants: The substances that are initially involved in a chemical reaction.
  • Products: The substances that are produced as a result of the chemical reaction.
  • +: Separates reactants from each other or products from each other.
  • Coefficients: Numbers placed in front of reactants or products to balance the equation, indicating the ratio of moles.
  • (s), (l), (g), or (aq): Symbols indicating the state of matter:
    • (s) - solid
    • (l) - liquid
    • (g) - gas
    • (aq) - aqueous (dissolved in water)

Thermodynamics of Chemical Reactions

  • Exothermic: A reaction that releases energy, usually in the form of heat. The energy of the products is lower than the energy of the reactants.
  • Endothermic: A reaction that absorbs energy, usually in the form of heat. The energy of the products is higher than the energy of the reactants.

Observations and Chemical Equations

  • Observations can tell us about a reaction that a chemical equation might not, such as:
    • Heat released (exothermic)
    • Light produced
    • Color change
    • Evolution of a gas
    • Formation of a precipitate.
  • Physical changes vs. chemical changes

Indicators of a Chemical Change

  • Evolution of a gas.
  • Formation of a precipitate.
  • Color change.
  • Change in temperature (either giving off heat or absorbing heat).
  • Production of light.

Energy Flow in Chemical Reactions

  • Bonds Breaking: Requires energy input (endothermic).
  • Bonds Forming: Releases energy (exothermic).

Ions, Electrons, and Batteries

  • How a Battery Works:
    • A battery consists of an anode, a cathode, and an electrolyte.
    • Chemical reactions at the anode and cathode create a flow of electrons through an external circuit.
    • Ion movement through the electrolyte maintains charge balance.
  • Common Battery Anode Elements (Lithium, Sodium, Magnesium):
    • These elements are easily oxidized, meaning they readily lose electrons.
    • They have a high energy density, allowing for smaller and lighter batteries.
  • Ion Movement and Electricity Production:
    • Ions move from the anode to the cathode through the electrolyte.
    • This ion movement balances the electron flow in the external circuit, enabling the battery to produce electricity.

Electron Movement Vocabulary

  • LEO the lion says GER:
    • Lose Electrons = Oxidation
    • Gain Electrons = Reduction
  • Reduction: The gain of electrons by a substance.
  • Oxidation: The loss of electrons by a substance.

Conservation of Mass

  • The total amount of matter in a system remains constant, regardless of chemical and physical changes.

Balancing Chemical Equations

  • Balancing Equations: Ensuring that the number of atoms of each element is the same on both sides of the equation.
  • Atom Inventory/Model Representation: A method to keep track of the number of atoms of each element on both sides of the equation.
  • Example
    • C<em>2H</em>2+O<em>2CO</em>2+H2OC<em>2H</em>2 + O<em>2 \rightarrow CO</em>2 + H_2O
    • FeS<em>2+Cl</em>2FeCl<em>3+S</em>2Cl2FeS<em>2 + Cl</em>2 \rightarrow FeCl<em>3 + S</em>2Cl_2
    • Al+HAsO<em>3H</em>2+Al(AsO<em>3)</em>3Al + HAsO<em>3 \rightarrow H</em>2 + Al(AsO<em>3)</em>3

Types of Chemical Reactions

  • Synthesis: Two or more reactants combine to form a single product. A+BABA + B \rightarrow AB
  • Decomposition: A single reactant breaks down into two or more products. ABA+BAB \rightarrow A + B
  • Single Exchange/Displacement: One element replaces another element in a compound. A+BCAC+BA + BC \rightarrow AC + B
  • Double Exchange/Displacement: Two compounds exchange ions or elements. AB+CDAD+CBAB + CD \rightarrow AD + CB
    • Note: An insoluble precipitate may form as a product.
  • Combustion: A substance reacts with oxygen, usually producing heat and light. Often involves hydrocarbons. C<em>xH</em>y+O<em>2CO</em>2+H2OC<em>xH</em>y + O<em>2 \rightarrow CO</em>2 + H_2O

Classifying Chemical Reactions

  • Examples:
    • 16Ag+S<em>88Ag</em>2S16Ag + S<em>8 \rightarrow 8Ag</em>2S (synthesis)
    • 2KI+Br<em>22KBr+I</em>22KI + Br<em>2 \rightarrow 2KBr + I</em>2 (single exchange)
    • BaCl<em>2+Na</em>2SO<em>4BaSO</em>4+2NaClBaCl<em>2 + Na</em>2SO<em>4 \rightarrow BaSO</em>4 + 2NaCl (double exchange)
    • 2KClO<em>32KCl+3O</em>22KClO<em>3 \rightarrow 2KCl + 3O</em>2 (decomposition)
    • 2KI+Pb(NO<em>3)</em>2PbI<em>2+2KNO</em>32KI + Pb(NO<em>3)</em>2 \rightarrow PbI<em>2 + 2KNO</em>3 (double exchange)
    • Zn+F<em>2ZnF</em>2Zn + F<em>2 \rightarrow ZnF</em>2 (synthesis)
    • 2C<em>3H</em>7OH+9O<em>26CO</em>2+8H2O2C<em>3H</em>7OH + 9O<em>2 \rightarrow 6CO</em>2 + 8H_2O (combustion)

Predicting Products and Balancing Equations

  • Using the understanding of common chemical reaction types to predict the products and balance the equation.
  • Examples:
    • HgOHgO \rightarrow
    • Mg+Ag<em>2SO</em>4Mg + Ag<em>2SO</em>4 \rightarrow
    • C<em>5H</em>10+O2C<em>5H</em>{10} + O_2 \rightarrow
    • K<em>2SO</em>4+Ca(NO<em>3)</em>2K<em>2SO</em>4 + Ca(NO<em>3)</em>2 \rightarrow
    • Al+O2Al + O_2 \rightarrow
    • F2+NaIF_2 + NaI \rightarrow