Chem 1113 Chapter 10

Line Formula of Organic Compounds

  • Line Formula: A simplified way to represent organic molecules.

    • Simplest Representation: This formula shows only the essential components of the molecule without detailing every atom indicated.

    • Carbon at Corners:

      • In a line formula, carbon atoms are presumed to be located at the "corners" of lines or where lines intersect.

      • A carbon atom is also assumed at the end of a line when no additional atoms are explicitly written.

    • Hydrogens on Carbons:

      • Each carbon atom is assumed to have enough hydrogen atoms to satisfy its tetravalency (four total bonds).

      • This means each carbon will be bonded to enough hydrogens to make a total of four connections (bonds).

Example: Hexane (C6H14)

  • Structural Formula: The detailed representation showing every atom and bond explicitly.

    • Visual representation of all carbon (C) and hydrogen (H) atoms including the bonds between them.

  • Condensed Formula: A more compact representation that summarizes the structure.

    • For hexane: C6H14 represents the entire compound without needing to illustrate every bond.

  • Line Formula: A skeletal representation that emphasizes connectivity and structure without showing all atoms.

    • The line formula for hexane would show a continuous line with implied carbons at the ends and intersections, while hydrogens are not explicitly shown.