8. Electronic Structure

1. Electron Shells and Rules

Electrons are arranged in shells (energy levels) around the nucleus. There are specific rules for how these shells fill up:

  • The First Shell: Closest to the nucleus, it has the lowest energy level and can hold a maximum of 2 electrons.

  • The Second Shell: Can hold a maximum of 8 electrons.

  • The Third Shell: Can also hold a maximum of 8 electrons.

  • Filling Order: It is best to add electrons one at a time (top, right, bottom, left) before pairing them up.

2. Stability and Reactivity
  • Stable Atoms: An atom is stable when its outermost shell is completely full.

  • Unstable Atoms: Most atoms have incomplete outer shells. To become stable, they must react with other atoms to either gain or lose electrons.

  • Noble Gases: Elements in Group 0 (e.g., Neon, Argon) already have full outer shells. Because they are stable, they are unreactive.

3. Representing Electron Structure

You can show the arrangement of electrons in two ways:

  • Dot and Cross Diagrams: Draw the nucleus and the shells as rings, placing dots or crosses to represent electrons.

  • Numerical Representation: List the number of electrons in each shell, separated by commas or spaces.

    • Example (Argon): Atomic number 18. Structure is 2, 8, 8.

    • Example (Calcium): Atomic number 20. Structure is 2, 8, 8, 2.

4. Ion Formation and Electronic Structure

When atoms gain or lose electrons to become stable, they become ions.

  • Positive Ions (Cations): Formed when an atom loses outer electrons.

    • Example (Calcium): A calcium atom (2, 8, 8, 2) loses 2 electrons to become a Ca²⁺ ion with a structure of 2, 8, 8.

  • Negative Ions (Anions): Formed when an atom gains electrons to fill its outer shell.

    • Example (Fluorine): A fluorine atom (2, 7) gains 1 electron to become a F⁻ ion with a structure of 2, 8.

  • Drawing Ions: Always place large square brackets around the ion diagram and write the overall charge in the top right corner.