Covalent compound bonds

Describe what covalent network substances are and give examples.

Covalent network substances are made of atoms covalently bonded in a continuous three-dimensional lattice.

  • not consist of discrete molecules.

Examples: diamond, graphite, silicon dioxide (SiO₂), silicon carbide (SiC).

Explain how the structure affects properties like melting point and hardness.

Hard and brittle

Atoms in covalent network substances are held together in a rigid 3D lattice by strong covalent bonds. This makes them extremely hard. However, when force is applied, the structure tends to shatter

High melting & boiling points

The continuous network of strong covalent bonds requires a large amount of energy to be broken, resulting in very high melting and boiling points.

Poor conductors of electricity

Most covalent network substances do not have free-moving electrons or ions. Electrons are held tightly in covalent bonds and cannot move, so they cannot conduct electricity (exception: graphite).

insoluble in water

The strong covalent bonds in the lattice are not broken by interactions with water molecules, making them insoluble

Compare covalent networks to other types of bonding structures.