Notes: Chemical and Waste Management in Modern Dental Assisting (Chapter 23)

Exposure Hazards in the Dental Office

  • The dental assistant is exposed to a wide variety of chemicals used for treatment procedures, cleaning of instruments and surfaces, disinfection and sterilization, laboratory procedures, and x-ray processing.

  • Potential damage targets: heart, kidney, liver, and lung tissues.

  • Results of exposure range from short-term discomfort (e.g., burns, rashes) to life-threatening conditions (e.g., cancer, sterility, organ failure).

Hazardous Chemicals: Definitions and Classifications

  • Hazardous chemicals are defined as any chemical that can cause a physical or health hazard.

  • A chemical is considered hazardous if it:

    • Can ignite (catch fire) extflammableorcombustibleext{flammable or combustible}.

    • Can react or explode when mixed with other substances.

    • Is corrosive.

    • Is toxic.

Hazardous Chemical Categories (Visual cues)

  • CORROSIVE MATERIALS

  • TOXIC CHEMICALS

  • FLAMMABLE SOLVENTS

  • Note: Copyright and source references pertain to textbook illustrations.

Exposure to Chemicals: Primary Routes

  • Three primary methods of exposure include:

    • Inhalation

    • Skin contact

    • Ingestion

  • Gases, vapors, and dusts of chemicals can cause direct damage to the lungs.

Acute and Chronic Chemical Toxicity

  • Acute chemical toxicity: Results from a high level of exposure over a short period.

  • Chronic chemical toxicity: Results from many repeated exposures, generally to lower levels, over a much longer time — months or years.

Hand Protection

  • When using chemical disinfectants, wear a utility-type glove made from a chemical-resistant material such as natural rubber, neoprene, or industrial-grade nitrile.

  • Latex gloves worn during patient care do not provide adequate protection when handling chemicals.

Eye Protection

  • Serious damage or blindness can result from chemical accidents.

  • Safety eyewear options vary; ideal goggles have soft vinyl flanges (rims) at the top and bottom and fit the face snugly.

Protective Clothing

  • When caustic or staining chemicals are used, wear a rubber or neoprene apron when mixing or pouring the chemical.

  • The Safety Data Sheet (SDS, formerly MSDS) for each product provides specific information regarding the need for additional personal protective equipment (PPE).

Inhalation Protection

  • Masks worn during patient care may or may not provide adequate protection when working with chemicals.

  • The proper face mask should be fluid-repellent and should provide respiratory protection.

Control of Chemical Spills

  • Accidents and spills should not be common occurrences.

  • Planning and practice in dealing with spills should minimize employee exposure to harmful chemicals.

  • Refer to the Safety Data Sheet (SDS) for the specific product for accurate information on how to manage spills.

Mercury Spill Kit

  • Should be available in all dental offices in which amalgam is used.

  • Exposure to even small amounts of mercury is very hazardous to health of dental personnel.

  • Mercury can be absorbed through the skin or inhaled as mercury vapors.

Acid Spill Emergency Cleanup Instructions (Acid Spill)

  • For a spill up to 1 liter (Not for use with hydrofluoric acid):

    • Protect

    • Absorbs

    • Neutralize

    • Cleanup

  • Steps referenced from Stepp CA, Woods M: Laboratory procedures for medical office personnel (1998).

  • Copyright © 2024, Elsevier Inc.

Eyewash Units

  • OSHA regulations require an eyewash unit in every place of employment where chemicals are used.

  • When turned on, eyewash irrigates the eyes with a soft, wide flow of water to bathe away contaminants without causing additional damage.

  • Employees must be trained in proper use of the eyewash station, and the unit should be inspected every 3 months3\text{ months} to ensure functionality.

Eyewash Units (Images and Examples)

  • Visual references show different eyewash configurations (A and B) from lab safety materials.

Ventilation

  • Good ventilation is essential when dealing with any type of chemical.

  • Many dental offices have specialized exhaust systems in the laboratory, sterilization, and darkroom areas for fumes and dust.

General Precautions for Storing Chemicals

  • Store dental medications and chemicals in a dry, cool, dark place and away from direct sunlight.

  • Follow instructions on the product; avoid exposure to light.

  • Check expiration date; rotate inventory to use older materials first.

Removal of Empty Containers

  • Empty containers may still hold residues that can burn or explode.

  • Never fill an empty container with another substance because dangerous chemical reactions could occur.

  • Follow the label and SDS guidance for disposing of empty containers.

Disposal of Waste in the Dental Office

  • Dental offices use substances regulated under federal, state, or local environmental regulations.

  • Materials may affect wastewater treatment or bypass treatment into waterways.

  • Many states require hauling specific waste by licensed carriers.

Classification of Waste

  • General waste: nonhazardous, nonregulated waste discarded in covered containers.

  • Hazardous waste: ignitable, corrosive, reactive, toxic, or EPA-listed waste.

  • Contaminated waste: contact with blood or other body fluids; infectious or regulated waste.

  • Pathologic Waste and Sharps.

