EB

Module 6

Module 6: Dislocations and Strengthening Mechanisms

Contents

  • Dislocations & Plastic Deformation
    • Mechanisms of plastic deformation in metals.
  • Strengthening Mechanisms in Metals.
  • Recovery, Recrystallization, and Grain Growth.

Plastic Deformation – Dislocations

  • Permanent plastic deformation is due to:
    • Shear processes where atoms change their neighbors.
    • Inter-atomic forces and crystal structure play significant roles.
  • Cumulative movement of dislocations leads to gross plastic deformation.
    • Edge dislocations move by slip and climb.
    • Screw dislocations move by slip and cross-slip.
  • Dislocation interactions are complex due to multiple dislocations moving across different slip systems.

Dislocation Interactions

  • Dislocations moving on parallel planes can annihilate each other, leading to:
    • Vacancies or interstitials.
  • Dislocations on non-parallel planes hinder each other's movement, causing sharp breaks:
    • Jog: Break out of slip plane.
    • Kink: Break in slip plane.
  • Other hindrances to dislocation motion include:
    • Interstitial and substitutional atoms.
    • Foreign particles and grain boundaries.
    • External grain surfaces and phase change structures.
  • Material strength can be increased by arresting dislocation motion.

Plastic Deformation Mechanisms – Slip

  • Two main mechanisms: Slip and Twinning.
    • Slip is more prominent, involving sliding of crystal blocks along slip planes.
    • Occurs when shear stress surpasses a critical value.
    • Slip occurs in specific directions (slip directions) on certain crystallographic planes.
    • A combination of a slip plane and a slip direction forms a Slip System.
  • During slip, each atom moves an integral number of atomic distances along the slip plane.

Factors Affecting Slip

  • Extent of slip is influenced by:
    • External load and resulting shear stress.
    • Crystal structure and slip planes’ orientation relative to shear stress directions.
    • Critical shear stress defined for single crystals by Schmid.

Slip in Polycrystalline Materials

  • In polycrystalline aggregates:
    • Individual grains mutually constrain each other, preventing plastic deformation at lower stresses.
    • Slip involves the generation, movement, and rearrangement of dislocations, maintaining mechanical integrity at grain boundaries.
    • Need at least five independent slip systems for ductility and grain boundary integrity (von Mises).
    • Twinning also contributes to crystal deformation.

Slip Systems Overview

Crystal TypeSlip PlanesSlip Directions
FCC{111}
BCC{110}, {112}, {123}
HCPBasal, Prismatic, Pyramidal
NaCl{110}

Plastic Deformation Mechanisms – Twinning

  • Twinning involves a portion of crystal changing orientation in a symmetrical way relative to the rest.
  • Twinning changes plane orientation, allowing further slip to take place and occurs on specific planes and directions for each crystal structure.

Slip vs. Twinning Comparison

CharacteristicSlipTwinning
OrientationSame across slip planeDifferent across twin plane
Size (in atomic distances)MultiplesFractions
OccurrenceEvery planeSpecific planes
Time RequiredMilli secondsMicro seconds

Strengthening Mechanisms

  • Increasing material strength by hindering dislocation motion leads to various strengthening mechanisms:
    • Single-phase materials:
    • Grain size reduction.
    • Solid solution strengthening.
    • Strain hardening.
    • Multi-phase materials:
    • Precipitation strengthening.
    • Dispersion strengthening.
    • Fiber strengthening.
    • Martensite strengthening.

Strengthening by Grain Size Reduction

  • Dislocations face hindrances when moving from one grain to another due to orientation changes.
  • Smaller grain sizes increase hindrances, increasing yield strength.
  • Yield strength is related to grain size through the Hall-Petch relation:
    • (\sigmay = \sigma0 + k d^{-1/2})
  • Can be controlled through cooling or plastic deformation followed by heat treatment.

Effects of Grain Size Reduction

  • Enhances both strength and toughness.
  • Grain size can be quantified by comparing with standard charts.
  • ASTM grain size number (Z) relates to grain diameter (D) as:
    • (D = \frac{1}{Z})

Solid Solution Strengthening

  • Impurities introduce lattice strains which anchor dislocations.
  • Effectiveness is determined by:
    • Size difference of solute and base material.
    • Volume fraction of solute.
  • Various interactions include elastic, modulus, stacking-fault, and electrical interactions.

Yield Point Phenomenon

  • Upper Yield Point (UYP) marks a transition from elastic to plastic deformation.
  • Lower Yield Point (LYP) requires higher stress for initiation of plastic flow compared to sustaining it.
  • Lüders bands occur during this phenomenon, aligning at approximately 45 degrees to the tensile axis.

Causes of Yield Point Phenomenon

  • Associated with small amounts of interstitial or substitutional impurities.
  • Could involve unlocking of dislocations or generation of new dislocations.
  • Magnitude is influenced by the interaction energy between solute atoms and dislocations.

Strain Hardening

  • Involves increasing strength and hardness through plastic deformation.
    • Strain hardening occurs primarily at low temperatures.
  • Increased dislocation density results from deformation, enhancing yield stress correlation:
    • (\tauT = \tau0 + A\sqrt{p})
  • Notable changes in physical properties include:
    • Decreased density and conductivity.
    • Increased thermal expansion and reactivity.
  • Recovery through annealing restores original properties in three stages: recovery, recrystallization, and grain growth.

Precipitation & Dispersion Hardening

  • Foreign particles obstruct dislocation movement, enhancing material strength.
  • Precipitation hardening (age hardening) requires a soluble second phase at high temperatures that precipitates upon cooling.
  • Aging can be natural (room temperature) or artificial (heated).
  • In dispersion hardening, fine particles, like oxides, are added and must have low solubility.

Fiber Strengthening

  • Incorporates high-strength fibers into a ductile matrix for improved performance.
  • Requires high strength and modulus for fibers and ductility for the matrix.
  • Strengthening mechanisms involve load distribution and require exceeding a critical fiber volume.

Martensite Strengthening

  • Formation of martensitic phase induces strengthening from the original high-temperature phase.
  • Characterized by unique growth patterns and twin structures; occurs in various alloy systems.
  • Strength attributed to dislocation density and carbon involvement in Fe-C systems.

Recovery, Recrystallization, and Grain Growth

  • Recovery:
    • Initial annealing stage, reducing dislocation density and stress without altering microstructure.
  • Recrystallization:
    • Occurs post-recovery; formation of new strain-free equiaxed grains; influenced by stored energy and purity.
  • Grain Growth:
    • Follows complete recrystallization, driven by grain boundary energy reduction. Effectively retarded by impurities.