GCSE Chemistry Topic 2 - Bonds, Structure & Properties of Matter


Part 1: Types of Bonding & Ionic Bonding

🔗 Ionic Bonding

Occurs between metal and non-metal atoms.

  • Electron transfer from metal to non-metal
    → Metal forms a positive ion (cation)
    → Non-metal forms a negative ion (anion)

📊 Diagram Suggestion:
Draw Na⁺ and Cl⁻ with dot & cross to show electron transfer.

🧲 Strong electrostatic attraction between oppositely charged ions = strong ionic bond

💎 Properties of Ionic Compounds

  • High melting & boiling points – lots of energy needed to break strong bonds

  • Conduct when molten or aqueous – ions are free to move and carry charge

  • Soluble in water

🎯 Command Word Tip

  • Explain = say why + link to structure and bonding

🧠 Think: Why don’t solids conduct?
Ions are fixed in a lattice

🧪 Recall Check
Q: Why do ionic compounds only conduct when molten or in solution?
A: Because ions are free to move and carry charge.


Part 2: Covalent Bonding & Metallic Bonding

Covalent Bonding

Occurs between non-metal + non-metal atoms.

  • Atoms share electrons to get full outer shells

  • Each shared pair = covalent bond (strong)

🧪 Simple Molecular Substances

  • Low melting/boiling points → only weak intermolecular forces to break

  • Do not conduct electricity → no free electrons or ions

  • Examples: H₂, CO₂, CH₄

🧠 Think: Why does H₂ have low m.p.?
→ Only weak forces between molecules

🎯 Command Word Tip

  • Describe = say what happens

  • Explain = give reasons with structure/bonding

💠 Giant Covalent Structures

🔹 Unlike simple molecules, these have strong covalent bonds throughout a 3D network
Examples:

Substance

Bonds

Key Feature

Diamond

4 bonds per carbon

Very hard, high m.p.

Graphite

3 bonds + free e⁻

Conducts, layers slide (slippery)

Graphene

1 atom thick

Strong + conductive

Silicon Dioxide (SiO₂)

Si-O bonds

Hard, like diamond

🧪 Metallic Bonding

  • Positive metal ions in a sea of delocalised electrons

  • Electrons are free to move, so metals conduct electricity

  • Strong electrostatic forces = high m.p./b.p.

  • Layers of atoms can slidemalleable

🧲 Alloys:
→ Made from different-sized atoms
Distort layers and prevent sliding → stronger

🧠 Think: Why is copper a good conductor?
→ Delocalised electrons move and carry charge.

🧪 Recall Check
Q: Why can graphite conduct but diamond can’t?
A: Graphite has delocalised electrons; diamond has none.


Part 3: States of Matter & Physical Changes

🧊 States of Matter

State

Particle Arrangement

Energy Level

Solid

Fixed, regular

🔽 Lowest

Liquid

Can move around

🔼 Medium

Gas

Free, far apart

🔼🔼 Highest

🧠 Think:
Why do particles move faster when heated?
→ Gain kinetic energy

🔁 Changes of State

  • Melting / Boiling: Energy used to break forces of attraction

  • Condensing / Freezing: Energy released as particles come together

  • Temperature stays the same during change

📘 Latent Heat (Grade 8–9):
Energy used to break bonds during change, without increasing temp

🎯 Command Word Tip

  • State = name it

  • Explain = reason + link to energy/particles

🧪 Quick Quiz
Q: Which state has the weakest forces?
A: Gas

Q: What’s the opposite of sublimation?
A: Deposition


Part 4: Structures & Properties of Substances

🧪 Ionic Compounds

  • Strong electrostatic bonds

  • High m.p./b.p., only conduct when molten or aqueous

Real-world link:
Used in grit salt for de-icing roads – high melting point helps melt ice


🧪 Simple Molecular Substances

  • Weak forces between molecules, NOT between atoms

  • Low m.p./b.p., don’t conduct

🎯 Exam Tip:
When asked why it’s a gas/liquid, mention weak intermolecular forces


🧪 Polymers

  • Long chains of covalently bonded molecules

  • Usually solid at room temp – stronger forces than gases/liquids

🎯 Exam Tip:
State it’s a solid due to intermolecular forces stronger than in gases/liquids


🧪 Giant Covalent Structures

Substance

Bonds

Properties

Diamond

4 per carbon

Strong, rigid, no conduction

Graphite

3 per carbon + delocalised e⁻

Conducts, slippery

Graphene

Single layer

Strong, light, conductive

SiO₂

Si–O bonds

Strong, hard, high m.p.


🧪 Fullerenes

  • Hollow molecules of carbon (e.g., C₆₀)

  • Can form nanotubes – cylindrical fullerenes

Used in nanotechnology and drug delivery due to cage-like shape

🧠 Think: Why are they good for electronics?
→ Conduct + small + strong

🧪 Quick Test
Q: What makes graphite slippery?
A: Weak forces between layers

Q: Why are nanotubes used in electronics?
A: Conduct electricity + strong