Rates of Reaction

  • Rateofachemicalreaction:Rate of a chemical reaction: The amount of reactant used up or product made in a given time.

Factors Affecting Rate of Reaction

Concentration
  • Increasing concentration of reactants increases rate of reaction
  • MoreparticlesperunitvolumeMore particles per unit volume, so the collision rate between reacting particles increases

  → The successful collision rate increases, which results in an increased rate of reaction.

 

Temperature
  • Increasing temperature increases the rate of reaction
  • The average kinetic energy of particles increase
  • ParticlesaremovingfasterandcollidingmoreftenandsomoreparticleshaveanenergygreaterthanorequaltotheactivationenergyParticles are moving faster and colliding more ften and so more particles have an energy greater than or equal to the activation energy
      * Increased rate of succesful collisions and so increased rate of reaction

 

Surface Area
  • Decreasing the particle size (increasing surface area) increases the rate of reaction
  • This is because there are morereactantparticlesexposedtocollide,more reactant particles exposed to collide, so the collision rate increases, therefore the successful collision rate increases, resulting in an increased rate of reaction

 

  • LargesurfaceareacanbedangerousLarge surface area can be dangerous'
      * For example, flour dust and wood dust have large surface areas, and are combustible. A spark from a machine, or a lit match, can cause an explosion. This also applies to gases from mines.
Pressure
  • Increasing the pressure in a gaseous system increases the rate of reaction
  • The distance between particles is reduced under pressure
  • There are moreparticlesperunitvolume,more particles per unit volume, so the collision rate increases, therefore the successful collision rate increases, resulting in an increased rate of reaction.

 

Presence of Catalyst
  • Catalyst:Catalyst: is a substance (usually a transition metal) which speeds up a chemical reaction, but remains unchanged at the end

  • Adding a catalyst increases the rate of reaction

  • AcatalystlowerstheactivationenergyforareactionA catalyst lowers the activation energy for a reaction

  • More particles will have an energy greater than or equal to the activation energy, therefore successful collision rate increases resulting in increased rate of reaction

 

  • Enzymes are protein molecules. They are biological catalysts which speed up reactions but remain chemically unchanged at the end
  • Enzymes function best at optimum temperature and pH level otherwise they may denature and completely stop functioning

Photochemical Reactions

Light Causing a Chemical Reaction

Photochemical Reaction: reaction which needs light to take place

  • The higher the light intensity the higher the rate of the reaction.

  • %%Photosynthesis:%% light provides energy for the reaction and chlorophyll is a dye that absorbs light. carbon dioxide + water → (light + chlorophyll) → glucose + oxygen

  • Use of silver salts in photography:
      * Silver halide salts are used in black and white photography
      * AgCl is sensitive to light & breaks down to form metallic silver Ag+ -> Ag
      * Appears black

  • Brighter the light on the film, the faster the reaction & the darker that part of the photograph appears i.e. improves efficiency & accuracy of photos