Table
quantity | symbol | represents | positive means | negative means | spontaneity |
enthalpy change | ΔH | heat absorbed/released at constant pressure | endothermic: system gains heat from surroundings and feels cold | exothermic: system releases heat to surroundings (feels hot) | spontaneous if negative |
entropy change | ΔS | change in disorder of system | more disorder | more order | spontaneous if positive |
gibbs free energy change | ΔG | driving force for a process at constant temperature and pressure | non-spontaneous | spontaneous | if its negative its spontaneous, if its positive its not spontaneous |
cell potential | E°cell | voltage of a redox reaction | galvanic cell, spontaneous, produces electricity | electrolytic cell, non spontaneous, needs external power | if its positive spontaneous, if its negative non spontaneous |
equilibrium constant | k | ratio of products/reactants at equilibrium | products favored | reactants favored |
ΔG = ΔH - TΔS
ΔG° = −nFE°cell