review

  • EWGS- increase dienophile reaction but decrease diene reaction

  • EDGS- increase diene reaction but decrease dienophile reaction,

  • the major and minor product of diels alder is the cis (major) and trans

  • NACN and diene +halogen= addition of CN

  • sn2:a nucleophilic substitution reaction where a bond is broken and another is formed synchronously

  • if a diene has an EWG, if it has >1 EDGS it will still be reactive

  • EWG TO dienophile, EDG to diene

  • diene must have cis confirmation to overlap p orbitals with trans dienophile

  • diels alder is concerted pericyclic reaction

  • if losing H makes you more aromatic, you’re best to be depropronated