Atomic Structure, Isotopes, and Ions

Atomic Structure
  • Atoms: Fundamental units of all matter.

  • Subatomic Particles & Location

    • Nucleus: Dense center, holds most mass. Contains protons and neutrons.

    • Electron Cloud: Region around nucleus, holds most volume. Contains electrons.

Subatomic Particles: Charges & Role
  • Proton (p⁺): Charge +1. Determines element (Atomic Number Z).

  • Neutron (n⁰): Charge 0. Varies in isotopes.

  • Electron (e⁻): Charge-1 . Controls chemical reactions and bonding.

Atomic Number (Z)
  • Definition: Number of protons.

  • Key Points

    • Uniquely identifies each element.

    • Equals electrons in a neutral atom.

Mass Number & Isotopes
  • Mass Number (A): Sum of protons and neutrons (not on periodic table).

  • Isotopes: Same element (same Z), different neutrons (different A).

  • Isotope Notation: {}^{A}_ {Z}X (e.g., {}^{14}_ {6}C has 6 protons, 8 neutrons).

Atomic Mass Unit (u)
  • Standard unit for atomic masses, approximate mass of proton or neutron.

Average Atomic Mass
  • Weighted average mass of an element's naturally occurring isotopes (on periodic table).

  • Formula: \overline{M} = (\text{fraction of isotope }1\times \text{mass of isotope }1) + (\text{fraction of isotope }2\times \text{mass of isotope }2) + \dots

Elements, Ions, and Charge Balance
  • Element: Substance of only one type of atom.

  • Ion Formation: Atoms lose/gain electrons to form ions.

    • Cation: Positive ion (loses electrons).

    • Anion: Negative ion (gains electrons).

  • Relevance: Ionic charge affects conductivity and chemical behavior.