Fatty Acids

Fatty Acids

Building Blocks

  • Fatty acids serve as the fundamental building blocks for other lipids.

Structure of a Fatty Acid

  • A fatty acid consists of:

    • A carboxyl group (-COOH) at one end (the head).
    • A long chain of carbons (the tail) at the other end.
  • The carbon chain is unbranched, forming a straight line.

  • The number of carbons in the chain varies, typically ranging from 12 to 20 in naturally occurring fatty acids.

  • The number of carbons is always even because fatty acid chains are built by adding two carbons at a time.

Types of Fatty Acids

  • Fatty acids are classified as either saturated or unsaturated.
Saturated Fatty Acids
  • Saturated fatty acids have the maximum number of hydrogen atoms attached to each carbon atom.

  • They are commonly found in animal fats.

  • Due to their straight, unkinked structure, saturated fatty acids can pack together tightly.

  • As a result, they are solid at room temperature (e.g., Crisco, butter).

Unsaturated Fatty Acids
  • Unsaturated fatty acids do not have the maximum number of hydrogen atoms due to the presence of at least one double bond between carbon atoms.

  • The double bond creates a kink in the fatty acid chain.

  • These kinks prevent unsaturated fatty acids from packing together tightly.

  • Consequently, they are liquid at room temperature (e.g., canola oil, olive oil).

  • These are typically plant fats.

Trans Fats
  • Normal unsaturated fats have a cis bond, which creates a significant kink in the fatty acid structure due to both hydrogen atoms being on the same side.

  • Trans fats have a trans bond, where hydrogen atoms are on opposite sides, reducing the kink.

  • Trans fats behave more like saturated fats and are solid at room temperature.

  • Most trans fats are created in a lab, although some occur naturally.

  • Trans fats are considered unhealthy because the body has difficulty processing them due to their infrequent natural occurrence.

  • The body has few enzymes to deal with trans fats, leading to efforts to eliminate them from diets.