Chapter 2 - Chemical Basis of Life

Matter and Elements

  • Matter occupies space and has mass.

  • Elements are substances that cannot be broken down into simpler substances by ordinary chemical reactions.

  • Total number of elements is 109109, consisting of 9292 natural and 1717 "artificial" elements.

  • Atoms are the building blocks of elements.

Atomic Structure and Isotopes

  • Subatomic particles:

    • Neutron: no electrical charge, mass of 1amu1\,\text{amu}, located within the nucleus.

    • Proton: +1+1 electrical charge, mass of 1amu1\,\text{amu}, located within the nucleus.

    • Electron: 1-1 electrical charge, mass of 0amu0\,\text{amu}.

  • Atoms are electrically neutral, where the number of protons equals the number of electrons.

  • Atomic number (ZZ) equals the number of protons (which also equals the number of electrons).

  • Mass number equals the number of protons plus the number of neutrons.

  • Isotopes are atoms with the same number of protons and electrons but different numbers of neutrons (e.g., 1H{}^1\text{H}, 2H{}^2\text{H}, 3H{}^3\text{H}).

  • Radioactive isotopes feature unstable nuclei that undergo decay; they are utilized in clinical imaging techniques and 14C{}^{14}\text{C} dating of biological materials.

Molecules and Chemical Bonds

  • Molecules are formed by 22 or more atoms joined together by chemical bonds.

  • Chemical bonds occur when atoms transfer or share electrons in their outermost shell.

  • Ionic bonds: attraction between oppositely charged ions (e.g., NaCl\text{NaCl}).

    • Ions: atoms that have gained or lost an electron.

    • Cation: loses electron, becomes positively charged, formed by metals.

    • Anion: gains electron, becomes negatively charged, formed by nonmetals.

  • Covalent bonds: sharing of electron pairs between atoms in a molecule.

    • Nonpolar covalent: equal sharing of electrons (e.g., H2\text{H}_2, O2\text{O}_2, N2\text{N}_2).

    • Polar covalent: unequal sharing of electrons, resulting in positive and negative regions on the molecule (e.g., H2O\text{H}_2\text{O}).