Ionization Energy

Ionization energy is the energy required to remove an electron from an isolated gaseous atom or ion.

  • In simpler terms, it measures how much energy is needed to remove an electron from an atom.

High ionization energy = Difficult to remove an electron.

Low ionization energy = Easier to remove an electron.


First ionization energy is the energy required to remove the first electron from a neutral gaseous atom.

  • First ionization energy = Removes the first electron.

  • The atom becomes a +1 ion.


Successive Ionization Energies

Successive ionization energies are the energies required to remove additional electrons from an already positively charged ion.


Ionization energy generally decreases down a group.

Why?

  1. Atomic radius increases as you move down a group.

  2. More electron shells are added.

  3. Shielding effect increases.

  4. The outermost electron experiences less effective attraction from the nucleus.

  5. Less energy is needed to remove it.