General Waste Management

  • Regular dental office waste should be recycled whenever possible (e.g., aluminum, glass, newspapers, corrugated fiber, office paper, mixed paper).

Handling Hazardous Waste

  • May include toxic chemicals, extracted teeth with amalgam restorations, and other toxic waste.

  • Dispose in accordance with local and state regulations.

Disinfectants

  • Small quantities of spent germicidal solutions containing 2%2\% or less of glutaraldehyde can usually be poured down the drain.

  • Check with local authorities on disposal methods for these chemicals.

Scrap Amalgam

  • Collect and store scrap amalgam in a designated, dry, airtight container.

  • Scrap amalgam not recycled must be managed as hazardous waste.

  • Recycled scrap amalgam container must be labeled with the dental office name, address, telephone, and the date collection started.

Photochemical Waste

  • Radiographic fixer: on-site treatment requires silver recovery systems.

  • Off-site treatment involves storing used fixer and contracting with a disposal company for pickup.

  • Radiographic developer: products with high or low pH are likely hazardous waste and must be managed per local regulations.

Lead Contamination

  • Lead foil is easily recyclable but cannot be disposed of in the regular garbage.

  • Exempt from regulation as hazardous waste when recycled as scrap metal, but must be recycled through a licensed recovery facility.

Handling Contaminated Waste

  • Should be placed in a lined trash receptacle with a properly fitted lid.

  • Empty contents daily or when full; in most states, dispose of with general waste.

Handling Infectious or Regulated Waste

  • Never dispose of infectious waste with general waste.

  • Types include blood/blood-soaked materials, pathologic waste (e.g., soft tissue, extracted teeth), and sharps.

  • Sharps must go in specialized “sharps” containers labeled with universal biohazard symbol.

Disposal of Medical Waste

  • Once contaminated waste leaves the office, disposal is regulated by the EPA and state/local laws.

  • Disposal manner is often determined by the weight of infectious materials.

  • The average dental practice is categorized as a “small producer” of infectious waste and disposal is regulated accordingly.

  • The dentist must maintain records of final disposal (how, when, where).

Pathologic Waste

  • Must be separated and collected for disposal in a container that is leak-proof, has a tight-fitting lid, labeled “pathologic waste – incineration only,” and collected by a medical waste company.

Handling Extracted Teeth

  • Dispose of extracted teeth as regulated medical waste unless returned to the patient.

  • If teeth are returned, standard disposal provisions no longer apply.

  • Do not dispose of extracted teeth containing amalgam in regulated medical waste destined for incineration.

  • Check state/local regulations for disposal of teeth containing amalgam.

Sharps (Infectious Waste)

  • OSHA, CDC, and EPA classify sharps as infectious waste.

  • Disposable sharps must be placed in a closable, leakproof, puncture-resistant container immediately after use.

  • Container must be labeled with the biohazard symbol and color-coded for easy identification.

  • State regulations differ on container pickup frequency.

Hazard Communication Program (OSHA)

  • OSHA issued the Hazard Communication Standard to ensure employees know the identity and hazards of chemicals in the workplace (Employee Right-to-Know).

  • Requires employers to implement a hazard communication program.

Major Changes to the Hazard Communication Standard (HCS)

  • Hazard classification: chemicals categorized to compare hazard severity within a hazard class; same category implies same label requirements and language.

  • Labels: all labels include a harmonized signal word, pictogram, and hazard statement for each hazard class/category.

  • Safety Data Sheets (SDS): now use a specified 16-section format16\text{-section format}.

Chemical Inventory

  • A comprehensive list of every product used in the office is required.

  • When a new product with a hazardous chemical is added, it must be added to the chemical list, and the SDS must be placed in the SDS file.

  • The manufacturer/distributor should provide an updated SDS when appropriate.

Safety Data Sheets (SDS)

  • SDSs contain health and safety information about every chemical in the office.

  • They provide comprehensive technical information and are a resource for employees.

  • Describe: physical and chemical properties, health hazards, routes of exposure, precautions for safe handling and use, emergency and first-aid procedures, spill-control measures.

Labeling of Chemical Containers

  • Containers must be labeled to indicate contents and any associated hazards.

  • When a chemical is transferred to a different container, the new container must also be labeled.

  • No single universal labeling system is required; multiple approaches are possible.

  • Two key requirements:

    • The labeling system includes all required information.

    • All employees are trained to read and understand the label.

NFPA Hazard Labeling System

  • The National Fire Protection Association (NFPA) labeling system uses four diamonds (blue, red, yellow, white).

  • Each diamond contains a numeric rating from 0 to 4 for each category:

    • Health hazard (blue)

    • Flammability (red)

    • Reactivity (yellow)

    • Special hazards (white), e.g., OXY for oxidizers.

Exemptions to Labeling Requirements

  • Certain chemicals are exempt from labeling requirements, such as tobacco and tobacco products, wood and wood products, food, drugs, cosmetics, and alcoholic beverages sold and packaged for consumer use.